Heulandite
Encyclopedia
Heulandite is the name of a series of tecto-silicate
Silicate minerals
The silicate minerals make up the largest and most important class of rock-forming minerals, constituting approximately 90 percent of the crust of the Earth. They are classified based on the structure of their silicate group...

 mineral
Mineral
A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not...

s of the zeolite
Zeolite
Zeolites are microporous, aluminosilicate minerals commonly used as commercial adsorbents. The term zeolite was originally coined in 1756 by Swedish mineralogist Axel Fredrik Cronstedt, who observed that upon rapidly heating the material stilbite, it produced large amounts of steam from water that...

 group. Prior to 1997, heulandite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association
International Mineralogical Association
The International Mineralogical Association is an international group of 38 national societies. The goal is to promote the science of mineralogy and to standardize the nomenclature of the 4000 plus known mineral species...

 changed it to a series name, with the mineral species being named:
  • heulandite-Ca
  • heulandite-Na
  • heulandite-K
  • heulandite-Sr
  • heulandite-Ba (described in 2002).

Heulandite-Ca, the most common of these, is a hydrous calcium and aluminium
Aluminium
Aluminium or aluminum is a silvery white member of the boron group of chemical elements. It has the symbol Al, and its atomic number is 13. It is not soluble in water under normal circumstances....

 silicate
Silicate
A silicate is a compound containing a silicon bearing anion. The great majority of silicates are oxides, but hexafluorosilicate and other anions are also included. This article focuses mainly on the Si-O anions. Silicates comprise the majority of the earth's crust, as well as the other...

, (Ca,Na)2-3Al3(Al,Si)2Si13O36·12H2O. Small amounts of sodium
Sodium
Sodium is a chemical element with the symbol Na and atomic number 11. It is a soft, silvery-white, highly reactive metal and is a member of the alkali metals; its only stable isotope is 23Na. It is an abundant element that exists in numerous minerals, most commonly as sodium chloride...

 and potassium
Potassium
Potassium is the chemical element with the symbol K and atomic number 19. Elemental potassium is a soft silvery-white alkali metal that oxidizes rapidly in air and is very reactive with water, generating sufficient heat to ignite the hydrogen emitted in the reaction.Potassium and sodium are...

 are usually present replacing part of the calcium. Strontium
Strontium
Strontium is a chemical element with the symbol Sr and the atomic number 38. An alkaline earth metal, strontium is a soft silver-white or yellowish metallic element that is highly reactive chemically. The metal turns yellow when exposed to air. It occurs naturally in the minerals celestine and...

 replaces calcium in the heulandite-Sr variety. The appropriate species name depends on the dominant element. The species are visually indistinguishable, and the series name heulandite is still used whenever testing has not been performed.

Crystallography and properties

Crystals are monoclinic. They may have a characteristic coffin-shaped habit, but may also form simple rhombic prisms. Frequently, a crust of fine crystals will form with only the ends of the rhombs visible, making the crystals look like wedges. They have a perfect cleavage parallel to the plane of symmetry, on which the lustre is markedly pearly; on other faces the lustre is of the vitreous type. The mineral is usually colourless or white, but may be orange, brown, yellow, brick-red, or green due to inclusion
Inclusion
Inclusion may refer to:- Metallurgy :*Inclusion , a type of metal casting defect*Inclusions in Aluminium Alloys, solid particles in liquid aluminium alloy- Social inclusion of persons :...

s of celadonite
Celadonite
Celadonite is a mica group mineral, a phyllosilicate of potassium, iron in both oxidation states, aluminium and hydroxide with formula: K[Si4O10]2....

. It varies from transparent to translucent. Isomorphous with heulandite is the strontium
Strontium
Strontium is a chemical element with the symbol Sr and the atomic number 38. An alkaline earth metal, strontium is a soft silver-white or yellowish metallic element that is highly reactive chemically. The metal turns yellow when exposed to air. It occurs naturally in the minerals celestine and...

 and barium
Barium
Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in Group 2, a soft silvery metallic alkaline earth metal. Barium is never found in nature in its pure form due to its reactivity with air. Its oxide is historically known as baryta but it reacts with...

 zeolite brewsterite
Brewsterite
Brewsterite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, brewsterite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named...

.

The Mohs
Mohs scale of mineral hardness
The Mohs scale of mineral hardness characterizes the scratch resistance of various minerals through the ability of a harder material to scratch a softer material. It was created in 1812 by the German geologist and mineralogist Friedrich Mohs and is one of several definitions of hardness in...

 hardness is 3-4, and the specific gravity 2.2. Heulandite is similar to stilbite
Stilbite
Stilbite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, stilbite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named:*...

. The two minerals may, however, be readily distinguished by the fact that in heulandite the acute positive bisectrix of the optic axes emerges perpendicular to the cleavage.

Discovery and occurrence

Heulandite was first separated from stilbite by August Breithaupt
August Breithaupt
Johann Friedrich August Breithaupt was a German mineralogist and professor at Freiberg Mining Academy in Freiberg, Saxony.-Biography:...

 in 1818, and named by him "euzeolite" (meaning beautiful zeolite); independently, in 1822, H. J. Brooke arrived at the same result, giving the name heulandite, after the mineral collector, Henry Heuland (1778–1856).

Heulandite occurs with stilbite and other zeolites in the amygdaloidal cavities of basalt
Basalt
Basalt is a common extrusive volcanic rock. It is usually grey to black and fine-grained due to rapid cooling of lava at the surface of a planet. It may be porphyritic containing larger crystals in a fine matrix, or vesicular, or frothy scoria. Unweathered basalt is black or grey...

ic volcanic rock
Volcanic rock
Volcanic rock is a rock formed from magma erupted from a volcano. In other words, it is an igneous rock of volcanic origin...

s, and occasionally in gneiss
Gneiss
Gneiss is a common and widely distributed type of rock formed by high-grade regional metamorphic processes from pre-existing formations that were originally either igneous or sedimentary rocks.-Etymology:...

 and hydrothermal veins.

Good specimens have been found in the basalts of Berufjord, near Djupivogr, in Iceland
Iceland
Iceland , described as the Republic of Iceland, is a Nordic and European island country in the North Atlantic Ocean, on the Mid-Atlantic Ridge. Iceland also refers to the main island of the country, which contains almost all the population and almost all the land area. The country has a population...

, the Faroe Islands
Faroe Islands
The Faroe Islands are an island group situated between the Norwegian Sea and the North Atlantic Ocean, approximately halfway between Scotland and Iceland. The Faroe Islands are a self-governing territory within the Kingdom of Denmark, along with Denmark proper and Greenland...

 and the Deccan Traps
Deccan Traps
The Deccan Traps are a large igneous province located on the Deccan Plateau of west-central India and one of the largest volcanic features on Earth. They consist of multiple layers of solidified flood basalt that together are more than thick and cover an area of and a volume of...

 of the Sahyadri Mountains of Maharashtra
Maharashtra
Maharashtra is a state located in India. It is the second most populous after Uttar Pradesh and third largest state by area in India...

 near Mumbai
Mumbai
Mumbai , formerly known as Bombay in English, is the capital of the Indian state of Maharashtra. It is the most populous city in India, and the fourth most populous city in the world, with a total metropolitan area population of approximately 20.5 million...

. Crystals of a brick-red colour are from Campsie Fells
Campsie Fells
The Campsie Fells are a range of hills in central Scotland, stretching east to west, from Denny Muir to Dumgoyne, in Stirlingshire. . The highest point in the range is Earl's Seat which is 578 m high...

 in Stirlingshire
Stirlingshire
Stirlingshire or the County of Stirling is a registration county of Scotland, based around Stirling, the former county town. It borders Perthshire to the north, Clackmannanshire and West Lothian to the east, Lanarkshire to the south, and Dunbartonshire to the south-west.Until 1975 it was a county...

 and the Fassa valley in Trentino. A variety known as beaumontite occurs as small yellow crystals on syenitic
Syenite
Syenite is a coarse-grained intrusive igneous rock of the same general composition as granite but with the quartz either absent or present in relatively small amounts Syenite is a coarse-grained intrusive igneous rock of the same general composition as granite but with the quartz either absent or...

 schist
Schist
The schists constitute a group of medium-grade metamorphic rocks, chiefly notable for the preponderance of lamellar minerals such as micas, chlorite, talc, hornblende, graphite, and others. Quartz often occurs in drawn-out grains to such an extent that a particular form called quartz schist is...

 near Baltimore
Baltimore
Baltimore is the largest independent city in the United States and the largest city and cultural center of the US state of Maryland. The city is located in central Maryland along the tidal portion of the Patapsco River, an arm of the Chesapeake Bay. Baltimore is sometimes referred to as Baltimore...

, Maryland
Maryland
Maryland is a U.S. state located in the Mid Atlantic region of the United States, bordering Virginia, West Virginia, and the District of Columbia to its south and west; Pennsylvania to its north; and Delaware to its east...

.
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