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Lacquer

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Lacquer



 
 
In a general sense, lacquer is a clear or coloured varnish
Varnish

Varnish is a Transparency , hard, protective finish or film primarily used in wood finishing but also for other materials. Varnish is traditionally a combination of a drying oil, a resin, and a Turpentine substitute or solvent....
 that dries by solvent evaporation and often a curing process as well that produces a hard, durable finish, in any sheen level from ultra matte
Matte

Matte may refer to:In film:* Matte , film and video technology* Matte painting, a process of creating sets used in film and video* Matte box, a camera accessory for controlling lens glare...
 to high gloss
Gloss (material appearance)

Gloss is an optical property, which is based on the interaction of light with physical characteristics of a surface. It is actually the ability of a surface to reflect light into the specular direction....
 and that can be further polished as required.

The term lacquer originates from the Portuguese word for lac
Lac

Lac is the scarlet resinous secretion of a number of species of insects, namely some of the species of the families Metatachardia, Laccifer, Tachordiella, Austrotacharidia, Afrotachardina, and Tachardina of the superfamily Coccoidea, of which the most commonly cultivated sp...
, a type of resin excreted from certain insects.






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Lacquerware Roundbox W Children
In a general sense, lacquer is a clear or coloured varnish
Varnish

Varnish is a Transparency , hard, protective finish or film primarily used in wood finishing but also for other materials. Varnish is traditionally a combination of a drying oil, a resin, and a Turpentine substitute or solvent....
 that dries by solvent evaporation and often a curing process as well that produces a hard, durable finish, in any sheen level from ultra matte
Matte

Matte may refer to:In film:* Matte , film and video technology* Matte painting, a process of creating sets used in film and video* Matte box, a camera accessory for controlling lens glare...
 to high gloss
Gloss (material appearance)

Gloss is an optical property, which is based on the interaction of light with physical characteristics of a surface. It is actually the ability of a surface to reflect light into the specular direction....
 and that can be further polished as required.

The term lacquer originates from the Portuguese word for lac
Lac

Lac is the scarlet resinous secretion of a number of species of insects, namely some of the species of the families Metatachardia, Laccifer, Tachordiella, Austrotacharidia, Afrotachardina, and Tachardina of the superfamily Coccoidea, of which the most commonly cultivated sp...
, a type of resin excreted from certain insects. Regardless, in modern usage, lac-based varnishes are referred to as shellac
Shellac

Shellac is a resin secreted by the female Laccifer lacca to form a cocoon, on trees in the forests of India and Thailand.. It is processed and sold as dry flakes , which are dissolved in denatured alcohol to make liquid shellac, which is used as a brush-on colorant, food glaze and wood finish much like a combination of stain and polyuretha...
, while lacquer refers to other polymers dissolved in volatile organic compound
Volatile organic compound

Volatile organic compounds are organic chemical compounds that have high enough vapor pressures under normal conditions to significantly vaporize and enter the atmosphere....
s (VOCs), such as nitrocellulose
Nitrocellulose

Nitrocellulose is a highly flammable compound formed by nitrating cellulose through exposure to nitric acid or another powerful nitrating agent....
, and later acrylic compounds dissolved in lacquer thinner, a mixture of several solvents typically containing butyl acetate
Butyl acetate

n-Butyl acetate, also known as butyl ethanoate, is an organic compound commonly used as a solvent in the production of lacquers and other products....
 and xylene
Xylene

The term xylene or xylol refers to a mixture of three aromatic hydrocarbon isomers which is used as a solvent in the printing, rubber, and leather industries....
 or toluene
Toluene

Toluene, also known as methylbenzene or phenylmethane, is a clear, Water -insoluble liquid with the typical smell of paint thinners, redolent of the sweet smell of the related compound benzene....
.

While both lacquer and shellac are traditional finishes, lacquer is more durable than shellac.

Urushiol-based lacquers

True lacquerwork is Chinese or Japanese in origin. According to Encyclopędia Britannica
Encyclopędia Britannica

The Encyclop?dia Britannica is a general English language encyclopedia published by Encyclop?dia Britannica, Inc., a privately held company....
, varnish resin derived from a tree indigenous to China, species Toxicodendron vernicifluum, commonly known as the varnish tree. The manufacturing process was introduced into Japan and remained secret for centuries. These lacquers produce very hard, durable finishes that are both beautiful and very resistant to damage by water, acid, alkali or abrasion. The active ingredient of the resin is urushiol
Urushiol

Urushiol is an organic oil toxin found in plants of the Linnaean taxonomy Anacardiaceae, especially Toxicodendron spp. . It causes an allergic skin rash on contact, known as urushiol-induced contact dermatitis....
, a mixture of various phenols suspended in water, plus a few proteins.

Urushiol
Urushiol

Urushiol is an organic oil toxin found in plants of the Linnaean taxonomy Anacardiaceae, especially Toxicodendron spp. . It causes an allergic skin rash on contact, known as urushiol-induced contact dermatitis....
-based lacquers differ from most others, being slow-drying, water-based, and set by oxidation and polymer
Polymer

A polymer is a large molecule composed of repeating structural units typically connected by covalent chemical bonds. While polymer in popular usage suggests plastic, the term actually refers to a large class of natural and synthetic materials with a variety of properties....
isation, rather than by evaporation
Evaporation

Evaporation is the slow vaporization of a liquid and the reverse of condensation. A type of phase transition, it is the process by which molecules in a liquid State of matter spontaneously become gaseous ....
 alone. In order for it to set properly it requires humidity and warm temperature. The phenols oxidize and polymerize under the action of an enzyme laccase, yielding a substrate that, upon proper evaporation of its water content, is hard and fairly resistant to mechanical stress. Lacquer skills became very highly developed in India and Asia, and many highly decorated pieces were produced. The process of lacquer application in India is different from China and Japan. There are two types of lacquer: one obtained from the Rhus tree and the other from an insect. In India the insect lac was once used from which a red dye was first extracted, later what was left of the insect was a grease that was used for lacquering objects. Insect lac was introduced to India from Persia (Iran). The fresh resin from the Rhus trees causes urushiol-induced contact dermatitis
Urushiol-induced contact dermatitis

Urushiol-induced contact dermatitis is the medical name given to allergy rashes produced by the oil urushiol, which is contained in various plants, including the plants of the genus Toxicodendron , as well as other plants in the family Anacardiaceae , and also unrelated plants such as Ginkgo biloba....
 and great care is required in its use. The Chinese treated the allergic reaction with shell-fish.

The contemporary theory held that from China, knowledge of lacquer technology was introduced to Korea
Korea

Korea is a geographic area composed of two sovereign countries, a civilization, and a former state situated on the Korean Peninsula in East Asia....
, and from there to Japan. It was believed that Japan had also been using lacquer from ancient times, but the systematic process of application was developed by the Chinese. With the discovery of lacquer ware in Japan dating back to Jomon period
Jomon period

The is the time in history of Japan from about 14th millennium BC to 5th century BC.The term "Jomon" means "cord-patterned" in Japanese. This refers to the markings made on clay vessels and figures using sticks with cords wrapped around them which are characteristic of the Jomon people....
, conflicting theories claim that technology may have been independently developed in Japan. Trade of lacquer objects traveled through various routes to the Middle East
Middle East

File:GreaterMiddleEast1.pngThe Middle East is a region that spans southwestern Asia, western Asia, and northeastern Africa. It has no clear boundaries, often used as a synonym to Near East, in opposition to Far East....
. Known applications of lacquer in China included coffins, plates, music instruments and furniture. Lacquer mixed with powdered cinnabar
Cinnabar

Cinnabar, sometimes written cinnabarite, is a name applied to red mercury sulfide , or native vermilion, the common ore of mercury . The name comes from the Greek language - "kinnabari" - used by Theophrastus, and was probably applied to several distinct substances....
 is used to produce the traditional red lacquerware from China.

Lacquer
The trees must be at least 10 years old before cutting to bleed the resin. It sets by a process called "aqua-polymerization", absorbing oxygen to set; placing in a humid environment (called "furo" or "muro" in Japanese, meaning "a bath" or "a room") allows it to absorb more oxygen from the evaporation of the water.

Lacquer-yielding trees in Thailand, Vietnam, Burma and Taiwan, called Thitsi, are slightly different; they do not contain urushiol, but similar substances called "laccol" or "thitsiol". The end result is similar but softer than the Chinese or Japanese lacquer. Unlike Japanese and Chinese Rhus verniciflua resin, Burmese lacquer does not cause allergic reactions; it sets slower, and is painted by craftsmen's hands without using brushes.

Raw lacquer can be "coloured" by the addition of small amounts of iron oxide
Iron oxide

Iron oxides are chemical compounds composed of iron and oxygen. Altogether, there are sixteen known iron oxides and oxyhydroxides....
s, giving red or black depending on the oxide. There is some evidence that its use is even older than 8,000 years from archeological digs in China. Later, pigments were added to make colours. It is used not only as a finish, but mixed with ground fired and unfired clays applied to a mould with layers of hemp cloth, it can produce objects without need for another core like wood. The process is called "kanshitsu" in Japan. Advanced decorative techniques using additional materials such as gold and silver powders and flakes ("makie") were refined to very high standards in Japan also after having been introduced from China. In the lacquering of the Chinese musical instrument, the guqin
Guqin

The is the modern name for a plucked seven-string List of traditional Chinese musical instruments of the zither family. It has been played since ancient times, and has traditionally been favored by scholars and literati as an instrument of great subtlety and refinement, as highlighted by the quote "a gentleman does not part with his qin'...
, the lacquer is mixed with deer horn powder (or ceramic powder) to give it more strength so it can stand up to the fingering.