Nephelometer
Encyclopedia
A nephelometer is a stationary or portable instrument for measuring suspended particulates
Suspension (chemistry)
In chemistry, a suspension is a heterogeneous fluid containing solid particles that are sufficiently large for sedimentation. Usually they must be larger than 1 micrometer. The internal phase is dispersed throughout the external phase through mechanical agitation, with the use of certain...

 in a liquid
Liquid
Liquid is one of the three classical states of matter . Like a gas, a liquid is able to flow and take the shape of a container. Some liquids resist compression, while others can be compressed. Unlike a gas, a liquid does not disperse to fill every space of a container, and maintains a fairly...

 or gas
Gas
Gas is one of the three classical states of matter . Near absolute zero, a substance exists as a solid. As heat is added to this substance it melts into a liquid at its melting point , boils into a gas at its boiling point, and if heated high enough would enter a plasma state in which the electrons...

 colloid
Colloid
A colloid is a substance microscopically dispersed evenly throughout another substance.A colloidal system consists of two separate phases: a dispersed phase and a continuous phase . A colloidal system may be solid, liquid, or gaseous.Many familiar substances are colloids, as shown in the chart below...

. A nephelometer measures suspended particulates by employing a light beam (source beam) and a light detector set to one side (often 90°) of the source beam. Particle density
Density
The mass density or density of a material is defined as its mass per unit volume. The symbol most often used for density is ρ . In some cases , density is also defined as its weight per unit volume; although, this quantity is more properly called specific weight...

 is then a function of the light reflected
Reflection (physics)
Reflection is the change in direction of a wavefront at an interface between two differentmedia so that the wavefront returns into the medium from which it originated. Common examples include the reflection of light, sound and water waves...

 into the detector from the particles. To some extent, how much light reflects for a given density of particles is dependent upon properties of the particles such as their shape, color
Color
Color or colour is the visual perceptual property corresponding in humans to the categories called red, green, blue and others. Color derives from the spectrum of light interacting in the eye with the spectral sensitivities of the light receptors...

, and reflectivity
Reflectivity
In optics and photometry, reflectivity is the fraction of incident radiation reflected by a surface. In general it must be treated as a directional property that is a function of the reflected direction, the incident direction, and the incident wavelength...

. Nephelometers are calibrated to a known particulate, commonly Arizona road dust then use environmental factors k-factors to compensate lighter or darker colored dusts accordingly. K-factor is determined by the user by running the nephelometer next to an air sampling pump and comparing results.

Nephelometer uses

The main uses of nephelometers relate to air quality measurement for pollution monitoring, climate monitoring, and visibility. Airborne particles are commonly either biological contaminants, particulate contaminants, gaseous contaminants, or dust.

This chart shows the types and sizes of various particulate contaminants. This information is helpful toward understanding the character of particulate pollution inside a building or in the ambient air. It is also useful for understanding the cleanliness level in a controlled environment.

Biological contaminants include mold, fungus, bacteria, viruses, animal dander, dust mites, pollen, human skin cells, cockroach parts, or anything alive or living at one time. These are the biggest enemy of Indoor Air Quality specialist because they are contaminants that cause health problems. Levels of biological contamination depend on humidity and temperature that supports the livelihood of micro-organisms. The presence of pets, plants, rodents, and insects will raise the level of biological contamination.

Sheath air

Sheath air is clean filtered air that surrounds the aerosol stream to prevent particulates from circulating or depositing within the optic chamber. Sheath air prevents contamination caused by build-up and deposits, improves response time by containing the sample, and improves maintenance by keeping the optic chamber clean. The nephelometer creates the sheath air by passing air through a zero filter before beginning the sample.

Global radiation balance

Nephelometers are also used in global warming studies, specifically measuring the global radiation balance. Three wavelength nephelometers fitted with a backscatter shutter can determine the amount of solar radiation that is reflected back into space through dust and particulate matter. This reflected light influences the amount of radiation reaching the earths lower atmosphere and warming the planet. A simple demonstration of this is found in www.aurora-nephelometer.com as seen below

Visibility

Nephelometers are also used for measurement of visibility with simple one-wavelength nephelometers used throughout the world by many EPAs. Nephelometers, through the measurement of light scattering, can determine visibility in distance through the application of a conversion factor called Koschmieder’s formula.

Turbidity units

  • Because optical properties depend on suspended particle size, a stable synthetic material called "Formazin" with uniform particle size is often used as a standard for calibration and reproducibility. The unit is called Formazin Turbidity Unit (FTU).
  • Nephelometric Turbidity Units (NTU) specified by United States Environmental Protection Agency
    United States Environmental Protection Agency
    The U.S. Environmental Protection Agency is an agency of the federal government of the United States charged with protecting human health and the environment, by writing and enforcing regulations based on laws passed by Congress...

     is a special case of FTU, where a white light source and certain geometrical properties of the measurement apparatus are specified. (Sometimes the alternate form "nephelos turbidity units" is used)
  • Formazin Nephelometric Units (FNU), prescribed for 9 measurements of turbidity in water treatment by ISO 7027, another special case of FTU with near infrared light (NIR) and 90º scatter.
  • Formazin Attenuation Units (FAU) specified by ISO 7027 for water treatment standards for turbidity measurements at 0°, also a special case of FTU.
  • Formazin Backscatter Units (FBU), not part of a standard, is the unit of optical backscatter detectors (OBS), measured at ca 180º, also a special case of FTU.
  • European Brewery Convention (EBC) turbidity units
  • Concentration Units (C.U.)
  • Optical Density (O.D.)
  • Jackson "Candle" Turbidity Units (JTU; an early measure)
  • Helms Units
  • American Society of Brewing Chemists (ASBC-FTU) turbidity units
  • Parts Per Million of standard substance, such as PPM/DE (Kieselguhr)
  • "Trübungseinheit/Formazin" (TE/F) a German standard, now replaced by the FNU unit.
  • diatomaceous earth ("ppm SiO2") an older standard, now obsolete


A more popular term for this instrument in water quality testing is a turbidimeter. However, there can be differences between models of turbidimeters, depending upon the arrangement (geometry
Geometry
Geometry arose as the field of knowledge dealing with spatial relationships. Geometry was one of the two fields of pre-modern mathematics, the other being the study of numbers ....

) of the source beam and the detector. A nephelometric turbidimeter always monitors light reflected off the particles and not attenuation
Attenuation
In physics, attenuation is the gradual loss in intensity of any kind of flux through a medium. For instance, sunlight is attenuated by dark glasses, X-rays are attenuated by lead, and light and sound are attenuated by water.In electrical engineering and telecommunications, attenuation affects the...

 due to cloudiness. In the United States
United States
The United States of America is a federal constitutional republic comprising fifty states and a federal district...

 environmental monitoring
Environmental monitoring
Environmental monitoring describes the processes and activities that need to take place to characterise and monitor the quality of the environment...

 the turbidity standard unit is called Nephelometric Turbidity Units (NTU), while the international standard unit is called Formazin Nephelometric Unit (FNU). The most generally applicable unit is Formazin Turbidity Unit (FTU), although different measurement methods can give quite different values as reported in FTU (see below).

Gas-phase nephelometers are also used to study the atmosphere
Atmosphere
An atmosphere is a layer of gases that may surround a material body of sufficient mass, and that is held in place by the gravity of the body. An atmosphere may be retained for a longer duration, if the gravity is high and the atmosphere's temperature is low...

. These can provide information on visibility
Visibility
In meteorology, visibility is a measure of the distance at which an object or light can be clearly discerned. It is reported within surface weather observations and METAR code either in meters or statute miles, depending upon the country. Visibility affects all forms of traffic: roads, sailing...

 and atmospheric albedo
Albedo
Albedo , or reflection coefficient, is the diffuse reflectivity or reflecting power of a surface. It is defined as the ratio of reflected radiation from the surface to incident radiation upon it...

. Gas-phase nephelometers are also used in the detection of smoke
Smoke
Smoke is a collection of airborne solid and liquid particulates and gases emitted when a material undergoes combustion or pyrolysis, together with the quantity of air that is entrained or otherwise mixed into the mass. It is commonly an unwanted by-product of fires , but may also be used for pest...

 & other particles of combustion
Combustion
Combustion or burning is the sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat and conversion of chemical species. The release of heat can result in the production of light in the form of either glowing or a flame...

. In such use, the apparatus is referred to as an aspirated smoke detector
Aspirated smoke detector
An aspirating smoke detector , consists of a central detection unit which draws air through a network of pipes to detect smoke. The sampling chamber is based on a nephelometer that is capable of detecting the presence of smoke particles suspended in air by detecting the light scattered by them in...

. These have the capability to detect extremely low particle concentrations (to 0.005%) and are therefore highly suitable to protecting sensitive or valuable electronic equipment, such as mainframe computer
Mainframe computer
Mainframes are powerful computers used primarily by corporate and governmental organizations for critical applications, bulk data processing such as census, industry and consumer statistics, enterprise resource planning, and financial transaction processing.The term originally referred to the...

s and telephone switches.
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