Clinohumite
Encyclopedia
Clinohumite is an uncommon member of the humite group
Humite (mineral group)
The humite group is a group of nesosilicates with the general formula Anm2.When A is predominantly magnesium we have the humite subgroup:*norbergite, Mg32*chondrodite, 522*humite, 732...

, a magnesium
Magnesium
Magnesium is a chemical element with the symbol Mg, atomic number 12, and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust and ninth in the known universe as a whole...

 silicate
Silicate
A silicate is a compound containing a silicon bearing anion. The great majority of silicates are oxides, but hexafluorosilicate and other anions are also included. This article focuses mainly on the Si-O anions. Silicates comprise the majority of the earth's crust, as well as the other...

 according to the chemical formula
Chemical formula
A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....

 (Mg
Magnesium
Magnesium is a chemical element with the symbol Mg, atomic number 12, and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust and ninth in the known universe as a whole...

,Fe
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

)9(Si
Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. A tetravalent metalloid, it is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive than germanium, the metalloid directly below it in the table...

O
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

4)4(F
Fluorine
Fluorine is the chemical element with atomic number 9, represented by the symbol F. It is the lightest element of the halogen column of the periodic table and has a single stable isotope, fluorine-19. At standard pressure and temperature, fluorine is a pale yellow gas composed of diatomic...

,OH
Hydrogen
Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...

)2. Most commonly found as tiny indistinct grains, large euhedral clinohumite crystal
Crystal
A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. The scientific study of crystals and crystal formation is known as crystallography...

s are sought by collectors and occasionally fashioned into bright, yellow-orange gemstone
Gemstone
A gemstone or gem is a piece of mineral, which, in cut and polished form, is used to make jewelry or other adornments...

s. Only two sources of gem-quality material are known: the Pamir Mountains
Pamir Mountains
The Pamir Mountains are a mountain range in Central Asia formed by the junction or knot of the Himalayas, Tian Shan, Karakoram, Kunlun, and Hindu Kush ranges. They are among the world’s highest mountains and since Victorian times they have been known as the "Roof of the World" a probable...

 of Tajikistan
Tajikistan
Tajikistan , officially the Republic of Tajikistan , is a mountainous landlocked country in Central Asia. Afghanistan borders it to the south, Uzbekistan to the west, Kyrgyzstan to the north, and China to the east....

, and the Taymyr
Taymyr Peninsula
The Taymyr Peninsula is a peninsula in the Far North of Russia, in the Siberian Federal District, that forms the northernmost part of mainland Eurasia and Asia...

 region of northern Siberia
Siberia
Siberia is an extensive region constituting almost all of Northern Asia. Comprising the central and eastern portion of the Russian Federation, it was part of the Soviet Union from its beginning, as its predecessor states, the Tsardom of Russia and the Russian Empire, conquered it during the 16th...

. It is one of two humite
Humite
Humite is a mineral found in the volcanically ejected masses of Vesuvius. It was first described in 1813 and named for Abraham Hume .-See also:* Jerrygibbsite* Chondrodite* Clinohumite* Alleghanyite...

 group minerals that have been cut into gems, the other being the much more common chondrodite
Chondrodite
Chondrodite is a nesosilicate mineral with formula 522. Although it is a fairly rare mineral, it is the most frequently encountered member of the humite group of minerals. It is formed in hydrothermal deposits from locally metamorphosed dolomite. It is also found associated with skarn and...

.

Properties

A monoclinic mineral, clinohumite is typically a dark to light brownish or orangy yellow, somewhat resembling the hessonite
Hessonite
Hessonite or Cinnamon Stone is a variety of grossular, a calcium aluminium mineral of the garnet group with the general formula Ca3Al2Si3O12. The name is from the Greek hēssōn, inferior, in allusion to its lower hardness and density than most other garnet species varieties.It has a characteristic...

 variety of grossular. Clinohumite's crystal habit
Crystal habit
Crystal habit is an overall description of the visible external shape of a mineral. This description can apply to an individual crystal or an assembly of crystals or aggregates....

 is usually granular, but may also be prismatic
Prism (geometry)
In geometry, a prism is a polyhedron with an n-sided polygonal base, a translated copy , and n other faces joining corresponding sides of the two bases. All cross-sections parallel to the base faces are the same. Prisms are named for their base, so a prism with a pentagonal base is called a...

; crystals are almost always small. Simple and multiple crystal twinning
Crystal twinning
Crystal twinning occurs when two separate crystals share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals in a variety of specific configurations. A twin boundary or composition surface separates the two crystals....

 (on {001}) is common, resulting in a highly variable habit. Clinohumite is brittle with a hardness
Mohs scale of mineral hardness
The Mohs scale of mineral hardness characterizes the scratch resistance of various minerals through the ability of a harder material to scratch a softer material. It was created in 1812 by the German geologist and mineralogist Friedrich Mohs and is one of several definitions of hardness in...

 of 6 and a poor basal cleavage
Cleavage (crystal)
Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite crystallographic structural planes. These planes of relative weakness are a result of the regular locations of atoms and ions in the crystal, which create smooth repeating surfaces that are visible both in the...

. Its specific gravity
Specific gravity
Specific gravity is the ratio of the density of a substance to the density of a reference substance. Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is nearly always water for...

 is 3.2–3.4, and its fracture
Fracture
A fracture is the separation of an object or material into two, or more, pieces under the action of stress.The word fracture is often applied to bones of living creatures , or to crystals or crystalline materials, such as gemstones or metal...

 is conchoidal to uneven; its streak is white.

Clinohumite's transparency ranges from transparent to translucent; its luster
Lustre (mineralogy)
Lustre is a description of the way light interacts with the surface of a crystal, rock, or mineral. The word lustre traces its origins back to the Latin word lux, meaning "light", and generally implies radiance, gloss, or brilliance....

 ranges from a dull vitreous to resinous. Its refractive index
Refractive index
In optics the refractive index or index of refraction of a substance or medium is a measure of the speed of light in that medium. It is expressed as a ratio of the speed of light in vacuum relative to that in the considered medium....

 (as measured via sodium light, 589.3 nm) is as follows: α 1.631; β 1.638–1.647; γ 1.668;, with a maximum birefringence
Birefringence
Birefringence, or double refraction, is the decomposition of a ray of light into two rays when it passes through certain anisotropic materials, such as crystals of calcite or boron nitride. The effect was first described by the Danish scientist Rasmus Bartholin in 1669, who saw it in calcite...

 of 0.028 (biaxial positive). Under shortwave ultraviolet
Ultraviolet
Ultraviolet light is electromagnetic radiation with a wavelength shorter than that of visible light, but longer than X-rays, in the range 10 nm to 400 nm, and energies from 3 eV to 124 eV...

 light, some clinohumite may fluoresce an orangy yellow; there is little to no response under longwave UV.

The Taymyr material is reported to be a dark reddish brown while the Pamir material is a bright yellow to orange or brownish orange. The Pamir material also has a hardness slightly greater than 6, a lower specific gravity (3.18), and higher maximum birefringence (0.036). Phillip Youngman, master facet
Facet
Facets are flat faces on geometric shapes. The organization of naturally occurring facets was key to early developments in crystallography, since they reflect the underlying symmetry of the crystal structure...

er of Los Osos, California
California
California is a state located on the West Coast of the United States. It is by far the most populous U.S. state, and the third-largest by land area...

, noticed not only that Pamir material is harder than expected, but also that it is less brittle than expected. Youngman observed that clinohumite reacted like beryl
Beryl
The mineral beryl is a beryllium aluminium cyclosilicate with the chemical formula Be3Al26. The hexagonal crystals of beryl may be very small or range to several meters in size. Terminated crystals are relatively rare...

 to cutting and polishing, and that it reminded him of polishing diopside
Diopside
Diopside is a monoclinic pyroxene mineral with composition MgCaSi2O6. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class...

.

Like other members of the humite group, the relative amounts of hydroxyl
Hydroxyl
A hydroxyl is a chemical group containing an oxygen atom covalently bonded with a hydrogen atom. In inorganic chemistry, the hydroxyl group is known as the hydroxide ion, and scientists and reference works generally use these different terms though they refer to the same chemical structure in...

 and fluorine
Fluorine
Fluorine is the chemical element with atomic number 9, represented by the symbol F. It is the lightest element of the halogen column of the periodic table and has a single stable isotope, fluorine-19. At standard pressure and temperature, fluorine is a pale yellow gas composed of diatomic...

 vary in clinohumite, and iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

 commonly substitutes for some of the magnesium, bringing about changes in physical and optical properties. Titanium
Titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. It has a low density and is a strong, lustrous, corrosion-resistant transition metal with a silver color....

 substitution also causes pronounced changes in optical properties, producing the variety titanclinohumite. Consequently, it is relatively easy to determine that a stone is a humite group mineral, but difficult to determine exactly which member. Other common impurities of clinohumite include aluminium
Aluminium
Aluminium or aluminum is a silvery white member of the boron group of chemical elements. It has the symbol Al, and its atomic number is 13. It is not soluble in water under normal circumstances....

, manganese
Manganese
Manganese is a chemical element, designated by the symbol Mn. It has the atomic number 25. It is found as a free element in nature , and in many minerals...

, and calcium
Calcium
Calcium is the chemical element with the symbol Ca and atomic number 20. It has an atomic mass of 40.078 amu. Calcium is a soft gray alkaline earth metal, and is the fifth-most-abundant element by mass in the Earth's crust...

.

Formation and occurrence

Clinohumite is a product of contact metamorphism and is commonly found as indistinct grains embedded in limestone
Limestone
Limestone is a sedimentary rock composed largely of the minerals calcite and aragonite, which are different crystal forms of calcium carbonate . Many limestones are composed from skeletal fragments of marine organisms such as coral or foraminifera....

. Its type occurrence is within the limestone ejecta of the Mount Vesuvius
Mount Vesuvius
Mount Vesuvius is a stratovolcano in the Gulf of Naples, Italy, about east of Naples and a short distance from the shore. It is the only volcano on the European mainland to have erupted within the last hundred years, although it is not currently erupting...

 volcano complex near Naples, Italy
Italy
Italy , officially the Italian Republic languages]] under the European Charter for Regional or Minority Languages. In each of these, Italy's official name is as follows:;;;;;;;;), is a unitary parliamentary republic in South-Central Europe. To the north it borders France, Switzerland, Austria and...

, where clinohumite was discovered in 1876. The aforementioned gem-quality occurrences of Pamir and Taymyr were discovered only recently: the former in the early 1980s, and the latter in 2000. These deposits are scarce and only sporadically mined, so clinohumite remains one of the rarest gemstones with only a few thousand carats known to exist in private collections.

Other (non-gem quality) occurrences of clinohumite include: the Sør Rondane
Sor Rondane Mountains
The Sør Rondane Mountains are a group of mountains about 100 miles long with main peaks rising to 3, 400 m, between the Queen Fabiola Mountains and Wohlthat Mountains in Queen Maud Land. They were discovered and photographed from the air by members of the Lars Christensen Expedition on February 6,...

 and Balchen Mountain
Balchen Mountain
Balchen Mountain is a mountain, high, standing at the east side of Byrdbreen in the Sør Rondane Mountains. It was mapped by Norwegian cartographers in 1957 from air photos taken by U.S. Navy Operation Highjump, 1946–47, and named for Bernt Balchen, famous Norwegian polar aviator and chief pilot...

s of Antarctica; Mount Bischoff, Waratah, Tasmania
Waratah, Tasmania
Waratah is a town in western Tasmania. It was constructed to support a tin mine at Mount Bischoff. The town is built at the top of a waterfall, and water was diverted from the stream to provide water for mine sluicing and processing. At the 2006 census, Waratah had a population of 227.Tin was...

; the Saualpe Mountains of Carinthia
Carinthia (state)
Carinthia is the southernmost Austrian state or Land. Situated within the Eastern Alps it is chiefly noted for its mountains and lakes.The main language is German. Its regional dialects belong to the Southern Austro-Bavarian group...

, the Koralpe
Koralpe
The Koralpe, also referred to as Koralm, is a mountain range in southern Austria which separates eastern Carinthia from southern Styria. Running from north to south, it drains to the river Lavant in the west, and to the river Sulm in the east...

 mountains of Styria
Styria (state)
Styria is a state or Bundesland, located in the southeast of Austria. In area it is the second largest of the nine Austrian federated states, covering 16,401 km². It borders Slovenia as well as the other Austrian states of Upper Austria, Lower Austria, Salzburg, Burgenland, and Carinthia. ...

, and the Vals, Virgen, and Ziller valleys of the Tyrol, Austria
Austria
Austria , officially the Republic of Austria , is a landlocked country of roughly 8.4 million people in Central Europe. It is bordered by the Czech Republic and Germany to the north, Slovakia and Hungary to the east, Slovenia and Italy to the south, and Switzerland and Liechtenstein to the...

; the Jacupiranga mine of Cajati
Cajati
Cajati is a municipality in the state of São Paulo in Brazil. The population in 2003 is 32,091 and the area is 455.97 km². The elevation is 75 m....

, São Paulo State, Southeast Region
Southeast Region, Brazil
The Southeast Region of Brazil is composed by the states of Espírito Santo, Minas Gerais, Rio de Janeiro and São Paulo. It is the richest region of the country, responsible for approximately 60% of the Brazilian GDP. São Paulo, Rio de Janeiro and Minas Gerais are three richest states of Brazil,...

, Brazil
Brazil
Brazil , officially the Federative Republic of Brazil , is the largest country in South America. It is the world's fifth largest country, both by geographical area and by population with over 192 million people...

; the Pirin Mountains of Bulgaria
Bulgaria
Bulgaria , officially the Republic of Bulgaria , is a parliamentary democracy within a unitary constitutional republic in Southeast Europe. The country borders Romania to the north, Serbia and Macedonia to the west, Greece and Turkey to the south, as well as the Black Sea to the east...

; Bancroft, Ontario
Bancroft, Ontario
Bancroft is a town located on the York River in Hastings County in the Canadian province of Ontario.- History :In 1853 the first pioneer family settled in the area, and over the next 15 years the settlement grew quickly, as another 88 families followed...

, Notre Dame du Laus, Wakefield
Wakefield, Quebec
Wakefield is a village on the western shore of the Gatineau River, at the confluence of the La Pêche River in the Outaouais region of Quebec. The village, named after the town of Wakefield in West Yorkshire, England, is now the southern edge of the municipality of La Pêche, and was founded in 1830...

, and Villedieu Township, Quebec
Quebec
Quebec or is a province in east-central Canada. It is the only Canadian province with a predominantly French-speaking population and the only one whose sole official language is French at the provincial level....

, Canada
Canada
Canada is a North American country consisting of ten provinces and three territories. Located in the northern part of the continent, it extends from the Atlantic Ocean in the east to the Pacific Ocean in the west, and northward into the Arctic Ocean...

; Southern
Southern Finland
Southern Finland was a province of Finland from 1997 to 2010. It bordered the provinces of Western Finland and Eastern Finland. It also bordered the Gulf of Finland and Russia.- History :...

 and Western Finland
Western Finland
Western Finland was a province of Finland from 1997 to 2010. It bordered the provinces of Oulu, Eastern Finland and Southern Finland. It also bordered the Gulf of Bothnia towards Åland.- History :...

; Bavaria
Bavaria
Bavaria, formally the Free State of Bavaria is a state of Germany, located in the southeast of Germany. With an area of , it is the largest state by area, forming almost 20% of the total land area of Germany...

 and Saxony
Saxony
The Free State of Saxony is a landlocked state of Germany, contingent with Brandenburg, Saxony Anhalt, Thuringia, Bavaria, the Czech Republic and Poland. It is the tenth-largest German state in area, with of Germany's sixteen states....

, Germany
Germany
Germany , officially the Federal Republic of Germany , is a federal parliamentary republic in Europe. The country consists of 16 states while the capital and largest city is Berlin. Germany covers an area of 357,021 km2 and has a largely temperate seasonal climate...

; eastern Greenland
Greenland
Greenland is an autonomous country within the Kingdom of Denmark, located between the Arctic and Atlantic Oceans, east of the Canadian Arctic Archipelago. Though physiographically a part of the continent of North America, Greenland has been politically and culturally associated with Europe for...

; Ambasamudram
Ambasamudram
Ambasamudram is a taluk in Tirunelveli district in the state of Tamil Nadu, India. The entire taluk had a population of 392,226 as of 2001, with 42.5% classified as rural. The taluk is named for the principal town with the same name...

 in Tamil Nadu
Tamil Nadu
Tamil Nadu is one of the 28 states of India. Its capital and largest city is Chennai. Tamil Nadu lies in the southernmost part of the Indian Peninsula and is bordered by the union territory of Pondicherry, and the states of Kerala, Karnataka, and Andhra Pradesh...

, India
India
India , officially the Republic of India , is a country in South Asia. It is the seventh-largest country by geographical area, the second-most populous country with over 1.2 billion people, and the most populous democracy in the world...

; Honshū
Honshu
is the largest island of Japan. The nation's main island, it is south of Hokkaido across the Tsugaru Strait, north of Shikoku across the Inland Sea, and northeast of Kyushu across the Kanmon Strait...

, Japan
Japan
Japan is an island nation in East Asia. Located in the Pacific Ocean, it lies to the east of the Sea of Japan, China, North Korea, South Korea and Russia, stretching from the Sea of Okhotsk in the north to the East China Sea and Taiwan in the south...

; Suan, North Korea; Nordland
Nordland
is a county in Norway in the North Norway region, bordering Troms in the north, Nord-Trøndelag in the south, Norrbottens län in Sweden to the east, Västerbottens län to the southeast, and the Atlantic Ocean to the west. The county was formerly known as Nordlandene amt. The county administration is...

, Norway
Norway
Norway , officially the Kingdom of Norway, is a Nordic unitary constitutional monarchy whose territory comprises the western portion of the Scandinavian Peninsula, Jan Mayen, and the Arctic archipelago of Svalbard and Bouvet Island. Norway has a total area of and a population of about 4.9 million...

; KwaZulu-Natal and Northern Cape Province, South Africa
South Africa
The Republic of South Africa is a country in southern Africa. Located at the southern tip of Africa, it is divided into nine provinces, with of coastline on the Atlantic and Indian oceans...

; Andalusia
Andalusia
Andalusia is the most populous and the second largest in area of the autonomous communities of Spain. The Andalusian autonomous community is officially recognised as a nationality of Spain. The territory is divided into eight provinces: Huelva, Seville, Cádiz, Córdoba, Málaga, Jaén, Granada and...

, Spain
Spain
Spain , officially the Kingdom of Spain languages]] under the European Charter for Regional or Minority Languages. In each of these, Spain's official name is as follows:;;;;;;), is a country and member state of the European Union located in southwestern Europe on the Iberian Peninsula...

; Värmland
Värmland
' is a historical province or landskap in the west of middle Sweden. It borders Västergötland, Dalsland, Dalarna, Västmanland and Närke. It is also bounded by Norway in the west. Latin name versions are Vermelandia and Wermelandia. Although the province's land originally was Götaland, the...

 and Västmanland
Västmanland
' is a historical Swedish province, or landskap, in middle Sweden. It borders Södermanland, Närke, Värmland, Dalarna and Uppland.The name comes from "West men", referring to the people west of Uppland, the core province of early Sweden.- Administration :...

, Sweden
Sweden
Sweden , officially the Kingdom of Sweden , is a Nordic country on the Scandinavian Peninsula in Northern Europe. Sweden borders with Norway and Finland and is connected to Denmark by a bridge-tunnel across the Öresund....

; Isle of Skye, Scotland
Scotland
Scotland is a country that is part of the United Kingdom. Occupying the northern third of the island of Great Britain, it shares a border with England to the south and is bounded by the North Sea to the east, the Atlantic Ocean to the north and west, and the North Channel and Irish Sea to the...

; and the states of California
California
California is a state located on the West Coast of the United States. It is by far the most populous U.S. state, and the third-largest by land area...

, Colorado
Colorado
Colorado is a U.S. state that encompasses much of the Rocky Mountains as well as the northeastern portion of the Colorado Plateau and the western edge of the Great Plains...

, Massachusetts
Massachusetts
The Commonwealth of Massachusetts is a state in the New England region of the northeastern United States of America. It is bordered by Rhode Island and Connecticut to the south, New York to the west, and Vermont and New Hampshire to the north; at its east lies the Atlantic Ocean. As of the 2010...

, New Jersey
New Jersey
New Jersey is a state in the Northeastern and Middle Atlantic regions of the United States. , its population was 8,791,894. It is bordered on the north and east by the state of New York, on the southeast and south by the Atlantic Ocean, on the west by Pennsylvania and on the southwest by Delaware...

, New Mexico
New Mexico
New Mexico is a state located in the southwest and western regions of the United States. New Mexico is also usually considered one of the Mountain States. With a population density of 16 per square mile, New Mexico is the sixth-most sparsely inhabited U.S...

, New York
New York
New York is a state in the Northeastern region of the United States. It is the nation's third most populous state. New York is bordered by New Jersey and Pennsylvania to the south, and by Connecticut, Massachusetts and Vermont to the east...

, Oklahoma
Oklahoma
Oklahoma is a state located in the South Central region of the United States of America. With an estimated 3,751,351 residents as of the 2010 census and a land area of 68,667 square miles , Oklahoma is the 28th most populous and 20th-largest state...

, Utah
Utah
Utah is a state in the Western United States. It was the 45th state to join the Union, on January 4, 1896. Approximately 80% of Utah's 2,763,885 people live along the Wasatch Front, centering on Salt Lake City. This leaves vast expanses of the state nearly uninhabited, making the population the...

, and Washington, USA
United States
The United States of America is a federal constitutional republic comprising fifty states and a federal district...

.

Clinohumite also occurs as a minor component of some masses of peridotite
Peridotite
A peridotite is a dense, coarse-grained igneous rock, consisting mostly of the minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium, reflecting the high proportions of magnesium-rich olivine, with appreciable iron...

 from the Earth's mantle emplaced into the Earth's crust and as a very rare component of peridotite xenolith
Xenolith
A xenolith is a rock fragment which becomes enveloped in a larger rock during the latter's development and hardening. In geology, the term xenolith is almost exclusively used to describe inclusions in igneous rock during magma emplacement and eruption...

s. These occurrences and implications have been summarized by Luth (2003) in a discussion of the possible importance of the mineral as a significant reservoir of water in the Earth's mantle. Titanium
Titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. It has a low density and is a strong, lustrous, corrosion-resistant transition metal with a silver color....

is a minor constituent of clinohumite in most such occurrences.
The source of this article is wikipedia, the free encyclopedia.  The text of this article is licensed under the GFDL.
 
x
OK