Carnallite
Encyclopedia
Carnallite is an evaporite
mineral, a hydrated potassium
magnesium
chloride
with formula: K
Mg
Cl
3·6(H2O
). It is variably colored yellow to white, reddish, and sometimes colorless or blue. It is usually massive to fibrous with rare pseudohexagonal orthorhombic crystals. The mineral is deliquescent (absorbs moisture from the surrounding air) and specimens must be stored in an airtight container.
Carnallite occurs with a sequence of potassium and magnesium evaporite minerals sylvite
, kainite
, picromerite, polyhalite
and kieserite
. Carnallite is a somewhat rare double chloride mineral which only forms under a specific environmental conditions in an evaporating sea or sedimentary basin
. It is mined for both potassium and magnesium and occurs in the evaporite deposits of Carlsbad, New Mexico
; the Paradox Basin
in Colorado
and Utah
; Stassfurt, Germany
; the Perm Basin, Russia
; and the Williston Basin
in Saskatchewan, Canada. These deposits date from the Devonian
through the Permian
Periods. In contrast, both Israel
and Jordan
produce potash
from the Dead Sea
by using evaporation pans to further concentrate the brine until carnallite precipitates, dredging the carnallite from the pans, and processing to remove the magnesium chloride
from the potassium chloride
.
Carnallite was first described in 1856 from its type location of Stassfurt Deposit, Saxony-Anhalt
, Germany
. It was named for the Prussia
n mining engineer
, Rudolf von Carnall (1804–1874).
Evaporite
Evaporite is a name for a water-soluble mineral sediment that result from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporate deposits, marine which can also be described as ocean deposits, and non-marine which are found in standing bodies of...
mineral, a hydrated potassium
Potassium
Potassium is the chemical element with the symbol K and atomic number 19. Elemental potassium is a soft silvery-white alkali metal that oxidizes rapidly in air and is very reactive with water, generating sufficient heat to ignite the hydrogen emitted in the reaction.Potassium and sodium are...
magnesium
Magnesium
Magnesium is a chemical element with the symbol Mg, atomic number 12, and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust and ninth in the known universe as a whole...
chloride
Chloride
The chloride ion is formed when the element chlorine, a halogen, picks up one electron to form an anion Cl−. The salts of hydrochloric acid HCl contain chloride ions and can also be called chlorides. The chloride ion, and its salts such as sodium chloride, are very soluble in water...
with formula: K
Potassium
Potassium is the chemical element with the symbol K and atomic number 19. Elemental potassium is a soft silvery-white alkali metal that oxidizes rapidly in air and is very reactive with water, generating sufficient heat to ignite the hydrogen emitted in the reaction.Potassium and sodium are...
Mg
Magnesium
Magnesium is a chemical element with the symbol Mg, atomic number 12, and common oxidation number +2. It is an alkaline earth metal and the eighth most abundant element in the Earth's crust and ninth in the known universe as a whole...
Cl
Chlorine
Chlorine is the chemical element with atomic number 17 and symbol Cl. It is the second lightest halogen, found in the periodic table in group 17. The element forms diatomic molecules under standard conditions, called dichlorine...
3·6(H2O
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...
). It is variably colored yellow to white, reddish, and sometimes colorless or blue. It is usually massive to fibrous with rare pseudohexagonal orthorhombic crystals. The mineral is deliquescent (absorbs moisture from the surrounding air) and specimens must be stored in an airtight container.
Carnallite occurs with a sequence of potassium and magnesium evaporite minerals sylvite
Sylvite
Sylvite is potassium chloride in natural mineral form. It forms crystals in the isometric system very similar to normal rock salt, halite . The two are, in fact, isomorphous. Sylvite is colorless to white with shades of yellow and red due to inclusions. It has a Mohs hardness of 2.5 and a specific...
, kainite
Kainite
Kainite is a mineral salt that consists of potassium chloride and magnesium sulfate and is used as a fertilizer. This mineral is dull and soft, is colored white through yellow to red and is found in the Stassfurt salt mines in Saxony, Germany...
, picromerite, polyhalite
Polyhalite
Polyhalite is an evaporite mineral, a hydrated sulfate of potassium, calcium and magnesium with formula: K2Ca2Mg4·2. Polyhalite crystallizes in the triclinic system although crystals are very rare. The normal habit is massive to fibrous. It is typically colorless, white to gray, although it...
and kieserite
Kieserite
Kieserite is a highly unstable magnesium sulfate mineral . It has a vitreous luster and it is colorless, grayish-white or yellowish. Its hardness is 3.5 and it has a monoclinic crystal system...
. Carnallite is a somewhat rare double chloride mineral which only forms under a specific environmental conditions in an evaporating sea or sedimentary basin
Sedimentary basin
The term sedimentary basin is used to refer to any geographical feature exhibiting subsidence and consequent infilling by sedimentation. As the sediments are buried, they are subjected to increasing pressure and begin the process of lithification...
. It is mined for both potassium and magnesium and occurs in the evaporite deposits of Carlsbad, New Mexico
Carlsbad, New Mexico
Carlsbad is a city in and the county seat of Eddy County, New Mexico, in the United States. As of the 2010 census, the city population was 26,138. Carlsbad is the center of the designated micropolitan area of Carlsbad-Artesia, which has a total population of 55,435...
; the Paradox Basin
Paradox Basin
The Paradox Basin is an asymmetric foreland basin located mostly in southeast Utah and southwest Colorado, but extending into northeast Arizona and northwest New Mexico. The basin is a large elongate northwest to southeast oriented depression formed during the late Paleozoic Era...
in Colorado
Colorado
Colorado is a U.S. state that encompasses much of the Rocky Mountains as well as the northeastern portion of the Colorado Plateau and the western edge of the Great Plains...
and Utah
Utah
Utah is a state in the Western United States. It was the 45th state to join the Union, on January 4, 1896. Approximately 80% of Utah's 2,763,885 people live along the Wasatch Front, centering on Salt Lake City. This leaves vast expanses of the state nearly uninhabited, making the population the...
; Stassfurt, Germany
Germany
Germany , officially the Federal Republic of Germany , is a federal parliamentary republic in Europe. The country consists of 16 states while the capital and largest city is Berlin. Germany covers an area of 357,021 km2 and has a largely temperate seasonal climate...
; the Perm Basin, Russia
Russia
Russia or , officially known as both Russia and the Russian Federation , is a country in northern Eurasia. It is a federal semi-presidential republic, comprising 83 federal subjects...
; and the Williston Basin
Williston Basin
The Williston Basin is a large intracratonic sedimentary basin in eastern Montana, western North and South Dakota, and southern Saskatchewan known for its rich deposits of petroleum and potash. The basin is a geologic structural basin but not a topographic depression; it is transected by the...
in Saskatchewan, Canada. These deposits date from the Devonian
Devonian
The Devonian is a geologic period and system of the Paleozoic Era spanning from the end of the Silurian Period, about 416.0 ± 2.8 Mya , to the beginning of the Carboniferous Period, about 359.2 ± 2.5 Mya...
through the Permian
Permian
The PermianThe term "Permian" was introduced into geology in 1841 by Sir Sir R. I. Murchison, president of the Geological Society of London, who identified typical strata in extensive Russian explorations undertaken with Edouard de Verneuil; Murchison asserted in 1841 that he named his "Permian...
Periods. In contrast, both Israel
Israel
The State of Israel is a parliamentary republic located in the Middle East, along the eastern shore of the Mediterranean Sea...
and Jordan
Jordan
Jordan , officially the Hashemite Kingdom of Jordan , Al-Mamlaka al-Urduniyya al-Hashemiyya) is a kingdom on the East Bank of the River Jordan. The country borders Saudi Arabia to the east and south-east, Iraq to the north-east, Syria to the north and the West Bank and Israel to the west, sharing...
produce potash
Potash
Potash is the common name for various mined and manufactured salts that contain potassium in water-soluble form. In some rare cases, potash can be formed with traces of organic materials such as plant remains, and this was the major historical source for it before the industrial era...
from the Dead Sea
Dead Sea
The Dead Sea , also called the Salt Sea, is a salt lake bordering Jordan to the east and Israel and the West Bank to the west. Its surface and shores are below sea level, the lowest elevation on the Earth's surface. The Dead Sea is deep, the deepest hypersaline lake in the world...
by using evaporation pans to further concentrate the brine until carnallite precipitates, dredging the carnallite from the pans, and processing to remove the magnesium chloride
Magnesium chloride
Magnesium chloride is the name for the chemical compounds with the formulas MgCl2 and its various hydrates MgCl2x. These salts are typical ionic halides, being highly soluble in water. The hydrated magnesium chloride can be extracted from brine or sea water...
from the potassium chloride
Potassium chloride
The chemical compound potassium chloride is a metal halide salt composed of potassium and chlorine. In its pure state, it is odorless and has a white or colorless vitreous crystal appearance, with a crystal structure that cleaves easily in three directions. Potassium chloride crystals are...
.
Carnallite was first described in 1856 from its type location of Stassfurt Deposit, Saxony-Anhalt
Saxony-Anhalt
Saxony-Anhalt is a landlocked state of Germany. Its capital is Magdeburg and it is surrounded by the German states of Lower Saxony, Brandenburg, Saxony, and Thuringia.Saxony-Anhalt covers an area of...
, Germany
Germany
Germany , officially the Federal Republic of Germany , is a federal parliamentary republic in Europe. The country consists of 16 states while the capital and largest city is Berlin. Germany covers an area of 357,021 km2 and has a largely temperate seasonal climate...
. It was named for the Prussia
Prussia
Prussia was a German kingdom and historic state originating out of the Duchy of Prussia and the Margraviate of Brandenburg. For centuries, the House of Hohenzollern ruled Prussia, successfully expanding its size by way of an unusually well-organized and effective army. Prussia shaped the history...
n mining engineer
Engineer
An engineer is a professional practitioner of engineering, concerned with applying scientific knowledge, mathematics and ingenuity to develop solutions for technical problems. Engineers design materials, structures, machines and systems while considering the limitations imposed by practicality,...
, Rudolf von Carnall (1804–1874).