Nyerereite
Encyclopedia
Nyerereite is a very rare sodium calcium carbonate mineral with formula Na
Sodium
Sodium is a chemical element with the symbol Na and atomic number 11. It is a soft, silvery-white, highly reactive metal and is a member of the alkali metals; its only stable isotope is 23Na. It is an abundant element that exists in numerous minerals, most commonly as sodium chloride...

2Ca
Calcium
Calcium is the chemical element with the symbol Ca and atomic number 20. It has an atomic mass of 40.078 amu. Calcium is a soft gray alkaline earth metal, and is the fifth-most-abundant element by mass in the Earth's crust...

(C
Carbon
Carbon is the chemical element with symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds...

O
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

3)2. It forms colorless, platey pseudohexagonal orthorhombic crystals that are typically twinned
Crystal twinning
Crystal twinning occurs when two separate crystals share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals in a variety of specific configurations. A twin boundary or composition surface separates the two crystals....

. It has a specific gravity
Specific gravity
Specific gravity is the ratio of the density of a substance to the density of a reference substance. Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is nearly always water for...

 of 2.54 and indices of refraction
Refractive index
In optics the refractive index or index of refraction of a substance or medium is a measure of the speed of light in that medium. It is expressed as a ratio of the speed of light in vacuum relative to that in the considered medium....

 of nα=1.511, nβ=1.533 and nγ=1.535. Nyerereite is not stable in contact with the atmosphere and rapidly breaks down. Collection specimens must be kept in a sealed argon
Argon
Argon is a chemical element represented by the symbol Ar. Argon has atomic number 18 and is the third element in group 18 of the periodic table . Argon is the third most common gas in the Earth's atmosphere, at 0.93%, making it more common than carbon dioxide...

 environment.

It has a Hermann–Mauguin notation of mm2 and the respective space group is Cmc21. In nature Nyerereite is naturally twinned
Crystal twinning
Crystal twinning occurs when two separate crystals share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals in a variety of specific configurations. A twin boundary or composition surface separates the two crystals....

 and is pseudohexagonal with triad twinning; meaning that this is a six sided crystal that apparently has a hexagonal shape but is not in the hexagonal system
Hexagonal crystal system
In crystallography, the hexagonal crystal system is one of the 7 crystal systems, the hexagonal lattice system is one of the 7 lattice systems, and the hexagonal crystal family is one of the 6 crystal families...

. Triad twinning is the intergrowth of three orthorhombic crystals that turn at their center and form hexagonally shaped crystals. Nyerereite is biaxial negative, and has a 2v of 29 degrees. It shows a center acute bisectrix and a birefringence of approximately 0.023. At high temperatures or just erupted lava nyerereite is uniaxial and shows an interference color of second order blue when twinning is not present, and when twinning is there the interference color of nyerereite is first order grey.

Special characteristics

Since nyerereite is very unstable when it reaches the surface it creates pseudomorph
Pseudomorph
In mineralogy, a pseudomorph is a mineral or mineral compound that appears in an atypical form , resulting from a substitution process in which the appearance and dimensions remain constant, but the original mineral is replaced by another...

s, which is basically the process by the appearance and dimensions remain constant but the main mineral which makes the components is replaced by another. There is an important observation that McKie (1976) made, he categorized nyrereite into two different categories high and low nyrereite. There are two types because the Ol Doinyo Lengai
Ol Doinyo Lengai
Ol Doinyo Lengai is an active volcano located in the north of Tanzania and is part of the volcanic system of the Great Rift Valley in Eastern Africa. It is located in the eastern Rift Valley, south of both Lake Natron and Kenya. It is unique among active volcanoes in that it produces...

 lavas are very soluble when they come in contact with water or the atmosphere, the lava changes physically and chemically. Therefore as nyerereite is at high temperature or warm we have what McKie (1976) calls high nyerereite but when it cools down and gets hydrated we have pirssonite that has a chemical formula of Na2Ca(CO3)2·2(H2O).

Occurrence and discovery

It was first recognized and described by J.B. Dawson from the Ol Doinyo Lengai
Ol Doinyo Lengai
Ol Doinyo Lengai is an active volcano located in the north of Tanzania and is part of the volcanic system of the Great Rift Valley in Eastern Africa. It is located in the eastern Rift Valley, south of both Lake Natron and Kenya. It is unique among active volcanoes in that it produces...

 carbonatite
Carbonatite
Carbonatites are intrusive or extrusive igneous rocks defined by mineralogic composition consisting of greater than 50 percent carbonate minerals. Carbonatites may be confused with marble, and may require geochemical verification....

 lava
Lava
Lava refers both to molten rock expelled by a volcano during an eruption and the resulting rock after solidification and cooling. This molten rock is formed in the interior of some planets, including Earth, and some of their satellites. When first erupted from a volcanic vent, lava is a liquid at...

s in 1963 and named in honor of the president of Tanzania
Tanzania
The United Republic of Tanzania is a country in East Africa bordered by Kenya and Uganda to the north, Rwanda, Burundi, and the Democratic Republic of the Congo to the west, and Zambia, Malawi, and Mozambique to the south. The country's eastern borders lie on the Indian Ocean.Tanzania is a state...

, Julius K. Nyerere (1922-1999). In the carbonatite lava it is associated with the potassium bearing gregoryite
Gregoryite
Gregoryite is an anhydrous carbonate that is rich in potasium and sodium...

. It has also been reported from the Afrikanda alkaline intrusive complex, in the Kola Peninsula
Kola Peninsula
The Kola Peninsula is a peninsula in the far northwest of Russia. Constituting the bulk of the territory of Murmansk Oblast, it lies almost completely to the north of the Arctic Circle and is washed by the Barents Sea in the north and the White Sea in the east and southeast...

, Russia
Russia
Russia or , officially known as both Russia and the Russian Federation , is a country in northern Eurasia. It is a federal semi-presidential republic, comprising 83 federal subjects...

.
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