Faraday's ice pail experiment
Encyclopedia
Faraday's ice pail experiment is a simple electrostatics
Electrostatics
Electrostatics is the branch of physics that deals with the phenomena and properties of stationary or slow-moving electric charges....

 experiment performed in 1843 by British scientist Michael Faraday
Michael Faraday
Michael Faraday, FRS was an English chemist and physicist who contributed to the fields of electromagnetism and electrochemistry....

 that demonstrates the effect of electrostatic induction
Electrostatic induction
Electrostatic induction is a redistribution of electrical charge in an object, caused by the influence of nearby charges. Induction was discovered by British scientist John Canton in 1753 and Swedish professor Johan Carl Wilcke in 1762. Electrostatic generators, such as the Wimshurst machine, the...

 on a conducting container. For a container, Faraday used a metal pail made to hold ice, which gave the experiment its name. The experiment shows that an electric charge
Electric charge
Electric charge is a physical property of matter that causes it to experience a force when near other electrically charged matter. Electric charge comes in two types, called positive and negative. Two positively charged substances, or objects, experience a mutual repulsive force, as do two...

 enclosed inside a conducting shell induces an equal charge on the shell, and that in an electrically conducting body, the charge resides entirely on the surface. It also demonstrates the principles behind electromagnetic shielding
Electromagnetic shielding
Electromagnetic shielding is the process of reducing the electromagnetic field in a space by blocking the field with barriers made of conductive and/or magnetic materials. Shielding is typically applied to enclosures to isolate electrical devices from the 'outside world' and to cables to isolate...

 such as employed in the Faraday cage
Faraday cage
A Faraday cage or Faraday shield is an enclosure formed by conducting material or by a mesh of such material. Such an enclosure blocks out external static and non-static electric fields...

. The ice pail experiment was the first precise quantitative experiment on electrostatic charge. It is still used today in lecture demonstrations and physics laboratory courses to teach the principles of electrostatics.

Description of experiment

Faraday's description of the experiment, from a letter he wrote on February 4, 1843 to Richard Phillips, the editor of Philosophical Journal, and published in the March 1844 issue:
"Let A in the diagram represent an insulated pewter ice-pail...connected by a wire to a delicate gold-leaf electrometer E, and let C be a round brass ball insulated by a dry thread of white silk, three or four feet in length, so as to remove the influence of the hand holding it from the ice-pail below. Let A be perfectly discharged, and then let C be charged at a distance by a [electrostatic] machine or Leyden jar, and introduced into A.. If C be positive, E will also diverge positively; if C be taken away, E will collapse perfectly... As C enters the vessel A the divergence of E will increase until C is ... below the edge of the vessel, and will remain quite steady and unchanged for any greater depression. This shows that at that distance the inductive action of C is entirely exerted upon the interior of A, ... If C is made to touch the bottom of A, all of its charge is communicated to A, ... and C, upon being withdrawn, ... is found to be perfectly discharged."


Below is a detailed modern description of the experimental procedure:
  1. The experiment uses a conductive metal container A open at the top, insulated from the ground. Faraday employed a 7 in. diameter by 10.5 in. tall pewter
    Pewter
    Pewter is a malleable metal alloy, traditionally 85–99% tin, with the remainder consisting of copper, antimony, bismuth and lead. Copper and antimony act as hardeners while lead is common in the lower grades of pewter, which have a bluish tint. It has a low melting point, around 170–230 °C ,...

     pail on a wooden stool, but modern demonstrations often use a hollow metal sphere with a hole in the top, or a cylinder of metal screen, mounted on an insulating stand. Its outside surface is connected by a wire to a sensitive electric charge detector. Faraday used a gold leaf electroscope, but modern demonstrations often use an electrometer
    Electrometer
    An electrometer is an electrical instrument for measuring electric charge or electrical potential difference. There are many different types, ranging from historical hand-made mechanical instruments to high-precision electronic devices...

     instrument because it is far more sensitive than an electroscope, can distinguish between positive and negative charge, and gives a quantitative readout. The container is discharged by connecting it briefly to a large conducting object, called a ground (earth); this can be done by touching it with a finger, using the conductive human body as a ground. Any initial charge drains off into the ground. The charge detector reads zero, indicating that the container has no charge.
  2. A metal object C (Faraday used a brass ball suspended by a nonconductive silk thread, but modern experiments often use a small metal ball or disk mounted on an insulating handle) is charged with electricity using an electrostatic machine and lowered into the container A without touching it . As it is lowered the charge detector's reading increases, indicating that the outside of the container is becoming charged. Once the object is well inside the lip of the container the charge detector levels off and registers a constant charge, even if the object is lowered further. The charge on the outside of the container is the same polarity as that on the object. If the charge detector is touched to the inside surface of the container, it is found to be charged with opposite polarity. For example, if the object C has a positive charge, the outside of the container A will be found to have a positive charge, while the inside of the container has a negative charge.
  3. If the object C is moved about inside the container without touching the walls, the charge detector's reading will not change, indicating that the charge on the outside of the container is not affected by where the charged object is inside the container.
  4. If the charged object C is lifted out of the container again, the charge detector will decrease to zero again. This shows the charges on the container were induced by C, and the container has no net charge. Therefore the opposite charges induced on the inside and the outside must be equal in size.
  5. The charged object C is touched to the inside of the container. The charge detector reading does not change. However if the object is now withdrawn from the container, the reading stays the same, indicating that the container now has a net charge. If the object is then tested with the charge detector, it is found to be completely uncharged, and the inside of the container is also found to be uncharged. This indicates that all the charge on C has been transferred to the container, and has exactly neutralized the opposite charge on the inside surface of the container, leaving only the charge on the outside. So the charge on the inside of the container was exactly equal to the charge on C.

Kits are available from educational supply firms containing all the apparatus needed for students to perform the experiment.

Preventing error due to stray charges

Stray static electric charges
Static electricity
Static electricity refers to the build-up of electric charge on the surface of objects. The static charges remain on an object until they either bleed off to ground or are quickly neutralized by a discharge. Static electricity can be contrasted with current electricity, which can be delivered...

 on the experimenter's body, clothes, or nearby apparatus, as well as AC
Alternating current
In alternating current the movement of electric charge periodically reverses direction. In direct current , the flow of electric charge is only in one direction....

 electric fields from mains
Mains electricity
Mains is the general-purpose alternating current electric power supply. In the US, electric power is referred to by several names including household power, household electricity, powerline, domestic power, wall power, line power, AC power, city power, street power, and grid power...

-powered equipment, can induce additional charges on parts of the container or charged object C, giving a false reading. The success of the experiment often requires precautions to eliminate these extraneous charges:
  • Any charges on the container and nearby conductive objects should be removed before the experiment by grounding
    Ground (electricity)
    In electrical engineering, ground or earth may be the reference point in an electrical circuit from which other voltages are measured, or a common return path for electric current, or a direct physical connection to the Earth....

     (earthing); touching them briefly to some large conducting object called a ground
    Ground (electricity)
    In electrical engineering, ground or earth may be the reference point in an electrical circuit from which other voltages are measured, or a common return path for electric current, or a direct physical connection to the Earth....

    . Any charge on the object will flow into the ground due to its mutual repulsion. This can be accomplished by touching them with a finger, using the conductive human body as a ground. However the experimenter's body itself should be grounded frequently by touching a good metal ground such as a metal workbench, or preferably a water pipe or the grounding wire of the building's mains power wiring. Ideally the experimenter's body should be grounded throughout the experiment. Some demonstration kits include conductive ground sheets which are laid on the workbench under the apparatus, and antistatic wrist strap
    Antistatic wrist strap
    An antistatic wrist strap, ESD wrist strap, or ground bracelet is an antistatic device used to safely ground a person working on very sensitive electronic equipment, to prevent the buildup of static electricity on their body, which can result in electrostatic discharge...

    s the experimenter wears during the experiment, which are connected to a good ground.
  • The electrometer measures charge with respect to ground, so it requires a connection to ground during use. It has a ground wire, usually colored black, ending in a clip which should be attached to a metal ground during use.
  • The experimenter should avoid excessive movement during the experiment. Walking around or waving his/her arms can cause the buildup of static charges on clothing. The experimenter should hold the handle of the charged object C as far from the object and the container as possible when lowering the object into the container.
  • In professional student laboratory kits, the container A is often in the form of two concentric cylinders of metal screen, open at the top. A screen acts the same as a solid metal sheet for electrostatic charge, as long as its holes are small. The inner cylinder is the Faraday pail container itself, separated from the outer cylinder with insulating supports. The outer cylindrical metal screen surrounds the inner, and acts as a ground to shield it from stray charges. This design largely eliminates the stray charge problem, as well as allowing the experimenter to see inside the container. The electrometer ground lead is clipped to the outer ground screen, and the experimenter touches this screen while performing any procedure. To ground the inner screen, the experimenter can bridge his finger between the inner and outer screens. When doing this it is important that he lift his finger first from the inner screen, not the outer, to avoid leaving charge on the inner screen.
  • Charge can leak off the charged object C and the container along handles and supports due to surface layers of dirt and oil from fingerprints. If this is suspected the equipment should be washed with detergent to remove oils and dried.
  • As explained below, the charge C must be well inside the lip of the container, at least a distance equal to the diameter of the opening, for the induced charge on the container to be equal to the internal charge. The container must be sufficiently deep, deeper than it is wide.
  • When measuring the charge on the inside or outside surface of the container, the charge detector should not be touched to the surface near the lip of the container. Extra charge concentrates near the edge of the opening due to the geometry of the metal.

Explanation

Conductive metal objects contain mobile electric charge
Electric charge
Electric charge is a physical property of matter that causes it to experience a force when near other electrically charged matter. Electric charge comes in two types, called positive and negative. Two positively charged substances, or objects, experience a mutual repulsive force, as do two...

s (electron
Electron
The electron is a subatomic particle with a negative elementary electric charge. It has no known components or substructure; in other words, it is generally thought to be an elementary particle. An electron has a mass that is approximately 1/1836 that of the proton...

s) that can move about freely in the metal. In an uncharged state, each part of the metal contains equal quantities of positive and negative charges, intimately mixed, so no part of it has a net charge. If an external charged object is brought near a piece of metal, the force of the charge causes these internal charges to separate. The charges of opposite polarity to the external charge are attracted to it, and move to the surface of the object facing the charge. The charges of the same polarity are repelled and move to the surface of the metal away from the charge. This is called electrostatic induction
Electrostatic induction
Electrostatic induction is a redistribution of electrical charge in an object, caused by the influence of nearby charges. Induction was discovered by British scientist John Canton in 1753 and Swedish professor Johan Carl Wilcke in 1762. Electrostatic generators, such as the Wimshurst machine, the...

. In Procedure 2 above, as the charge C is lowered into the container, the charges in the metal of the container separate. If C has a positive charge, the negative charges in the metal are attracted to it and move to the inner surface of the container, while the positive charges are repelled and move to the outside surface. If C has a negative charge, the charges have opposite polarity. Since the container was originally uncharged, the two regions have equal and opposite charges. The induction process is reversible: in Procedure 4, when C is removed, the attraction of the opposite charges cause them to intermingle again, and the charge on the surfaces reduces to zero.

The force which causes the mobile charges to move is the electrostatic field of the charged object C. As the charges in the metal separate, the resulting regions of induced charge on the surfaces of the metal container create their own electrostatic field, which opposes the field from C. The field of the induced charges exactly cancels the field from C throughout the interior of the metal. The electrostatic field inside a piece of metal is always zero. If it was not, the force of the field would cause more motion of charges and more charge separation, until the electric field became zero.

Once C is well inside the container, almost all of the electric field lines
Field line
A field line is a locus that is defined by a vector field and a starting location within the field. Field lines are useful for visualizing vector fields, which are otherwise hard to depict...

 from C strike the container surface. The result (proved below) is that the total charge induced on the inside of the container is equal to the charge on C.
In Procedure 5, when C is touched to the container's inner wall, all the charge on C flows out and neutralizes the induced charge, leaving both the inner wall and C uncharged. The container is left with the charge on its outside. The net effect is that all the charge that was previously on C is now on the outside of the container.

An important conclusion that can be drawn from this is that the net charge inside a closed conducting container is always zero, even if a charged object is put in. If the charge inside can find a conducting path to the container wall, it will flow to the outside surface of the container due to its mutual repulsion. If it cannot, the interior charge will induce an equal and opposite charge on the inside surface, so the net charge inside is still zero. Any net charge on a conducting object is located on its surface.

Proof induced charge is equal to object's charge

The result found in Procedure 5, that a charged object enclosed in a metal container induces an equal charge on the container, can be proved using Gauss's law
Gauss's law
In physics, Gauss's law, also known as Gauss's flux theorem, is a law relating the distribution of electric charge to the resulting electric field. Gauss's law states that:...

. Assume the container A completely encloses the object C, without an opening (this assumption is explained below), and that C has a charge of Q coulombs. The electric field of the charge C will cause the charges in the volume of the metal to separate, creating regions of induced charge on the inside and outside surfaces of the shell. Now imagine a closed surface S inside the metal of the shell, between the inside and outside surfaces. Since S is in a conducting region (inside the volume of metal) where the electric field is zero, the electric field everywhere on the surface S is zero. Therefore the total electric flux through the surface S must be zero. Therefore from Gauss's law
Gauss's law
In physics, Gauss's law, also known as Gauss's flux theorem, is a law relating the distribution of electric charge to the resulting electric field. Gauss's law states that:...

 the total electric charge inside the surface S must be zero:


The only charges inside S are the charge Q on the object C, and the induced charge Qinduced on the inside surface of the metal. Since the sum of these two charges is zero, the induced charge on the inside surface of the shell must have an equal but opposite value to the charge on C: Qinduced = −Q.

Explanation using electric field lines

Another way to see that the enclosed charge induces an equal charge in the container is to use the visualization device of electric field line
Field line
A field line is a locus that is defined by a vector field and a starting location within the field. Field lines are useful for visualizing vector fields, which are otherwise hard to depict...

s. Electric field lines terminate on equal charges; that is each line begins on a specific quantity of positive charge, and ends on an equal quantity of negative charge. An additional fact needed is that electric field lines cannot penetrate conductors; if an electric field line penetrated into a volume of metal, the electrons in the metal would flow along the field line, redistributing the charge in the conductor until no electric field was left. Only when the electric field in the conductor is zero can the charges in the conductor be at electrostatic equilibrium.

When the charged object C is enclosed inside the conductive container A. all the field lines extending from the object must terminate on the inside surface of the container; there is nowhere else for them to go. Since each unit of charge on the object originates a field line, which ends on an equal induced charge on the container, the total charge on the object and the induced charge on the container's interior must be equal.

A charged object outside any container also induces an equal charge on its surroundings. The field lines extending from it end on charges induced in the walls or other objects in the room. This illustrates the general principle that for every positive charge, there must be a corresponding negative charge somewhere in the universe.

The effect of the hole

Strictly speaking, for the induced charge on the container to exactly equal the charge on the object, the metal container must completely enclose the charged object, without a hole. If there is an opening, some of the electric field lines from C will pass through the opening, and therefore will not induce an opposite charge on the container, so the charge on the container's surfaces will be less than the charge on C. But an opening is necessary to get the charged object in and out. In his experiment, Faraday closed the opening by attaching the thread suspending the ball to the metal lid of the pail, so when the ball was lowered to the center of the container the lid covered the opening. However this is not necessary. The experiment works very well even for containers with large uncovered openings, like Faraday's pail. As long as it is deep enough, and the depth of C inside the container is greater than the diameter of the opening, the induced charge will be very close in value to the charge on C. This is because once the charged object is well inside, the electric field lines are attracted to the induced charges on the container walls (see drawing above), so very few of them pass through the opening. John Ambrose Fleming
John Ambrose Fleming
Sir John Ambrose Fleming was an English electrical engineer and physicist. He is known for inventing the first thermionic valve or vacuum tube, the diode, then called the kenotron in 1904. He is also famous for the left hand rule...

, a prominent early electrical researcher, wrote in 1911:

But the experiment is often explained, as in the above sections, by assuming the container has no hole.

Electrostatic shielding

Since there is no electric field in the intervening volume of the metal, the charge distribution on the outside surface of the container and its electric field is completely unaffected by the charges inside the container. If the charged object inside the container is moved about as in Procedure 3, the induced charge distribution on the inside surface will redistribute itself, maintaining the cancellation of the electric fields outside the inner surface. So the charges on the outside surface will be completely unaffected, along with any charges in the outside world. From the outside, the metal container acts exactly like it simply has a charge +Q, with no charges inside. Similarly, if an external charge is brought near the container from outside, the induced charge distribution on the outside surface will redistribute to cancel its electric field inside the container. So the charges inside the container will not "feel" any electric field and will not change. In summary, the regions inside and outside of the container are electrically isolated from each other, electric fields from one region cannot penetrate or affect the other. This is the principle of electrostatic shielding used in the Faraday cage
Faraday cage
A Faraday cage or Faraday shield is an enclosure formed by conducting material or by a mesh of such material. Such an enclosure blocks out external static and non-static electric fields...

.

Alternate procedure

An alternate way of conducting the experiment: after the charged object C is lowered into the container in Procedure 2, the outside surface of the container is momentarily grounded. The charge on the outside of the container all drains off to ground, and the charge detector declines to zero, leaving the charge on the inside of the container, equal but opposite to that on C. Then the object C is removed from the container. Since C is no longer present to hold the induced charge on the inside surface of the container, it migrates to the outside of the container. so the charge detector registers an equal but opposite charge from its previous reading. This new charge can be proved to be equal and opposite to the charge on C by touching C to the exterior surface of the container. The two charges exactly neutralize each other, so both the exterior of the container and C are found to be uncharged.

Noncontact charge measurement

Lowering an object into a Faraday container offers a way to measure the charge on it without touching it or disturbing its charge. The charge induced on the outside of the container by charges inside it depends only on the total charge inside. If several charged objects are lowered into the container, the charge on the outside will be equal to their sum.

Charge addition

If several conducting charged objects are lowered one after the other into the container and touched to the inside, all the charge on each object will be transferred to the outside of the container, regardless of how much charge is already on the container. This is the only way electrostatic charges on objects can be added together. If two conducting charged objects are simply touched together on their outside surfaces, the charge on both will merely be shared between the two objects.

This is how charge is transferred to the top terminal of a Van de Graaf generator. The terminal is a hollow metal shell and functions as a Faraday pail. Charge is transported inside it on a moving belt, then removed from the belt by a wire attached to the inside of the terminal. Since the inside of the terminal is at a constant potential, the charge from the belt flows to the outside surface, adding to the charge there, regardless of how much charge is already on the terminal.

Contact electrification produces equal charges

The "charge summing" property of Faraday's pail can be used to prove that contact electrification (triboelectricity), charging objects by rubbing or touching them together, produces equal and opposite charges. A piece of fur
Fur
Fur is a synonym for hair, used more in reference to non-human animals, usually mammals; particularly those with extensives body hair coverage. The term is sometimes used to refer to the body hair of an animal as a complete coat, also known as the "pelage". Fur is also used to refer to animal...

 and a piece of rubber or plastic are first discharged so they have no charge, then both are lowered together into the container attached to nonconductive handles. The charge detector registers no charge. Then they are rubbed together inside the container. The rubbing will cause the fur to become positively charged and the rubber to become negatively charged due to the triboelectric effect
Triboelectric effect
The triboelectric effect is a type of contact electrification in which certain materials become electrically charged after they come into contact with another different material and are then separated...

. However, since this is due to a separation of equal charges, the two charges are equal and opposite, so the sum of the charge on both objects is still zero. This is proven by the charge detector, which continues to read zero after the operation. The charges on the individual objects can be demonstrated by removing one at a time from the container. The charge detector will register opposite charges for each remaining object.

Multiple concentric containers

In his original 1844 paper, Faraday also investigated the effect of using several conducting containers one inside the other. He found that the induction effect works through multiple containers the same way it does through one container. He used four pails, each supported on a nonconductive pad inside the next. If a charge is lowered into the innermost pail, an exactly equal induced charge will appear on the outside of the outer pail. The charge on the outside of each pail induces an equal charge on the next. If one of the pails is grounded, the charge on all the pails outside it goes to zero.
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