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Dielectric



 
 
A dielectric is a nonconducting substance, i.e. an insulator. The term was coined by William Whewell
William Whewell

William Whewell was an English polymath, scientist, Anglican priest, philosopher, theologian, and History of science. His surname is pronounced "hew-el." ...
 in response to a request from Michael Faraday
Michael Faraday

Michael Faraday, Fellow of the Royal Society was an English chemist and physicist who contributed to the fields of electromagnetism and electrochemistry....
. Although "dielectric" and "insulator" are generally considered synonymous, the term "dielectric" is more often used when considering the effect of alternating electric fields on the substance while "insulator" is more often used when the material is being used to withstand a high electric field.






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A dielectric is a nonconducting substance, i.e. an insulator. The term was coined by William Whewell
William Whewell

William Whewell was an English polymath, scientist, Anglican priest, philosopher, theologian, and History of science. His surname is pronounced "hew-el." ...
 in response to a request from Michael Faraday
Michael Faraday

Michael Faraday, Fellow of the Royal Society was an English chemist and physicist who contributed to the fields of electromagnetism and electrochemistry....
. Although "dielectric" and "insulator" are generally considered synonymous, the term "dielectric" is more often used when considering the effect of alternating electric fields on the substance while "insulator" is more often used when the material is being used to withstand a high electric field. Von Hippel
Arthur R. von Hippel

Arthur Robert von Hippel was a German American Materials science and physicist. Von Hippel was a pioneer in the study of dielectrics, ferromagnetic and ferroelectric materials, and semiconductors and was a codeveloper of radar during World War II....
, in his seminal book, takes this definition further, stating:

Dielectrics... are not a narrow class of so-called insulators, but the broad expanse of nonmetals considered from the standpoint of their interaction with electric, magnetic, of electromagnetic fields. Thus we are concerned with gases as well as with liquids and solids, and with the storage of electric and magnetic energy as well as its dissipation.


Dielectrics is the study of dielectric materials and involves physical models to describe how an electric field
Electric field

In physics, the space surrounding an electric charge or in the presence of a time-varying magnetic field has a property called an electric field ....
 behaves inside a material. It is characterized by how an electric field interacts with an atom and is therefore possible to approach from either a classical
Classical electromagnetism

Classical electromagnetism is a theory of electromagnetism that was developed over the course of the 19th century, most prominently by James Clerk Maxwell....
 interpretation or a quantum
Quantum mechanics

Quantum mechanics is a set of principles underlying the most fundamental known description of all physical systems at the microscopic scale . Notable amongst these principles are both a dual wave-like and particle-like behavior of matter and radiation, and prediction of probabilities in situations where classical physics predicts certaintie...
 one.

Many phenomena in electronics
Electronics

Electronics refers to the flow of charge through nonmetal electrical conductor , whereas electrical refers to the flow of charge through metal electrical conductor....
, solid state
Solid-state physics

Solid-state physics, the largest branch of condensed matter physics, is the study of rigid matter, or solids, through methods such as quantum mechanics, crystallography, electromagnetism and metallurgy....
 and optical
Optics

Optics is the study of the behavior and properties of light including its optical phenomena with matter and its imaging by optical instruments....
 physics can be described using the underlying assumptions of the dielectric model. This can mean that the same mathematical objects can go by many different names.

Definitions


Classical

In the classical approach to the dielectric model, a material is made up of atoms. Each atom consists of a cloud of negative charge bound to and surrounding a positive point charge at its centre. Because of the comparatively huge distance between them, none of the atoms in the dielectric material interact with one another . Note: Remember that the model is not attempting to say anything about the structure of matter. It is only trying to describe the interaction between an electric field and matter.

In the presence of an electric field
Electric field

In physics, the space surrounding an electric charge or in the presence of a time-varying magnetic field has a property called an electric field ....
 the charge cloud is distorted, as shown in the top right of the figure.

This can be reduced to a simple dipole
Dipole

In physics, there are two kinds of dipoles :*An electric dipole is a separation of positive and negative charge. The simplest example of this is a pair of electric charges of equal magnitude but opposite sign, separated by some, usually small, distance....
 using the superposition principle
Superposition principle

In physics and systems theory, the superposition principle, also known as superposition property, states that, for all linear systems,So that if input A produces response X and input B produces response Y then input produces response ....
. A dipole is characterized by its dipole moment, a vector quantity shown in the figure as the blue arrow labeled M. It is the relationship between the electric field and the dipole moment that gives rise to the behavior of the dielectric. Note: The dipole moment is shown to be pointing in the same direction as the electric field. This isn't always correct, and it is a major simplification, but it is suitable for many materials.

When the electric field is removed the atom returns to its original state. The time required to do so is the so-called relaxation time; an exponential decay.

Behavior

This is the essence of the model. The behavior of the dielectric now depends on the situation. The more complicated the situation the more rich the model has to be in order to accurately describe the behavior. Important questions are:
  • Is the electric field constant or does it vary with time?
    • If the electric field does vary, does it vary quickly or slowly?
  • What are the characteristics of the material?
    • Is the direction of the field important (isotropy
      Isotropy

      Isotropy is uniformity in all directions. Precise definitions depend on the subject area. The word is made up from Greek iso and tropos ....
      )?
    • Is the material the same all the way through (homogeneous
      Homogeneity (physics)

      In physics, homogeneous mixtures are mixtures that have definite, consistent composition and properties. Particles are uniformly spread. For example, any amount of a given mixture has the same composition and properties....
      )?
    • Are there any boundaries/interfaces that have to be taken into account?
  • Is the system linear
    Linear system

    A linear system is a mathematical model of a system based on the use of a linear operator.Linear systems typically exhibit features and properties that are much simpler than the general, nonlinear case....
     or do nonlinearities have to be taken into account?


The relationship between the electric field E and the dipole moment M gives rise to the behavior of the dielectric, which, for a given material, can be characterized by the function F defined by the equation: .

When both the type of electric field and the type of material have been defined, one then chooses the simplest function F that correctly predicts the phenomena of interest. Examples of possible phenomena:

  • Refractive index
    Refractive index

    The refractive index of a medium is a measure for how much the speed of light is reduced inside the medium. For example, typical soda-lime glass has a refractive index of 1.5, which means that in glass, light travels at times the speed of light in a vacuum....
  • Group velocity dispersion
  • Birefringence
    Birefringence

    Birefringence, or double refraction, is the decomposition of a Ray of light into two rays when it passes through certain types of material, such as calcite crystals or boron nitride, depending on the polarization of the light....
  • Self-focusing
    Self-focusing

    Self-focusing is a nonlinear optics process induced by the change in refractive index of materials exposed to intense electromagnetic radiation....
  • Harmonic generation
    Harmonic generation

    Perturbative Harmonic Generation Perturbative Harmonic Generation is a process where by laser lightof frequency ? and photon energy h? can be used...


May be modeled by choosing a suitable function F.

Dielectric model applied to vacuum

From the definition it might seem strange to apply the dielectric model to a vacuum, however, it is both the simplest and the most accurate example of a dielectric.

Recall that the property which defines how a dieletric behaves is the relationship between the applied electric field and the induced dipole moment. For a vacuum the relationship is a real
Real number

In mathematics, the real numbers may be described informally in several different ways. The real numbers include both rational numbers, such as 42 and −23/129, and irrational numbers, such as pi and the square root of two; or, a real number can be given by an infinite decimal representation, such as 2.4871773339...., where the digits co...
 constant number. This constant is called the permittivity of free space, e0.

Applications


Capacitors

Commercially manufactured capacitors typically use a solid
Solid

A solid object is in the states of matter characterized by resistance to deformation and changes of volume. In other words, it has high values both of Young's modulus and of shear modulus; this contrasts e.g....
 dielectric material with high permittivity
Permittivity

Permittivity is a physical quantity that describes how an electric field affects, and is affected by a dielectric medium, and is determined by the ability of a material to polarization in response to the field, and thereby reduce the total electric field inside the material....
 as the intervening medium between the stored positive and negative charges. This material is often referred to in technical contexts as the "capacitor dielectric"

. The most obvious advantage to using such a dielectric material is that it prevents the conducting plates on which the charges are stored from coming into direct electrical contact. More significantly however, a high permittivity allows a greater charge to be stored at a given voltage. This can be seen by treating the case of a linear dielectric with permittivity e and thickness d between two conducting plates with uniform charge density . In this case, the charge density is given by

and the capacitance
Capacitance

In electromagnetism and electronics, capacitance is the ability of a body to hold an electrical charge.Capacitance is also a measure of the amount of electric charge stored for a given electric potential....
 per unit area by

From this, it can easily be seen that a larger leads to greater charge stored and thus greater capacitance.

Dielectric materials used for capacitors are also chosen such that they are resistant to ionization
Ionization

Ionization is the physics process of converting an atom or molecule into an ion by adding or removing charged particles such as electrons or other ions....
. This allows the capacitor to operate at higher voltages before the insulating dielectric ionizes and begins to allow undesirable current flow.

Cable insulation

The term "dielectric" may also refer to the insulation used in power and RF cables. Common materials used as electrical inulations are electrical insulation paper
Electrical insulation paper

Electrical insulation papers are paper types that are used as Insulation in many applications due to pure cellulose has outstanding electrical properties....
 and plastics.

Some practical dielectrics

Dielectric materials can be solids, liquids, or gases. In addition, a high vacuum can also be a useful, lossless dielectric even though its relative dielectric constant is only unity.

Solid dielectrics are perhaps the most commonly used dielectrics in electrical engineering, and many solids are very good insulators. Some examples include porcelain
Porcelain

Porcelain is a ceramic material made by heating raw materials, generally including clay in the form of kaolin, in a kiln to temperatures between and ....
, glass
Glass

Glass generally refers to a Hardness, brittle, transparency amorphous solid, such as that used for windows, many Glass Bottles, or eyewear, including, but not limited to, soda-lime glass, borosilicate glass, acrylic glass, sugar glass, Muscovite , or aluminium oxynitride....
, and most plastic
Plastic

Plastic is the general common term for a wide range of synthetic or semisynthetic organic chemistry solid materials suitable for the manufacture of industrial products....
s. Air, nitrogen
Nitrogen

Nitrogen is a chemical element that has the symbol N and atomic number 7 and atomic mass 14.00674?. Elemental nitrogen is a colorless, odorless, tasteless and mostly inert diatomic gas at standard conditions, constituting 78% by volume of Earth's atmosphere....
 and sulfur hexafluoride
Sulfur hexafluoride

Sulfur hexafluoride is an inorganic compound with the formula . It is a colorless, odorless, non-toxicity and non-flammable gas . has an octahedral geometry, consisting of six fluorine atoms attached to a central sulfur atom....
 are the three most commonly used gaseous dielectrics.
  • Industrial coating
    Industrial coating

    An industrial coating is a paint or coating defined by its protective, rather than its aesthetic properties, although it can provide both.The most common use of industrial coatings is for corrosion control of steel or concrete....
    s such as parylene
    Parylene

    Parylene is the tradename for a variety of polyxylylene polymers marketed by several providers, including Kisco Conformal Coating, LLC, Para Tech Coating, Inc., Specialty Coating Systems, Inc., Comelec, SA, Parylene Coating Services and others....
     provide a dielectric barrier between the substrate and its environment.
  • Mineral oil
    Mineral oil

    Mineral oil or liquid petroleumis a by-product in the distillation of petroleum to produce gasoline and other petroleum based products from crude oil....
     is used extensively inside electrical transformer
    Transformer

    A transformer is a device that transfers electrical energy from one electrical network to another through inductive coupling conductors — the transformer's coils or "windings"....
    s as a fluid dielectric and to assist in cooling. Dielectric fluids with higher dielectric constant
    Dielectric constant

    The relative static permittivity of a material under given conditions is a measure of the extent to which it concentrates electrostatic lines of flux....
    s, such as electrical grade castor oil
    Castor oil

    Castor oil is a vegetable oil obtained from the castor bean . Castor oil is a colorless to very pale yellow liquid with mild or no odor or taste....
    , are often used in high voltage
    High voltage

    The term high voltage characterizes electrical circuits, in which the voltage used is the cause of particular safety concerns and insulation requirements....
     capacitor
    Capacitor

    A capacitor or condenser is a Passive component electronic component consisting of a pair of electrical conductor separated by a dielectric....
    s to help prevent corona discharge
    Corona discharge

    In electricity, a corona discharge is an electrical discharge brought on by the ionization of a fluid surrounding a conductor , which occurs when the potential gradient exceeds a certain value, but conditions are insufficient to cause complete electrical breakdown or electric arc....
     and increase capacitance.
  • Because dielectrics resist the flow of electricity, the surface of a dielectric may retain stranded excess electrical charges. This may occur accidentally when the dielectric is rubbed (the triboelectric effect
    Triboelectric effect

    The triboelectric effect is a type of contact electrification in which certain materials become electric charge after they come into contact with another different material and are then separated ....
    ). This can be useful, as in a Van de Graaff generator
    Van de Graaff generator

    A Van de Graaff generator is an Electrostatic generator which uses a moving belt to accumulate very high electrostatically stable voltages on a hollow metal globe....
     or electrophorus
    Electrophorus

    An electrophorus is a Capacitor Electric generator used to produce electrostatic charge via the process of electrostatic induction. It was invented in 1764 by Swedish professor Johan Carl Wilcke,...
    , or it can be potentially destructive as in the case of electrostatic discharge
    Electrostatic discharge

    Electrostatic discharge is the sudden and momentary electric current that flows between two objects at different electrical potentials caused by direct contact or induced by an electrostatic field....
    .
  • Specially processed dielectrics, called electret
    Electret

    Electret is a dielectric material that has a quasi-permanent electric charge or dipole polarization . An electret generates internal and external electric fields, and is the electrostatic equivalent of a permanent magnet....
    s (also known as ferroelectrics), may retain excess internal charge or "frozen in" polarization. Electrets have a semipermanent external electric field, and are the electrostatic equivalent to magnets. Electrets have numerous practical applications in the home and industry.
  • Some dielectrics can generate a potential difference when subjected to mechanical stress
    Stress (physics)

    In continuum mechanics, stress is a measure of the average amount of force exerted per unit area. It is a measure of the intensity of the total internal forces acting within a body across imaginary internal surfaces, as a reaction to external applied forces and body forces....
    , or change physical shape if an external voltage is applied across the material. This property is called piezoelectricity
    Piezoelectricity

    Piezoelectricity is the ability of some materials to generate an electric potential in response to applied mechanical Stress . This may Piezoelectricity#Crystal classes of a separation of electric charge across the crystal lattice....
    . Piezoelectric materials are another class of very useful dielectrics.
  • Some ionic crystal
    Crystal

    A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions....
    s and polymer
    Polymer

    A polymer is a large molecule composed of repeating structural units typically connected by covalent chemical bonds. While polymer in popular usage suggests plastic, the term actually refers to a large class of natural and synthetic materials with a variety of properties....
     dielectrics exhibit a spontaneous dipole moment which can be reversed by an externally applied electric field. This behavior is called the ferroelectric effect. These materials are analogous to the way ferromagnetic materials behave within an externally applied magnetic field. Ferroelectric materials often have very high dielectric constants, making them quite useful for capacitors.


See also


External links

  • - A chapter from an online textbook