Dimethylamine
Dimethylamine or N-methylmethanamine or DMA is an
organic compound and an
amine. It is a colorless, liquefied and flammable gas with an
ammonia and fish- like odor. Dimethylamine is generally used as a solution in water at concentrations up to around 40%.
Encyclopedia
| Dimethylamine |
|---|
| |
| Chemical name | Dimethylamine |
| Chemical formula | C2H7N |
| Molecular mass | 45.085 g/mol |
| Melting point | - 92.2 °C |
| Boiling point | 7 °C |
| Density | 1.5 gas; 0.67 liquid |
| CAS number | 124-40-3 |
| SMILES | CNC |
| CH3-NH-CH3 |
| |
|
Dimethylamine or
N-methylmethanamine or
DMA is an
organic compound and an
amine. It is a colorless, liquefied and flammable gas with an
ammonia and fish- like odor. Dimethylamine is generally used as a solution in water at concentrations up to around 40%.
Chemistry
Dimethylamine is a
secondary amine. The
molecule consists of an
amine atom with two methyl substituents and one
proton. Dimethylamine is a base and the pKa of the
ammonium salt CH
3-NH
2+-CH
3 is 10.73, a value intermediate between
methylamine and
trimethylamine .
Dimethylamine reacts with acids to form salts.
Dimethylamine hydrochloride is an odorless white solid with a melting point of 171.5 °C. Dimethylamine is produced by
catalytic reaction of
methanol and
ammonia at elevated temperatures and high pressure.
Biochemistry
The
German cockroach utilizes dimethylamine as a
pheromone for communication.
DMA undergoes nitrosation under weak acid conditions to give dimethlynitrosamine. This animal carcinogen has been detected and quantified in human urine samples and it may also arise from nitrosation of DMA by nitrogen oxides present in acid rain in highly industrilized countries .
Uses
Dimethylamine is used as dehairing agent in
tanning, in
dyes, in
rubber accelerators, in soaps and cleaning compounds and as an agricultural fungicide. In industry dimethylamine is converted to
dimethylformamide and the surfactant lauryl dimethylamine oxide. It is raw material in the production of many
pharmaceuticals such as
diphenhydramine and also that of the
chemical weapon tabun.
External links
- MSDS http://www.airliquide.com
- MSDS http://physchem.ox.ac.uk
- production at http://www.methylamines.com
-
See also
References
Zhang AQ, Mithchell SC, Smith RL Dimethylamine formation in the rat from various related amine precursors. Food Chem Toxicol 36:923-7