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Greek Fire

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Greek fire



 
 
Greek fire was a primitive incendiary
Incendiary device

Incendiary devices or incendiary bombs are bombs designed to start fires or destroy sensitive equipment using materials such as napalm, thermite, chlorine trifluoride, or white phosphorus incendiary....
 weapon
Weapon

A weapon is a tool used to apply or threaten to apply force for the purpose of hunting, attack or defense in combat, subduing enemy personnel, or to destroy enemy weapons, equipment and defensive structures....
 used by the Byzantine Empire
Byzantine Empire

Byzantine Empire and Eastern Roman Empire are conventional names used to describe the Roman Empire during the Middle Ages, centered on its capital of Constantinople....
. The Byzantines typically used it in naval battles to great effect as it could continue burning even on water. It provided a key technological advantage, and was responsible for many Byzantine military victories, and partly the reason for the Byzantine Empire
Byzantine Empire

Byzantine Empire and Eastern Roman Empire are conventional names used to describe the Roman Empire during the Middle Ages, centered on its capital of Constantinople....
 surviving as long as it did.






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Greekfire Madridskylitzes1
Greek fire was a primitive incendiary
Incendiary device

Incendiary devices or incendiary bombs are bombs designed to start fires or destroy sensitive equipment using materials such as napalm, thermite, chlorine trifluoride, or white phosphorus incendiary....
 weapon
Weapon

A weapon is a tool used to apply or threaten to apply force for the purpose of hunting, attack or defense in combat, subduing enemy personnel, or to destroy enemy weapons, equipment and defensive structures....
 used by the Byzantine Empire
Byzantine Empire

Byzantine Empire and Eastern Roman Empire are conventional names used to describe the Roman Empire during the Middle Ages, centered on its capital of Constantinople....
. The Byzantines typically used it in naval battles to great effect as it could continue burning even on water. It provided a key technological advantage, and was responsible for many Byzantine military victories, and partly the reason for the Byzantine Empire
Byzantine Empire

Byzantine Empire and Eastern Roman Empire are conventional names used to describe the Roman Empire during the Middle Ages, centered on its capital of Constantinople....
 surviving as long as it did. Medieval sources mention weapons sometimes referred to as "Greek fire" as being also used by Arab
Arab

An Arab is a person who Identity as such on linguistic or cultural grounds. The plural form, Arabs , refers to the Ethnocultural group at large....
s, Chinese
China

China is a Culture of China, an ancient civilization, and, depending on perspective, a national or multinational entity extending over a large area in East Asia....
, and Mongols
Mongols

The name Mongol specifies one or several ethnic groups, now mainly located in Mongolia, China, and Russia....
; however, these were most likely another incendiary weapon of a different composition and not Greek fire based on the original formula, which was a highly protected secret of the Byzantine Empire and not even discovered by the Latin Empire
Latin Empire

The Latin Empire or Latin Empire of Constantinople is the name given by historians to the Crusader state founded by the leaders of the Fourth Crusade on lands captured from the Byzantine Empire after their sack of Constantinople in 1204 and ended in 1261....
 or the Ottoman Empire
Ottoman Empire

The Ottoman Empire , also known by its contemporaries as the Turkish Empire or Turkey , was an empire that lasted from 1299?1923. It was Treaty of Lausanne by the Republic of Turkey, which was officially proclaimed on October 29, 1923....
. Whilst the real formula is not known, some of the ingredients may have included naphtha
Naphtha

Naphtha normally refers to a number of different flammable liquid mixtures of hydrocarbons, i.e. a distillation product from petroleum or coal tar boiling in a certain range and containing certain hydrocarbons, a broad term encompassing any volatile, flammable liquid hydrocarbon mixture....
, quicklime, sulfur
Sulfur

Sulfur or sulphur is the chemical element that has the atomic number 16. It is denoted with the symbol S. It is an abundant Valence non-metal....
, and niter
Niter

Niter or nitre is the mineral form of potassium nitrate, KNO3, also known as saltpeter or saltpetre . Historically, the term "nitre" ? cognate with "natrium", an old word for sodium ? has been very vaguely defined, and it has been applied to a variety of other minerals and chemical compounds, including sodium n...
.

Although the phrase "Greek fire" is general in English and most other languages (Greek being a notable exception), early sources used terms whose literal translation would be otherwise, such as "Byzantine fire", "Roman fire", "sea fire" (pyr thalàssion), "liquid fire
Liquid fire

Liquid fire is a term used to describe a number of things:In warfare:* Greek fire - ancient and medieval incendiary weapon* Early thermal weapons - used as an incendiary weapon...
" , or "artificial fire" (pyr skevastòn, a term used in the Byzantine military manuals
Byzantine military manuals

This article lists and briefly discusses the most important of a large number of treatises on military science produced in the Byzantine Empire during its thousand-year existence....
).

Origin

Incendiary and flaming weapons had been used in warfare for centuries prior to the invention of Greek fire, including a number of petroleum
Petroleum

Petroleum or crude oil is a naturally occurring, flammable liquid found in rock formations in the Earth consisting of a complex mixture of hydrocarbons of various molecular weights, plus other organic compounds....
- and bitumen-based mixtures; however, Greek fire was difficult to extinguish and could burn on water, making it a devastating invention. The first use of an incendiary chemical substance at sea by the Byzantines dates from the suppression of a revolt against the Emperor Anastasius I
Anastasius I (emperor)

Flavius Anastasius or Anastasius I was Byzantine Emperor from 11 April 491 until his death. He was born at Dyrrhachium not later than 430/431....
 in AD 513. According to the chronicler John Malalas
John Malalas

John Malalas or Ioannes Malalas was a , Byzantine Empire chronicler. He was born at Antioch....
, the Emperor called on a philosopher from Athens
Athens

Athens , the Capital and largest city of Greece, dominates the Attica periphery; as one of the List of cities by time of continuous habitation, its recorded history spans around 3,400 years....
 called Proclus, who invented a powder that ignited when exposed to the heat of the sun's rays.

However, Theophanes
Theophanes the Confessor

Saint Theophanes Confessor was a member of the Byzantine Empire aristocracy, who became a monk and chronicler. He is venerated on March 12 in the Roman Catholic Church and the Eastern Orthodox Church ....
 records that the concoction that would become known as Greek fire was invented c. 670 in Constantinople by Callinicus, an architect from Heliopolis
Baalbek

Baalbek is a town in the Bekaa Valley of Lebanon, altitude 1,170 m , situated east of the Litani River. It is famous for its exquisitely detailed yet monumentally scaled temple ruins of the Roman Empire period, when Baalbek, known as Heliopolis was one of the largest sanctuaries in the Empire....
 in the former province of Phoenice. The historian James Partington
J. R. Partington

James Riddick Partington was a United Kingdom chemist and historian of chemistry. He was Professor of Chemistry at Queen Mary, University of London from 1919 to 1951....
 thinks it likely that "Greek fire was really invented by chemists in Constantinople who had inherited the discoveries of the Alexandria
Alexandria

Alexandria , with a population of 4.1 million, is the second-largest city in Egypt, and is the country's largest seaport, serving about 80% of Egypt's imports and exports....
n chemical school".

Many accounts note that the fires it caused could not be put out by pouring water on the flames—on the contrary, the water served to intensify or spread them—suggesting that Greek fire may have been a thermite
Thermite

Thermite is a pyrotechnic composition of a metal powder and a metal oxide, which produces an aluminothermic reaction known as a thermite reaction....
-like reaction, probably involving a quicklime or similar compound. Others have posited a flammable liquid that floated on water, possibly a form of naphtha
Naphtha

Naphtha normally refers to a number of different flammable liquid mixtures of hydrocarbons, i.e. a distillation product from petroleum or coal tar boiling in a certain range and containing certain hydrocarbons, a broad term encompassing any volatile, flammable liquid hydrocarbon mixture....
 or another low-density liquid hydrocarbon, as petroleum was known to Eastern chemists long before its use became widespread in the 1800s. Yet another possibility could have been highly heated (200°C) wax and olive oil
Olive oil

Olive oil is a fruit oil obtained from the olive , a traditional tree crop of the Mediterranean Basin. The wild olive tree originated in Anatolia and spread from there as far as southern Africa, Australia, Japan and China....
 mixture.

Use

In its earliest uses, it was applied onto enemy forces by firing a burning cloth-wrapped ball, perhaps containing a flask, using a form of light catapult
Catapult

A catapult is any one of a number of non-handheld mechanical devices used to throw a projectile a great distance without the aid of an explosive substance?particularly various types of ancient and medieval siege engines....
, most probably a seaborne variant of the Roman light catapult or onager
Onager (siege weapon)

The onager was a post-classical Roman Empire siege engine, which derived its name from the kicking action of the machine, similar to that of an onager ....
. These were capable of hurling light loads (around to ) a distance of  – . Later technological improvements in machining
Machining

Conventional machining, one of the most important material removal methods, is a collection of material-working processes in which power-driven machine tools, such as Lathe s, milling machines, and drill presses are used with a sharp cutting tool to mechanically cut the material to achieve the desired geometry....
 technology enabled the devising of a pump mechanism discharging a stream of burning fluid
Fluid

A fluid is defined as a substance that continually deforms under an applied shear stress. All liquids and all gases are fluids. Fluids are a subset of the Phase and include liquids, gas, Plasma physics and, to some extent, plasticity ....
 (flame thrower) at close ranges, devastating wooden ships in naval warfare
Naval warfare

Naval warfare is combat in and on seas, oceans, or any other major bodies of water such as large lakes and wide rivers....
 and also very effective on land as a counter-force suppression weapon used on besieging forces. There are many accounts of the Byzantine Empire
Byzantine Empire

Byzantine Empire and Eastern Roman Empire are conventional names used to describe the Roman Empire during the Middle Ages, centered on its capital of Constantinople....
 driving off attacks on the walls using the secret formula.

Link to Byzantine victories

Greek fire was largely responsible for many Byzantine military victories and partly the reason the Eastern Roman Empire survived as long as it did. It was particularly helpful near the end of the empire's life when there were not enough inhabitants to defend its territories effectively. It was first used to repel the Muslim Arabs at the first Rus'-Byzantine War]] of 941 and against the Venetians during the [[Fourth Crusade]] (1202–1204). It quickly became one of the most feared weapons of the medieval world. The sight of any sort of [[siphon]], whether it was used for Greek fire or not, was often enough to demoralize an enemy. However, Greek fire was very hard to control, and it would often accidentally set Byzantine ships ablaze. The early 20th-century historian C.W.C. Oman paraphrases an account by the Byzantine historian [[Anna Komnene]] (1083–1153)—daughter of [[Alexios I Komnenos]]—about a sea battle between the [[Pisa]]ns and Byzantines near [[Rhodes]] in the year 1103:

[Alexios] had fixed to the bows of each of his galleys a tube ending in the head of a lion or other beast wrought in brass or iron, 'so that the animals might seem to vomit flames'. The fleet came up with the Pisans between Rhodes and Patara, but as its vessels were pursuing them with too great zeal it could not attack as a single body. The first to reach the enemy was the Byzantine admiral Landulph, who shot off his fire too hastily, missed his mark and accomplished nothing. But Count Eleemon, who was the next to close, had better fortune; he rammed the stern of a Pisan vessel, so that the bows of his ship got stuck in its steering-oar tackle. Then, shooting forth the fire, he set it ablaze, after which he pushed off and successfully discharged his tube into three other vessels, all of which were soon in flames. The Pisans then fled in disorder, 'having had no previous knowledge of the device, and wondering that fire, which usually burns upwards, could be directed downwards or to either hand, at the will of the engineer who discharged it'.


That the Greek fire was a liquid, and not merely an inflammable substance attached to ordinary missiles after the manner of fire-arrows, is quite clear from the fact that Leo [VI the Wise] proposes to cast it on the enemy in fragile earthen vessels which may break and allow the material to run about—as also from the name pyr enygron (p?? ???????) or "liquid fire" which Anna uses for it.

The effectiveness of Greek fire was indisputable; however, it was mainly effective under certain circumstances. For instance, it was less effective in the open sea than in narrow sea passages. Greek fire should not be considered an invention that solved all the maritime problems of the Byzantine Empire. Naval war continued to be based on the traditional art of maritime strategy, to which Greek fire added an effective weapon for the Byzantines.

Manufacture

The ingredients, process of manufacture, and usage were very carefully guarded military secrets. Indeed, the 10th-century emperor Constantine VII Porphyrogenitus cautions his son in his book De administrando imperio
De Administrando Imperio

De Administrando Imperio is the commonly used Latin title of a scholarly work written in Greek language, by the 10th-century Byzantine emperor Constantine VII....
 never to give away three things to a foreigner: a crown, the hand of a purple-born princess, and the secret of "liquid fire". So strict was the secrecy that it remains a source of speculation to this day. The only information we have is indirect, or through secondary sources like Anna Comnena:
"This fire is made by the following arts. From the pines and the certain such evergreen trees inflammable resin is collected. This is rubbed with sulfur and put into tubes of reed, and is blowing by men using it with violent and continuous breath. Then in this manner it meets the fire on the tip and catches light and falls like a fiery whirlwind on the faces of the enemies."
Speculations as to its composition include:

  • petroleum
    Petroleum

    Petroleum or crude oil is a naturally occurring, flammable liquid found in rock formations in the Earth consisting of a complex mixture of hydrocarbons of various molecular weights, plus other organic compounds....
    , niter
    Niter

    Niter or nitre is the mineral form of potassium nitrate, KNO3, also known as saltpeter or saltpetre . Historically, the term "nitre" ? cognate with "natrium", an old word for sodium ? has been very vaguely defined, and it has been applied to a variety of other minerals and chemical compounds, including sodium n...
    , sulfur
    Sulfur

    Sulfur or sulphur is the chemical element that has the atomic number 16. It is denoted with the symbol S. It is an abundant Valence non-metal....
    ;
  • naphtha
    Naphtha

    Naphtha normally refers to a number of different flammable liquid mixtures of hydrocarbons, i.e. a distillation product from petroleum or coal tar boiling in a certain range and containing certain hydrocarbons, a broad term encompassing any volatile, flammable liquid hydrocarbon mixture....
    , quicklime, sulfur
    Sulfur

    Sulfur or sulphur is the chemical element that has the atomic number 16. It is denoted with the symbol S. It is an abundant Valence non-metal....
    ;
  • phosphorus
    Phosphorus

    Phosphorus is the chemical element that has the symbol P and atomic number 15. The name comes from the and . A Valency nonmetal of the nitrogen group, phosphorus is commonly found in inorganic phosphate minerals....
     and saltpeter
    Potassium nitrate

    Potassium nitrate is a chemical compound with the chemical formula PotassiumNitrogenOxygen3. A naturally occurring mineral source of nitrogen, KNO3 constitutes a critical oxidation component of black powder/gunpowder....
    .


It is not clear if the operator ignited the mixture with a flame as it emerged from the syringe or if it ignited spontaneously on contact with water or air. If the latter is the case, it is possible that the active ingredient was calcium phosphide
Calcium phosphide

Calcium phosphide is a chemical that has uses in incendiary bombs. It has the appearance of red-brown crystalline powder or grey lumps, with melting point of 1600 ?C....
, made by heating lime, bones, and charcoal. On contact with water, calcium phosphide releases phosphine
Phosphine

Phosphine is the common name for phosphorus trihydride , also known by the IUPAC name phosphane and, occasionally, phosphamine....
, which ignites spontaneously. The reaction of quicklime with water also creates enough heat to ignite hydrocarbons, especially if an oxidizer such as saltpeter is present. However, Greek fire was also used on land.

These ingredients were apparently heated in a cauldron
Cauldron

A cauldron or caldron is a large metal Cooking pot for cooking and/or boiling over an open fire, with a large mouth and frequently with an arc-shaped hanger....
 and then pumped out through a siphon
Siphon

A siphon is a continuous tube that allows liquid to drain from a reservoir through an intermediate point that is higher, or lower, than the reservoir, the flow being driven only by the difference in hydrostatic pressure without any need for pumping....
 or large syringe
Syringe

A syringe is a simple piston pump consisting of a plunger that fits tightly in a tube. The plunger can be pulled and pushed along inside a cylindrical tube , allowing the syringe to take in and expel a liquid or gas through an orifice at the open end of the tube....
 (handled by a specialist known as siphonarios or siphonator) mounted on the bow of the ship. Such a ship was herself called a siphonophoros dromon
Dromon

The dromons were the most important warships of the Byzantine navy from the 6th to 12th centuries AD. They were indirectly developed from the ancient trireme and were usually propelled by both oar and sail, a configuration that had been used by navies in the Mediterranean Sea for centuries....
. Larger vessels could also have two more siphons, one on each side. Greek fire could also be used in hand grenades made of earthenware vessels. If a pyrophoric reaction was involved, perhaps these grenades contained chambers for the fluids, which mixed and ignited when the vessel broke on impact with the target.

Testimony

The medieval text The Rise of Gawain, Nephew of Arthur
The Rise of Gawain, Nephew of Arthur

The Rise of Gawain, Nephew of Arthur is an anonymous Medieval Latin romance dating to the 12th or 13th century. An Arthurian legend tale, it describes the birth, boyhood deeds, and early adventures of King Arthur's nephew Gawain....
 contains one of the earliest European references to the processing and projection of Greek fire. The unusual description mixes magic and folklore into the process of creating the substance, but would have created a working compound similar to napalm
Napalm

Napalm is the name given to any of a number of flammable liquids used in warfare, often jellied gasoline. Napalm is actually the thickener in such liquids, which when mixed with gasoline makes a sticky incendiary gel....
.

The Memoirs of Jean de Joinville
Jean de Joinville

Jean de Joinville was one of the great chroniclers of Middle Ages France.Son of Simon de Joinville and Beatrice d'Auxonne, he belonged to a great noble family from Champagne....
, a 13th-century French nobleman, include these observations of a weapon similar to Greek fire during the Seventh Crusade
Seventh Crusade

The Seventh Crusade was a crusade led by Louis IX of France from 1248 to 1254. Approximately 50,000 gold bezants was paid in ransom for King Louis who, along with thousands of his troops, were captured and defeated by the Egyptian army led by the Ayyubid Sultan Al-Muazzam Turanshah supported by the Bahri dynasty Mamluks led by Faris ad-Din A...
:

It happened one night, whilst we were keeping night-watch over the tortoise-towers, that they brought up against us an engine called a perronel, (which they had not done before) and filled the sling

Sling (weapon)

A sling is a projectile weapon typically used to throw a blunt projectile such as a stone. It is also known as the shepherd's sling.A sling has a small cradle or pouch in the middle of two lengths of cord....
 of the engine with Greek fire. When that good knight, Lord Walter of Cureil, who was with me, saw this, he spoke to us as follows: "Sirs, we are in the greatest peril that we have ever yet been in. For, if they set fire to our turrets and shelters, we are lost and burnt; and if, again, we desert our defences which have been entrusted to us, we are disgraced; so none can deliver us from this peril save God alone. My opinion and advice therefore is: that every time they hurl the fire at us, we go down on our elbows and knees, and beseech Our Lord to save us from this danger."



So soon as they flung the first shot, we went down on our elbows and knees, as he had instructed us; and their first shot passed between the two turrets, and lodged just in front of us, where they had been raising the dam. Our firemen were all ready to put out the fire; and the Saracens, not being able to aim straight at them, on account of the two pent-house wings which the King had made, shot straight up into the clouds, so that the fire-darts fell right on top of them.



This was the fashion of the Greek fire: it came on as broad in front as a vinegar cask, and the tail of fire that trailed behind it was as big as a great spear; and it made such a noise as it came, that it sounded like the thunder of heaven. It looked like a dragon flying through the air. Such a bright light did it cast, that one could see all over the camp as though it were day, by reason of the great mass of fire, and the brilliance of the light that it shed.



Thrice that night they hurled the Greek fire at us, and four times shot it from the tourniquet crossbow.



See also

  • Flamethrower
    Flamethrower

    A flamethrower is a mechanical device designed to project a long controllable stream of fire.Some flamethrowers project a stream of ignited liquid fuel; some project a long Liquefied petroleum gas flame....
  • Napalm
    Napalm

    Napalm is the name given to any of a number of flammable liquids used in warfare, often jellied gasoline. Napalm is actually the thickener in such liquids, which when mixed with gasoline makes a sticky incendiary gel....
  • Byzantine navy
    Byzantine navy

    The Byzantine navy comprised the navy of the Byzantine Empire. Like the empire it served, it developed directly from its earlier Roman Navy, but in comparison with its precursor played a far greater role in the defense and survival of the state....
  • Early thermal weapons


External links

  • at LoveToKnow 1911
  • . Wired Blog. December 29, 2006.
  • . By Richard Groller.