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Dielectric constant

 

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Dielectric constant



 
 
relative static permittivity (or static relative permittivity) of a material under given conditions is a measure of the extent to which it concentrates electrostatic lines of flux
Flux

In the various subfields of physics, there exist two common usages of the term flux, both with rigorous mathematical frameworks.*In the study of transport phenomena , flux is defined as the amount that flows through a unit area per unit time....
.






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Relative static permittivities of some materials at room temperature
Room temperature

Room temperature is a common term to denote a certain temperature within enclosed space at which humans are accustomed.Room temperature is thus often indicated by general human comfort, with the common range of 10celsius to 23?C , though climate may acclimatize people to higher or lower temperatures....
 under 1 kHz
Radio Wave

Radio Wave may refer to:*Radio frequency*Radio Wave 96.5, a radio station in Blackpool, UK...
Material Relative static permittivity r
Aluminium
Aluminium

Aluminium or aluminum is a silvery white and ductile member of the boron group of chemical elements. It has the symbol Al; its atomic number is 13....

(1 kHz)
-1300a
(-1300+i
Imaginary unit

In mathematics, physics, and engineering, the imaginary unit is denoted by  or the Latin   or the Greek iota . It allows the real number system, to be extended to the complex number system,   Its precise definition is dependent upon the particular method of extension....
1.3Χ1014)a
Silver
Silver

Silver is a chemical element with the chemical symbol Ag and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal....

(1 kHz)
-85b
(-85+i
Imaginary unit

In mathematics, physics, and engineering, the imaginary unit is denoted by  or the Latin   or the Greek iota . It allows the real number system, to be extended to the complex number system,   Its precise definition is dependent upon the particular method of extension....
8Χ1012)b
Vacuum
Vacuum

A vacuum is a volume of space that is essentially empty of matter, such that its gaseous pressure is much less than atmospheric pressure. The word comes from the Latin term for "empty," but in reality, no volume of space can ever be perfectly empty....
 
1 (by definition)
Air
AIR

Air is the part of Earth's atmosphere that humans breath and as such Air .Air may also refer to:...
 
1.00054
Teflon 2.1
Polyethylene
Polyethylene

Polyethylene or polythene is a thermoplastic commodity heavily used in consumer products . Over 60 million tons of the material are produced worldwide every year....
 
2.25
Polystyrene
Polystyrene

Polystyrene , sometimes abbreviated PS, is an Aromaticity polymer made from the aromatic monomer styrene, a liquid hydrocarbon that is commercially manufactured from petroleum by the chemical industry....
 
2.4–2.7
Carbon disulfide
Carbon disulfide

Carbon disulfide is a colorless, volatile liquid with the chemical formula CS2. The compound is used frequently as a building block in organic chemistry as well as an industrial and chemical non-polar solvent....
 
2.6
Paper
Paper

Paper is thin material mainly used for writing upon, printing upon or packaging. It is produced by pressing together moist fibers, typically cellulose pulp derived from wood, rags or grasses, and drying them into flexible sheets....
 
3.5
Electroactive polymers
Electroactive polymers

Electroactive Polymers or EAPs are polymers whose shape is modified when a voltage is applied to them.They can be used as actuators or sensors....
 
2–12
Silicon dioxide
Silicon dioxide

The chemical compound 'silicon dioxide', also known as 'silica' , is an oxide of silicon with a chemical formula of and has been known for its hardness since antiquity....
 
4.5
Concrete
Concrete

Concrete is a construction material composed of cement as well as other cementitious materials such as fly ash and slag cement, construction aggregate , water , and Chemistry admixtures....
 
4.5
Pyrex
Pyrex

Pyrex is a brand name for glassware, introduced by Corning Incorporated in 1915. Originally, Pyrex was made from thermal shock resistant borosilicate glass....
 (Glass
Glass

Glass generally refers to a Hardness, brittle, transparency amorphous solid, such as that used for windows, many Glass Bottles, or eyewear, including, but not limited to, soda-lime glass, borosilicate glass, acrylic glass, sugar glass, Muscovite , or aluminium oxynitride....
)
4.7 (3.7–10)
Rubber
Rubber

Natural rubber is an elastomer?an Elasticity_ hydrocarbon polymer?that was originally derived from a milky colloidal suspension, or latex , found in the sap of some plants....
 
7
Diamond
Diamond

In mineralogy, diamond is the Allotropes of carbon where the carbon atoms are arranged in an isometric-hexoctahedral crystal lattice. After graphite, diamond is the second most stable form of carbon....
 
5.5–10
Salt
Salt

A salt, in chemistry, is defined as the product formed from the neutralisation reaction of acids and base . Salts are ionic compounds composed of cations and anions so that the product is electrically electric charge ....
 
3–15
Graphite
Graphite

The mineral graphite is one of the allotropes of carbon. It was named by Abraham Gottlob Werner in 1789 from the Greek language ??afe?? : "to draw/write", for its use in pencils, where it is commonly called lead, as distinguished from the actual metallic element lead....
 
10–15
Silicon
Silicon

Silicon is the most common metalloid. It is a chemical element, which has the symbol Si and atomic number 14. The atomic mass is 28.0855....
 
11.68
Ammonia
Ammonia

Ammonia is a chemical compound with the chemical formula nitrogenhydrogen. It is normally encountered as a gas with a characteristic pungent odor....
 
26–22–20–17
(-80–-40–0–20 °C)
Methanol
Methanol

Methanol, also known as methyl alcohol, carbinol, wood alcohol, wood naphtha or wood spirits, is a chemical compound with chemical formula carbonhydrogen3oxygenhydrogen ....
 
30
Furfural
Furfural

The chemical compound furfural is an industrial chemical derived from a variety of agriculture byproducts, including maize, oat and wheat bran, and sawdust....
 
42.0
Glycerol
Glycerol

Glycerol is a chemical compound also commonly called glycerin or glycerine. It is a colorless, odorless, Viscosity liquid that is widely used in pharmaceutical formulations....
 
41.2–47–42.5
(0–20–25 °C)
Water
Water

Water is a common chemical substance that is essential for the survival of all known forms of life. In typical usage, water refers only to its liquid form or States of matter, but the substance also has a solid state, ice, and a gaseous state, water vapor or steam....
 
88–80.1–55.3–34.5
(0–20–100–200 °C)
Hydrofluoric acid
Hydrofluoric acid

Hydrofluoric acid is a solution of hydrogen fluoride in water. While it is extremely corrosive and dangerous to handle, it is technically a weak acid....
 
83.6 (0 °C)
Formamide
Formamide

Formamide, also known as methanamide, is an amide derived from formic acid. It is a clear liquid which is miscible with water and has an ammonia-like odor....
 
84.0 (20 °C)
Sulfuric acid
Sulfuric acid

Sulfuric acid, hydrogen2sulfuroxygen4, is a strong mineral acid. It is soluble in water at all concentrations. Sulfuric acid has many applications, and is one of the top products of the chemical industry....
 
84–100
(20–25 °C)
Hydrogen peroxide
Hydrogen peroxide

Hydrogen peroxide is a very pale blue liquid which appears colorless in a dilute solution, slightly more viscous than water. It is a weak acid....
 
128 aq–60
(-30–25 °C)
Hydrocyanic acid 158.0–2.3
(0–21 °C)
Titanium dioxide
Titanium dioxide

Titanium dioxide, also known as titanium oxide or titania, is the naturally occurring oxide of titanium, chemical formula titaniumoxygen2....
 
86–173
Strontium titanate
Strontium titanate

Strontium titanate is an oxide of strontium and titanium with the chemical formula strontiumtitaniumoxygen3. It is a centrosymmetric paraelectricity material with a perovskite structure....
 
310
Barium strontium titanate 15 nc
Nanocrystal

Fahlman, B. D. has described a nanocrystal as any nanomaterial with at least one dimension = 100nm and that is singlecrystalline. More properly, any material with a dimension of less than 1 micrometre, i.e., 1000 nanometers, should be referred to as a nanoparticle, not a nanocrystal....
–500
Barium titanate
Barium titanate

Barium titanate is an oxide of barium and titanium with the chemical formula BaTiO3. It is a ferroelectric ceramic material, with a photorefractive effect and piezoelectric properties....
 
90 nc
Nanocrystal

Fahlman, B. D. has described a nanocrystal as any nanomaterial with at least one dimension = 100nm and that is singlecrystalline. More properly, any material with a dimension of less than 1 micrometre, i.e., 1000 nanometers, should be referred to as a nanoparticle, not a nanocrystal....
–1250–10,000
(20–120 °C)
(La,Nb)PbO3
Lead zirconate titanate

Lead zirconate titanate is a ceramic perovskite material that shows a marked piezoelectricity.It is also known as PZT which is an abbreviation of the chemical formula....
 
500–6000
Conjugated polymers
Conjugated system

A conjugated system occurs in an organic compound where atoms covalently Chemical bond with alternating single and multiple bonds and influence each other to produce a region called electron delocalization....
 
6–100,000
΅m
Micrometre

A micrometre or micron is one Micro- of a metre, or equivalently one thousandth of a millimetre. It is also commonly known as a micron....
–nm
Nanometre

A nanometre is a Units of measurement of length in the metric system, equal to one billionth of a metre .It is one of the more often used units for very small lengths, and equals ten ?ngstr?m, an internationally recognized non-International System of Units of length....
 heterostructures
1000–100,000
(106–108 at 100 Hz)
|} The relative static permittivity (or static relative permittivity) of a material under given conditions is a measure of the extent to which it concentrates electrostatic lines of flux
Flux

In the various subfields of physics, there exist two common usages of the term flux, both with rigorous mathematical frameworks.*In the study of transport phenomena , flux is defined as the amount that flows through a unit area per unit time....
. It is the ratio of the amount of stored electrical energy when a potential is applied, relative to the permittivity of a vacuum. The relative static permittivity is the same as the relative permittivity evaluated for a frequency
Frequency

Frequency is the number of occurrences of a repeating event per unit time. It is also referred to as temporal frequency.The period is the duration of one cycle in a repeating event, so the period is the reciprocal of the frequency....
 of zero.

The relative static permittivity is represented as er or sometimes or K or Dk. It is defined as

where es is the static permittivity of the material, and e0 is the electric constant
Electric constant

Vacuum permittivity, referred to by international standards organizations as the electric constant, and denoted by the symbol e0, is a fundamental physical constant relating the mechanical quantities to the units for electrical charge, for example, in Coulomb's law....
. (The relative permittivity is the complex
Complex number

In mathematics, the complex numbers are an extension of the real numbers obtained by adjoining an imaginary unit, denoted i, which satisfies:...
 frequency-dependent , which gives the static relative permittivity for .)

Other terms for the relative static permittivity are the dielectric constant, or relative dielectric constant, or static dielectric constant. These terms, while they remain very common, are ambiguous and have been deprecated by some standards organizations. The reason for the potential ambiguity is twofold. First, some older authors used "dielectric constant" or "absolute dielectric constant" for the absolute permittivity rather than the relative permittivity. Second, while in most modern usage "dielectric constant" refers to a relative permittivity, it may be either the static or the frequency-dependent relative permittivity depending on context.

By definition, the linear relative permittivity of vacuum, where , is equal to 1, although there are theoretical nonlinear quantum
Quantum electrodynamics

Quantum electrodynamics is a relativity theory quantum field theory of electrodynamics. QED was developed by a number of physicists, beginning in the late 1920s....
 effects in vacuum that have been predicted at high field strengths (but not yet observed).

The static relative permittivity of a medium is related to its static electric susceptibility
Electric susceptibility

The electric susceptibility ?e of a dielectric material is a measure of how easily it polarization density in response to an electric field....
, by

in SI
Si

Si, si, or SI may refer to :...
 units.

Measurement

The relative static permittivity, er, can be measured for static electric field
Electric field

In physics, the space surrounding an electric charge or in the presence of a time-varying magnetic field has a property called an electric field ....
s as follows: first the capacitance
Capacitance

In electromagnetism and electronics, capacitance is the ability of a body to hold an electrical charge.Capacitance is also a measure of the amount of electric charge stored for a given electric potential....
 of a test capacitor, C0, is measured with vacuum between its plates. Then, using the same capacitor and distance between its plates the capacitance Cx with a dielectric
Dielectric

A dielectric is a nonconducting substance, i.e. an Insulator . The term was coined by William Whewell in response to a request from Michael Faraday....
 between the plates is measured. The relative dielectric constant can be then calculated as

For time-variant electromagnetic field
Electromagnetic field

The electromagnetic field is a physical field produced by electric charge. It affects the behavior of charged objects in the vicinity of the field....
s, this quantity becomes frequency
Frequency

Frequency is the number of occurrences of a repeating event per unit time. It is also referred to as temporal frequency.The period is the duration of one cycle in a repeating event, so the period is the reciprocal of the frequency....
 dependent and in general is called relative permittivity.

Practical relevance


The dielectric constant is an essential piece of information when designing capacitor
Capacitor

A capacitor or condenser is a Passive component electronic component consisting of a pair of electrical conductor separated by a dielectric....
s, and in other circumstances where a material might be expected to introduce capacitance
Capacitance

In electromagnetism and electronics, capacitance is the ability of a body to hold an electrical charge.Capacitance is also a measure of the amount of electric charge stored for a given electric potential....
 into a circuit. If a material with a high dielectric constant is placed in an electric field
Electric field

In physics, the space surrounding an electric charge or in the presence of a time-varying magnetic field has a property called an electric field ....
, the magnitude of that field will be measurably reduced within the volume of the dielectric. This fact is commonly used to increase the capacitance of a particular capacitor design. The layers beneath etched conductors in Printed Circuit Boards (PCB
Printed circuit board

A printed circuit board, or PCB, is used to mechanically support and electrically connect electronic components using Conductor pathways, or signal traces, industrial etchinged from copper sheets laminated onto a non-conductive substrate....
s) also act as dielectrics.

Dielectrics are used in RF
RF

Rf or RF is an abbreviation for:* ** Radiative forcing, is an IPCC unit that nominates the global, annual average of radiative imbalance in net heating of the Earth's lower atmosphere as a result of human activities since the beginning of the industrial era....
 transmission lines. In a coaxial
Coaxial

In geometry, coaxial means that two or more forms share a common Coordinate axis; it is the three-dimensional linear analog of "concentric".Coaxial cable, as a common example, has a wire Conductor in the center a circumferential outer conductor and an insulating medium called the dielectric separating these two conductors....
 cable, polyethylene
Polyethylene

Polyethylene or polythene is a thermoplastic commodity heavily used in consumer products . Over 60 million tons of the material are produced worldwide every year....
 can be used between the center conductor and outside shield. It can also be placed inside waveguides to form filters. Optical fibers are examples of dielectric waveguide
Waveguide

A waveguide is a structure which guides waves, such as electromagnetic waves or sound waves. There are different types of waveguide for each type of wave....
s
. They consist of dielectric materials that are purposely doped with impurities so as to control the precise value of er within the cross-section. This controls the refractive index of the material and therefore also the optical modes of transmission. However, in these cases it is technically the relative permittivity that matters, as they are not operated in the electrostatic limit.

Chemical applications

The relative static permittivity of a solvent is a relative measure of its polarity
Polarity

In physics, polarity is a description of an attribute, typically a binary attribute , or a vector . For example:* An electric charge has a polarity of either positive or negative....
. For example, water
Water (molecule)

File:Blue-water-pool.jpgWater is the most abundant molecule on Earth's surface, constituting about 70% of the Earth's surface in liquid, solid, and gaseous states....
 (very polar) has a dielectric constant of 80.10 at 20 °C while n-hexane
Hexane

Hexane is an alkane hydrocarbon with the chemical formula CH34CH3 or C6H14. The "hex" prefix refers to its six carbons, while the "ane" ending indicates that its carbons are connected by single bonds....
 (very non-polar) has a dielectric constant of 1.89 at 20 °C. This information is of great value when designing separation, sample preparation and chromatography
Chromatography

Chromatography is the collective term for a family of laboratory techniques for the separation of mixtures. It involves passing a mixture dissolved in a "mobile phase" through a stationary phase, which separates the analyte to be measured from other molecules in the mixture and allows it to be isolated....
 techniques in analytical chemistry
Analytical chemistry

Analytical chemistry is the study of the chemical composition of natural and artificial materials. Unlike other major sub disciplines of chemistry such as inorganic chemistry and organic chemistry, analytical chemistry is not restricted to any particular type of chemical compound or chemical reaction....
.

See also

  • Permittivity
    Permittivity

    Permittivity is a physical quantity that describes how an electric field affects, and is affected by a dielectric medium, and is determined by the ability of a material to polarization in response to the field, and thereby reduce the total electric field inside the material....
  • Refractive index
    Refractive index

    The refractive index of a medium is a measure for how much the speed of light is reduced inside the medium. For example, typical soda-lime glass has a refractive index of 1.5, which means that in glass, light travels at times the speed of light in a vacuum....
  • Ferroelectricity
    Ferroelectricity

    Ferroelectricity is a spontaneous Polarization density of a material that can be reversed by the application of an external electric field. The term is used in analogy to ferromagnetism, in which a material exhibits a permanent magnetic moment....
  • Dielectric strength
    Dielectric strength

    In physics, the term dielectric strength has the following meanings:*Of an insulating material, the maximum electric field strength that it can withstand intrinsically without breaking down, i.e., without experiencing failure of its insulating properties....
  • Low-k
    Low-K

    In semiconductor manufacturing, a Low-? dielectric is a material with a small dielectric constant relative to silicon dioxide. Although the proper symbol for the dielectric constant is the Greece letter ? , in conversation such materials are referred to as being "low-k" rather than "low-?" ....
  • High-k
  • Linear response function
    Linear response function

    A linear response function describes the input-output relationshipof a signal transducer such as a radio turning electromagnetic waves into music...
  • Kramers–Kronig relation
  • Green–Kubo relations
  • Dielectric spectroscopy
    Dielectric spectroscopy

    Dielectric spectroscopy measures the dielectric properties of a medium as a function of frequency. It is based on the interaction of an external field with the electric dipole moment of the sample, often expressed by permittivity....
  • Curie point
    Curie point

    The Curie point , or Curie temperature, is a term in physics and materials science, named after Pierre Curie , and refers to a characteristic property of a ferromagnetic or piezoelectric material....
  • Electret
    Electret

    Electret is a dielectric material that has a quasi-permanent electric charge or dipole polarization . An electret generates internal and external electric fields, and is the electrostatic equivalent of a permanent magnet....