Frederick Thomas Trouton FRS (24 November 1863 – 21 September 1922) was an Irish
physicistPhysics is a natural science that involves the study of matter and its motion through spacetime, along with related concepts such as energy and force. More broadly, it is the general analysis of nature, conducted in order to understand how the universe behaves.Physics is one of the oldest academic...
known for
Trouton's RuleTrouton’s rule states that the entropy of vaporization is almost the same value, about 87–88 J K−1 mol−1, for various kinds of liquids. The entropy of vaporization is defined as the ratio between the enthalpy of vaporization and the boiling temperature...
and experiments to detect the Earth's motion through the
luminiferous aetherIn the late 19th century, luminiferous aether or ether, meaning light-bearing aether, was the term used to describe a medium for the propagation of light....
.
Life and work
Trouton was born in
Dublin on 24 November 1863, the youngest son of the wealthy and prominent Thomas Trouton. He attended
Royal School DungannonThe Royal School is a school located in Dungannon, County Tyrone, Northern Ireland. It was one of a number of 'free schools' created by James I in 1608 to provide an education to the sons of local merchants and farmers during the plantation of Ulster. Originally setup in Mountjoy near Lough Neagh...
and went on to
Trinity College, DublinTrinity College, Dublin , formally known as the College of the Holy and Undivided Trinity of Queen Elizabeth near Dublin, was founded in 1592 by letters patent from Queen Elizabeth I as the "mother of a university", Extracts from Letters Patent of Elizabeth I, 1592: "...we...found and...
in 1884, where he studied engineering and physical science. While still an undergraduate student, Trouton observed a relationship between
boiling pointsBoiling Points is a prank reality television show, much like the format used on Candid Camera. It is broadcast on MTV in the United States. In each half-hour episode, annoying situations are set up and deliberately inflicted on one or more young adults who are unaware that they are being tested...
and
energies of vaporizationLatent heat is the heat released or absorbed by a chemical substance or a thermodynamic system during a process that occurs without a change in temperature. A typical example is a change of state of matter, meaning a phase transition such as the melting of ice or the boiling of water. The term was...
s, which he presented in two short papers. He found the change of entropy per mole for vaporisation at a boiling point is constant, or expressed mathematically ΔS
m,vap = 10.5 R (where R is the ideal gas constant). This became known as
Trouton's RuleTrouton’s rule states that the entropy of vaporization is almost the same value, about 87–88 J K−1 mol−1, for various kinds of liquids. The entropy of vaporization is defined as the ratio between the enthalpy of vaporization and the boiling temperature...
and, despite having some exceptions, is used to estimate the enthalpy of vaporization of liquids whose boiling points are known. Trouton himself belittled his discovery as it was merely the result of an afternoon's manipulation of data from a book of tables. Before graduating he also took a leading role in
surveyingSee Also: Public Land Survey SystemSurveying or land surveying is the technique, profession, and science of accurately determining the terrestrial or three-dimensional position of points and the distances and angles between them...
for a railway.
Trouton graduated
M.A.A Master of Arts from the Latin Magister Artium, is a type of Master's degree awarded by universities in many countries. The M.A. is usually contrasted with the M.S. or M.Sc. degrees...
and
D. ScDoctor of Science , usually abbreviated Sc.D., D.Sc., S.D. or Dr.Sc., is an academic research degree awarded in a number of countries throughout the world. In some countries Doctor of Science is the name used for the standard doctorate in the sciences, elsewhere the Sc.D...
in 1884, and was immediately appointed assistant to the professor of experimental physics,
George FitzGeraldGeorge Francis FitzGerald was an Irish professor of "natural and experimental philosophy" at Trinity College in Dublin, Ireland, during the last quarter of the 19th century....
. They colloborated on many experiments and became good friends; FitzGerald's influence can be seen in a lot of Trouton's earlier work.
He was elected a Fellow of the Royal Society in June 1897. His application citation read: "
Discovered the law connecting the extent head of vaporisation and molecular weights of bodies known as "Trouton's law" and experimentally determined the directions of vibration of electric and inaquatic force in plane polarised light. He has made other important observations on the phase of secondary waves and on the influence of the size of the reflector in Hertz's equipment."
A 1902 appointment as Quain Professor of Physics at
University College LondonUniversity College London is a public research university located in London, United Kingdom and the oldest and largest constituent college of the federal University of London...
led to a 12-year career of experimental physics, including work on the Trouton-Rankine experiment. He received an OBE in 1918.
Trouton married Anne Maria Fowler in 1887 and they had four sons and three daughters. Their two eldest sons, Eric and Desmond, were killed in
World War IWorld War I , which was predominantly called the World War or the Great War from its occurrence until 1939, and the First World War or World War I thereafter, was a major war centred in Europe that began on 28 July 1914 and lasted until 11 November 1918...
. He was severely ill in 1912, and an operation in 1914 left him paralysed in the lower limbs and caused his retirement. Despite this, he retained the wit and charm he was known for. After retiring, Trouton lived in
TilfordTilford is a small village about two miles south of Farnham in Surrey, England. It lies within the Surrey Hills Area of Outstanding Natural Beauty- History :The name "Tilford" is probably derived from "Tila's ford" or "Tilla's ford"....
,
SurreySurrey is a county in the South East of England and is one of the Home Counties. The county borders Greater London, Kent, East Sussex, West Sussex, Hampshire and Berkshire. The historic county town is Guildford. Surrey County Council sits at Kingston upon Thames, although this has been part of...
, and then
DowneDowne is a village in the London Borough of Bromley in London, UK.Downe is south west of Orpington and south east of Charing Cross. Downe lies in a wooded valley, and much of the centre of the village is unchanged; the former village school now acts as the village hall.-Darwin:Charles Darwin...
in
KentKent is a county in southeast England, and is one of the home counties. It borders East Sussex, Surrey and Greater London and has a defined boundary with Essex in the middle of the Thames Estuary. The ceremonial county boundaries of Kent include the shire county of Kent and the unitary borough of...
where he died on 21 September 1922.
See also
- Trouton's Rule
Trouton’s rule states that the entropy of vaporization is almost the same value, about 87–88 J K−1 mol−1, for various kinds of liquids. The entropy of vaporization is defined as the ratio between the enthalpy of vaporization and the boiling temperature...
- Trouton-Rankine Experiment
- Trouton-Noble Experiment
The Trouton–Noble experiment attempted to detect motion of the Earth through the luminiferous aether, and was conducted in 1901–1903 by Frederick Thomas Trouton and H. R. Noble...
External links