Hydrogen anion
Encyclopedia
The hydrogen
anion is a negative
hydrogen ion
, H−. It is an important constituent of the atmosphere of star
s, such as the Sun
, where it is the dominant absorber of photon
s with energies in the range 0.75-4.0 eV
, ranging from the infrared
into the visible spectrum
(Rau 1999). It also occurs in the Earth's ionosphere
(Rau 1999).
Its existence was first proven theoretically by Hans Bethe
in 1929 (Bethe 1929). H− is unusual because it has no bound excited states, as was finally proven in 1977 (Hill 1977). It has been studied experimentally using particle accelerators (Bryant 1977).
Chemical compounds that formally contain a hydrogen anion are called hydride
s.
Hydrogen
Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...
anion is a negative
Electric charge
Electric charge is a physical property of matter that causes it to experience a force when near other electrically charged matter. Electric charge comes in two types, called positive and negative. Two positively charged substances, or objects, experience a mutual repulsive force, as do two...
hydrogen ion
Hydrogen ion
Hydrogen ion is recommended by IUPAC as a general term for all ions of hydrogen and its isotopes.Depending on the charge of the ion, two different classes can be distinguished: positively charged ions and negatively charged ions....
, H−. It is an important constituent of the atmosphere of star
Star
A star is a massive, luminous sphere of plasma held together by gravity. At the end of its lifetime, a star can also contain a proportion of degenerate matter. The nearest star to Earth is the Sun, which is the source of most of the energy on Earth...
s, such as the Sun
Sun
The Sun is the star at the center of the Solar System. It is almost perfectly spherical and consists of hot plasma interwoven with magnetic fields...
, where it is the dominant absorber of photon
Photon
In physics, a photon is an elementary particle, the quantum of the electromagnetic interaction and the basic unit of light and all other forms of electromagnetic radiation. It is also the force carrier for the electromagnetic force...
s with energies in the range 0.75-4.0 eV
Electronvolt
In physics, the electron volt is a unit of energy equal to approximately joule . By definition, it is equal to the amount of kinetic energy gained by a single unbound electron when it accelerates through an electric potential difference of one volt...
, ranging from the infrared
Infrared
Infrared light is electromagnetic radiation with a wavelength longer than that of visible light, measured from the nominal edge of visible red light at 0.74 micrometres , and extending conventionally to 300 µm...
into the visible spectrum
Visible spectrum
The visible spectrum is the portion of the electromagnetic spectrum that is visible to the human eye. Electromagnetic radiation in this range of wavelengths is called visible light or simply light. A typical human eye will respond to wavelengths from about 390 to 750 nm. In terms of...
(Rau 1999). It also occurs in the Earth's ionosphere
Ionosphere
The ionosphere is a part of the upper atmosphere, comprising portions of the mesosphere, thermosphere and exosphere, distinguished because it is ionized by solar radiation. It plays an important part in atmospheric electricity and forms the inner edge of the magnetosphere...
(Rau 1999).
Its existence was first proven theoretically by Hans Bethe
Hans Bethe
Hans Albrecht Bethe was a German-American nuclear physicist, and Nobel laureate in physics for his work on the theory of stellar nucleosynthesis. A versatile theoretical physicist, Bethe also made important contributions to quantum electrodynamics, nuclear physics, solid-state physics and...
in 1929 (Bethe 1929). H− is unusual because it has no bound excited states, as was finally proven in 1977 (Hill 1977). It has been studied experimentally using particle accelerators (Bryant 1977).
Chemical compounds that formally contain a hydrogen anion are called hydride
Hydride
In chemistry, a hydride is the anion of hydrogen, H−, or, more commonly, a compound in which one or more hydrogen centres have nucleophilic, reducing, or basic properties. In compounds that are regarded as hydrides, hydrogen is bonded to a more electropositive element or group...
s.
See also
- HydronHydron (chemistry)In chemistry, a hydron is the general name for a cationic form of atomic hydrogen : most commonly a "proton". However, hydron includes cations of hydrogen regardless of their isotopic composition: thus it refers collectively to protons , deuterons , and tritons...
(hydrogen cation) - HydroniumHydroniumIn chemistry, a hydronium ion is the cation , a type of oxonium ion produced by protonation of water. This cation is often used to represent the nature of the proton in aqueous solution, where the proton is highly solvated...
- ProtonProtonThe proton is a subatomic particle with the symbol or and a positive electric charge of 1 elementary charge. One or more protons are present in the nucleus of each atom, along with neutrons. The number of protons in each atom is its atomic number....
- Hydrogen ionHydrogen ionHydrogen ion is recommended by IUPAC as a general term for all ions of hydrogen and its isotopes.Depending on the charge of the ion, two different classes can be distinguished: positively charged ions and negatively charged ions....