Fulminic acid
Encyclopedia
Fulminic acid is a compound with a molecular formula HCNO. This substance was discovered in 1824 by Justus von Liebig
Justus von Liebig
Justus von Liebig was a German chemist who made major contributions to agricultural and biological chemistry, and worked on the organization of organic chemistry. As a professor, he devised the modern laboratory-oriented teaching method, and for such innovations, he is regarded as one of the...

. It is an organic acid and an isomer
Isomer
In chemistry, isomers are compounds with the same molecular formula but different structural formulas. Isomers do not necessarily share similar properties, unless they also have the same functional groups. There are many different classes of isomers, like stereoisomers, enantiomers, geometrical...

 of isocyanic acid
Isocyanic acid
Isocyanic acid is an inorganic compound with the formula HNCO, discovered in 1830 by Liebig and Wöhler. This colourless substance is volatile and poisonous, with a boiling point of 23.5 °C...

, discovered one year later by Friedrich Woehler.

Fulminic acid and its salts (fulminate
Fulminate
Fulminates are chemical compounds which include the fulminate ion. The fulminate ion, is a pseudohalic ion, acting like a halogen with its charge and reactivity. Due to the instability of the ion, fulminate salts are friction-sensitive explosives. The best known is mercury fulminate, which has...

s), for instance mercury fulminate, are very dangerous, and are often used as detonators for other explosive materials, and are examples of primary explosives. The vapors also are toxic.
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