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Gadolinium
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Gadolinium is a chemical element that has the symbol Gd and atomic number 64.
Characteristics Gadolinium is a silvery-white, malleable and ductile rare-earth metal with a metallic lustre. It crystallizes in hexagonal, close-packed alpha form at room temperature, but, when heated to 1508 K or more, it transforms into its beta form, which has a body-centered cubic structure.
Unlike other rare earth elements, gadolinium is relatively stable in dry air.

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Encyclopedia
Gadolinium is a chemical element that has the symbol Gd and atomic number 64.
Characteristics Gadolinium is a silvery-white, malleable and ductile rare-earth metal with a metallic lustre. It crystallizes in hexagonal, close-packed alpha form at room temperature, but, when heated to 1508 K or more, it transforms into its beta form, which has a body-centered cubic structure.
Unlike other rare earth elements, gadolinium is relatively stable in dry air. However, it tarnishes quickly in moist air, forming a loosely-adhering oxide which spalls off, exposing more surface to oxidation. Gadolinium reacts slowly with water, and is soluble in dilute acids.
Gadolinium-157 has the highest thermal neutron capture cross-section of any known nuclide with the exception of xenon-135, 49,000 barns, but it also has a fast burn-out rate, limiting its usefulness as a nuclear control rod material.
Gadolinium is strongly paramagnetic at room temperature, and exhibits ferromagnetic properties below room temperature.
Gadolinium demonstrates a magnetocaloric effect whereby its temperature increases when it enters a magnetic field and decreases when it leaves the magnetic field. The effect is considerably stronger for the gadolinium alloy Gd5(Si2Ge2)
.
Applications
Gadolinium is used for making gadolinium yttrium garnets, which have microwave applications, and gadolinium compounds are used for making phosphors for colour TV tubes. Gadolinium is also used for manufacturing compact discs and computer memory.
Gadolinium is used in nuclear marine propulsion systems as a burnable poison. Gadolinium is also used as a secondary, emergency shut-down measure in some nuclear reactors, particularly of the CANDU type.
Gadolinium also possesses unusual metallurgic properties, with as little as 1% of gadolinium improving the workability and resistance of iron, chromium, and related alloys to high temperatures and oxidation.
Because of their paramagnetic properties, solutions of organic gadolinium complexes and gadolinium compounds are used as intravenous MRI contrast agent to enhance images in medical magnetic resonance imaging. Magnevist is the most widespread example.
Besides MRI, gadolinium (Gd) is also used in other imaging. In X-ray, gadolinium is contained in the phosphor layer, suspending in a polymer matrix at the detector. Terbium-doped gadolinium oxysulfide (Gd2O2S: Tb) at the phosphor layer is to convert the X-rays releasing from the source into light. Gd can emit at 540nm (green light spectrum = 520 – 570nm), which is very useful for enhancing the imaging quality of the X-ray that is exposed to the photographic film. Beside Gd's spectrum range, the compound also has a K-edge at 50 kiloelectronVolts (keV), which means its absorption of X-ray through photoelectric interactions is great. The energy conversion of Gd is up to 20%, which means, one-fifth of the X-ray striking on the phosphor layer can be converted into light photons.
Gadolinium oxyorthosilicate (Gd2SiO5, GSO; usually doped by 0.1-1% of Ce) is a single crystal that is used as a scintillator in medical imaging such as Positron Emission Tomography (PET) or for detecting neutrons.
Gadolinium gallium garnet (Gd3Ga5O12) is a material with good optical properties, and is used in fabrication of various optical components and as substrate material for magneto–optical films.
In the future, gadolinium ethyl sulfate, which has extremely low noise characteristics, may be used in masers. Furthermore, gadolinium's high magnetic moment and low Curie temperature (which lies just at room temperature) suggest applications as a magnetic component for sensing hot and cold.
Due to extremely high neutron cross-section of gadolinium, this element is very effective for use with neutron radiography.
History
In 1880, Swiss chemist Jean Charles Galissard de Marignac observed spectroscopic lines due to gadolinium in samples of didymium and gadolinite; French chemist Paul Émile Lecoq de Boisbaudran separated gadolinia, the oxide of Gadolinium, from Mosander's yttria in 1886. The element itself was isolated only recently.
Gadolinium, like the mineral gadolinite, is named after Finnish chemist and geologist Johan Gadolin.
In older literature, the natural form of the element is often called an earth, meaning that the element came from Earth. In fact, gadolinium is the element that comes from the earth, gadolinia. Earths are compounds of the element and one or more other elements. The two most common combining-elements are oxygen and sulfur. For example, gadolinia contains gadolinium oxide (Gd2O3).
Biological role
Gadolinium has no known native biological role, but in research on biological systems it has a few roles. It is used as a component of MRI contrast agents, as, in the 3+ oxidation state, the metal has 7 unpaired f electrons. This causes water around the contrast agent to relax quickly, enhancing the quality of the MRI scan. Second, as a member of the lanthanides, it is used in various ion channel electrophysiology experiments, where it is used to block sodium leak channels, as well as to stretch activated ion channels.
Gadolinium-based contrast agents are dangerous in patients with kidney disease. The contrast agent is normally chelated as it is expected to pass through the body quickly. In patients with kidney disease, the excretion is slower and the gadolinium becomes unbound, causing serious health issues.
Occurrence
Gadolinium is never found in nature as the free element, but is contained in many rare minerals such as monazite and bastnäsite. It occurs only in trace amounts in the mineral gadolinite, which was also named after Johan Gadolin. Today, it is prepared by ion exchange and solvent extraction techniques, or by the reduction of its anhydrous fluoride with metallic calcium.
Value In 1994, the cost of gadolinium was about US$ 0.12 per gram, and it has only increased in value by about US$ 0.01 per gram since then.:
1994.....$0.121 per gram ( or $55 per pound)
1995.....$0.121 per gram ( or $55 per pound)
1996.....$0.115 per gram (or $115 per kilogram)
1997.....$0.115 per gram (or $115 per kilogram)
1998.....$0.115 per gram (or $115 per kilogram)
1999.....$0.115 per gram (or $115 per kilogram)
2000.....$0.130 per gram (or $130 per kilogram)
2001.....$0.130 per gram (or $130 per kilogram)
2002.....$0.130 per gram (or $130 per kilogram)
2003.....$0.130 per gram (or $130 per kilogram)
2004.....$0.130 per gram (or $130 per kilogram)
2005.....$0.130 per gram (or $130 per kilogram)
Compounds
Compounds of gadolinium include:
See also gadolinium compounds.
Isotopes Naturally occurring gadolinium is composed of 6 stable isotopes, 154Gd, 155Gd, 156Gd, 157Gd, 158Gd and 160Gd, and 1 radioisotope, 152Gd, with 158Gd being the most abundant (24.84% natural abundance). The predicted double beta decay of 160Gd has never been observed (only lower limit on its half-life of more than 1.3×1021 years has been set experimentally ).
Twenty nine radioisotopes have been characterized, with the most stable being alpha-decaying 152Gd (naturally occurring) with a half-life of 1.08×1014 years, and 150Gd with a half-life of 1.79×106 years. All of the remaining radioactive isotopes have half-lives less than 74.7 years. The majority of these have half-lives less than 24.6 seconds. Gadolinium isotopes have 4 metastable isomers, with the most stable being 143mGd (T½=110 seconds), 145mGd (T½=85 seconds) and 141mGd (T½=24.5 seconds).
The primary decay mode at atomic masses lower than the most abundant stable isotope, 158Gd, is electron capture, and the primary mode at higher atomic masses is beta decay. The primary decay products for isotopes of weights lower than 158Gd are the element Eu (europium) isotopes and the primary products at higher weights are the element Tb (terbium) isotopes.
Gadolinium-153 has a half-life of 240.4±10 days and emits gamma radiation with strong peaks at 41 keV and 102 keV. It is used as a gamma ray source in X-ray absorptiometry or bone density gauges for osteoporosis screening, and in the Lixiscope portable X-ray imaging system.
Precautions
As with the other lanthanides, gadolinium compounds are of low to moderate toxicity, although their toxicity has not been investigated in detail. Also, in patients with renal failure or other pro-inflammatory conditions, there is data associating its use with development of nephrogenic fibrosing dermopathy as a side effect of gadolinium chelates used as a contrast agent for MRI examinations.
General references
External links
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