Lepidocrocite
Encyclopedia
Lepidocrocite also called esmeraldite or hydrohematite, is an iron oxide-hydroxide
Iron(III) oxide-hydroxide
A number of species are dubbed iron oxide-hydroxide. These chemicals are oxide-hydroxides of iron, and may occur in anhydrous or hydrated forms...

 mineral
Mineral
A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not...

. Lepidocrocite has an orthorhombic crystal structure
Crystal structure
In mineralogy and crystallography, crystal structure is a unique arrangement of atoms or molecules in a crystalline liquid or solid. A crystal structure is composed of a pattern, a set of atoms arranged in a particular way, and a lattice exhibiting long-range order and symmetry...

, a hardness
Mohs scale of mineral hardness
The Mohs scale of mineral hardness characterizes the scratch resistance of various minerals through the ability of a harder material to scratch a softer material. It was created in 1812 by the German geologist and mineralogist Friedrich Mohs and is one of several definitions of hardness in...

 of 5, specific gravity
Specific gravity
Specific gravity is the ratio of the density of a substance to the density of a reference substance. Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is nearly always water for...

 of 4, a submetallic luster
Lustre (mineralogy)
Lustre is a description of the way light interacts with the surface of a crystal, rock, or mineral. The word lustre traces its origins back to the Latin word lux, meaning "light", and generally implies radiance, gloss, or brilliance....

 and a yellow-brown streak. It is red to reddish brown and forms when iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

-containing substances rust
Rust
Rust is a general term for a series of iron oxides. In colloquial usage, the term is applied to red oxides, formed by the reaction of iron and oxygen in the presence of water or air moisture...

 underwater. Lepidocrocite is commonly found in the weathering
Weathering
Weathering is the breaking down of rocks, soils and minerals as well as artificial materials through contact with the Earth's atmosphere, biota and waters...

 of primary iron minerals and in iron ore deposits. It can be seen as rust scale inside old steel
Steel
Steel is an alloy that consists mostly of iron and has a carbon content between 0.2% and 2.1% by weight, depending on the grade. Carbon is the most common alloying material for iron, but various other alloying elements are used, such as manganese, chromium, vanadium, and tungsten...

 water pipe
Water pipe
Water pipes are pipes or tubes, frequently made of polyvinyl chloride , ductile iron, steel, cast iron, polypropylene, polyethylene, or copper, that carry pressurized and treated fresh water to buildings , as well as inside the building.-History:For many centuries, lead was the favoured material...

s and water tanks.

The structure of lepidocrocite is similar to the boehmite
Boehmite
Boehmite or Böhmite is an aluminium oxide hydroxide mineral, a component of the aluminium ore bauxite. It is dimorphous with diaspore. It crystallizes in the orthorhombic dipyramidal system and is typically massive in habit. It is white with tints of yellow, green, brown or red due to impurities...

 structure found in bauxite
Bauxite
Bauxite is an aluminium ore and is the main source of aluminium. This form of rock consists mostly of the minerals gibbsite Al3, boehmite γ-AlO, and diaspore α-AlO, in a mixture with the two iron oxides goethite and hematite, the clay mineral kaolinite, and small amounts of anatase TiO2...

 and consists of layered iron(III) oxide octahedra bonded by hydrogen bonding via hydroxide
Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and a hydrogen atom held together by a covalent bond, and carrying a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, as a ligand, a nucleophile, and a...

 layers. This relatively weakly bonded layering accounts for the scaley habit of the mineral.

It was first described in 1813 from the Zlaté Hory polymetallic ore
Ore
An ore is a type of rock that contains minerals with important elements including metals. The ores are extracted through mining; these are then refined to extract the valuable element....

 deposit in Moravia
Moravia
Moravia is a historical region in Central Europe in the east of the Czech Republic, and one of the former Czech lands, together with Bohemia and Silesia. It takes its name from the Morava River which rises in the northwest of the region...

, Czech Republic
Czech Republic
The Czech Republic is a landlocked country in Central Europe. The country is bordered by Poland to the northeast, Slovakia to the east, Austria to the south, and Germany to the west and northwest....

. The name is from the Greek
Greek language
Greek is an independent branch of the Indo-European family of languages. Native to the southern Balkans, it has the longest documented history of any Indo-European language, spanning 34 centuries of written records. Its writing system has been the Greek alphabet for the majority of its history;...

lipis for scale and krokis for fibre.
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