Calcium acetate
Encyclopedia
The chemical compound
Chemical compound
A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together...

 calcium acetate is the calcium
Calcium
Calcium is the chemical element with the symbol Ca and atomic number 20. It has an atomic mass of 40.078 amu. Calcium is a soft gray alkaline earth metal, and is the fifth-most-abundant element by mass in the Earth's crust...

 salt of acetic acid
Acetic acid
Acetic acid is an organic compound with the chemical formula CH3CO2H . It is a colourless liquid that when undiluted is also called glacial acetic acid. Acetic acid is the main component of vinegar , and has a distinctive sour taste and pungent smell...

. It has the formula Ca(C2H3O2)2. Its standard name is calcium acetate, while calcium ethanoate is the systematic IUPAC name. An older name is acetate of lime. The anhydrous form is very hygroscopic; therefore the monohydrate
Hydrate
Hydrate is a term used in inorganic chemistry and organic chemistry to indicate that a substance contains water. The chemical state of the water varies widely between hydrates, some of which were so labeled before their chemical structure was understood....

 (Ca(CH3COO)2•H2O, CAS [5743-26-0]) is the common form.

If an alcohol is added to a saturated solution of calcium acetate, a semisolid, flammable gel forms that is much like "canned heat" products such as Sterno.
Chemistry teachers often prepare "California Snowballs", a mixture of calcium acetate solution and ethanol
Ethanol
Ethanol, also called ethyl alcohol, pure alcohol, grain alcohol, or drinking alcohol, is a volatile, flammable, colorless liquid. It is a psychoactive drug and one of the oldest recreational drugs. Best known as the type of alcohol found in alcoholic beverages, it is also used in thermometers, as a...

. The resulting gel is whitish in color, and can be formed to resemble a snowball
Snowball
A snowball is a spherical object made from snow, usually created by scooping snow with the hands, and compacting it into a roughly fist-sized ball. The snowball is often used to engage in games, such as snowball fights. Snowball fights are usually light-hearted and involve throwing snowballs at...

.

Calclacite is a name for calcium acetate chloride pentahydrate, which is treated as mineral species but possess anthropogenic origin.

History

Because it is inexpensive, calcium acetate was once a common starting material for the synthesis of acetone
Acetone
Acetone is the organic compound with the formula 2CO, a colorless, mobile, flammable liquid, the simplest example of the ketones.Acetone is miscible with water and serves as an important solvent in its own right, typically as the solvent of choice for cleaning purposes in the laboratory...

 before the development of the cumene process
Cumene process
The Cumene process is an industrial process for developing phenol and acetone from benzene and propylene. The term stems from cumene , the intermediate material during the process. It was invented by Heinrich Hock in 1944 and independently by R. Ūdris and P...

.
Calcium acetate can be prepared by soaking calcium carbonate (found in eggshells, or in common carbonate rocks such as limestone
Limestone
Limestone is a sedimentary rock composed largely of the minerals calcite and aragonite, which are different crystal forms of calcium carbonate . Many limestones are composed from skeletal fragments of marine organisms such as coral or foraminifera....

 or marble
Marble
Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or dolomite.Geologists use the term "marble" to refer to metamorphosed limestone; however stonemasons use the term more broadly to encompass unmetamorphosed limestone.Marble is commonly used for...

) in vinegar. Since both reagents would have been available pre-historically, the chemical
would have been observable as crystals then.

Uses

In kidney disease, blood levels of phosphate
Phosphate
A phosphate, an inorganic chemical, is a salt of phosphoric acid. In organic chemistry, a phosphate, or organophosphate, is an ester of phosphoric acid. Organic phosphates are important in biochemistry and biogeochemistry or ecology. Inorganic phosphates are mined to obtain phosphorus for use in...

 may rise (called hyperphosphatemia
Hyperphosphatemia
Hyperphosphatemia is an electrolyte disturbance in which there is an abnormally elevated level of phosphate in the blood. Often, calcium levels are lowered due to precipitation of phosphate with the calcium in tissues.-Signs and symptoms:...

) leading to bone problems. Calcium acetate binds phosphate in the diet to lower blood phosphate levels. Side effects of this treatment include upset stomach.

Calcium acetate is used as a food additive
Food additive
Food additives are substances added to food to preserve flavor or enhance its taste and appearance.Some additives have been used for centuries; for example, preserving food by pickling , salting, as with bacon, preserving sweets or using sulfur dioxide as in some wines...

, as a stabilizer, buffer and sequestrant, mainly in candy products. It also neutralizes fluoride in water.
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