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Automobile emissions control

 

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Automobile emissions control



 
 
Automobile emissions control covers all the technologies that are employed to reduce the air pollution
Air pollution

Air pollution is the introduction of chemicals, particulate matter, or biological materials that cause harm or discomfort to humans or other living organisms, or damages the natural environment, into the Earth's atmosphere....
-causing emissions produced by automobile
Automobile

An automobile or motor car is a wheeled motor vehicle for transportation passengers, which also carries its own car engine or motor. Most definitions of the term specify that automobiles are designed to run primarily on roads, to have seating for one to eight people, to typically have four wheels, and to be constructed principally f...
s. The first effort at controlling pollution from automobiles was the PCV (positive crankcase ventilation)
PCV valve

The Positive Crankcase Ventilation valve, or PCV valve, is a Check valve that ensures continual evacuation of gases from inside a gasoline internal combustion engine's crankcase....
 system. This draws crankcase fumes heavy in unburned hydrocarbons — a precursor to photochemical smog — into the engine's intake tract so they are burned rather than released unburned from the crankcase into the atmosphere.






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Automobile emissions control covers all the technologies that are employed to reduce the air pollution
Air pollution

Air pollution is the introduction of chemicals, particulate matter, or biological materials that cause harm or discomfort to humans or other living organisms, or damages the natural environment, into the Earth's atmosphere....
-causing emissions produced by automobile
Automobile

An automobile or motor car is a wheeled motor vehicle for transportation passengers, which also carries its own car engine or motor. Most definitions of the term specify that automobiles are designed to run primarily on roads, to have seating for one to eight people, to typically have four wheels, and to be constructed principally f...
s. The first effort at controlling pollution from automobiles was the PCV (positive crankcase ventilation)
PCV valve

The Positive Crankcase Ventilation valve, or PCV valve, is a Check valve that ensures continual evacuation of gases from inside a gasoline internal combustion engine's crankcase....
 system. This draws crankcase fumes heavy in unburned hydrocarbons — a precursor to photochemical smog — into the engine's intake tract so they are burned rather than released unburned from the crankcase into the atmosphere. Positive crankcase ventilation was first installed on a widespread basis by law on all new 1961-model
Model year

The model year of a product is a number used in North America to describe approximately when a product was produced.The model year and the actual calendar year of production do not always coincide....
 cars first sold in California
California

California is a U.S. state on the West Coast of the United States of the United States, along the Pacific Ocean. It is bordered by Oregon to the north, Nevada to the east, Arizona to the southeast, and to the south the Mexico state of Baja California....
. The following year, New York
New York

The State of New York is a U.S. state in the Mid-Atlantic States and Northeastern United States regions of the United States and is the nation's List of U.S....
 required it. By 1964, most new cars sold in the U.S. were so equipped, and PCV quickly became standard equipment on all vehicles worldwide.

The first legislated exhaust (tailpipe) emission standards were promulgated by the State of California for 1966 model year for cars sold in that state, followed by the United States as a whole in model year 1968. The standards were progressively tightened year by year, as legislated by the U.S. EPA
United States Environmental Protection Agency

The U.S. Environmental Protection Agency is an List of United States federal agencies of the federal government of the United States charged to Regulation of chemicals and protect human health by safeguarding the natural environment: air, water, and land....
.

By the 1974 model year, the emission standards had tightened such that the de-tuning techniques used to meet them were seriously reducing engine efficiency and thus increasing fuel usage. The new emission standards for 1975 model year, as well as the increase in fuel usage, forced the invention of the catalytic converter
Catalytic converter

A catalytic converter is a device used to reduce the toxicity of emissions from an internal combustion engine. First widely introduced on Mass production automobiles in the United States market for the 1975 model year to comply with tightening United States Environmental Protection Agency regulations on auto exhaust, catalytic converters a...
 for after-treatment of the exhaust gas. This was not possible with existing leaded gasoline, because the lead residue contaminated the platinum catalyst. In 1972, General Motors proposed to the American Petroleum Institute the elimination of leaded fuels for 1975 and later model year cars. The production and distribution of unleaded fuel was a major challenge, but it was completed successfully in time for the 1975 model year cars. All modern cars are now equipped with catalytic converters and unleaded fuel can now be found almost everywhere.

The auto industry now uses about half the annual world-wide platinum production for catalytic converters.
The emissions produced by a vehicle fall into these basic categories:
  1. Tailpipe emissions: This is what most people think of when they think of vehicle air pollution; the products of burning fuel in the vehicle's engine
    Internal combustion engine

    The internal combustion engine is an engine in which the combustion of a fuel occurs in a combustion chamber inside and integral to the engine. In an internal combustion engine it is always the expansion of the high temperature and pressure gases that are produced by the combustion which apply force to the movable component of the engine, such as...
    , emitted from the vehicle's exhaust system. The major pollutants emitted include:
    1. Hydrocarbons: this class is made up of unburned or partially burned fuel, and is a major contributor to urban smog
      Smog

      Smog is a kind of air pollution; the word "smog" is a portmanteau of smoke and fog. Classic smog results from large amounts of coal burning in an area caused by a mixture of smoke and sulfur dioxide....
      , as well as being toxic. They can cause liver damage and even cancer.
    2. Nitrogen oxide
      Nitrogen oxide

      The term nitrogen oxide typically refers to any binary compound of oxygen and nitrogen, or to a mixture of such compounds:* Nitric oxide , nitrogen oxide...
      s (NOx
      Nox

      Nox may refer to:* Nox , the primordial goddess of the night in Greek mythology* Nox , a race in the television series Stargate SG-1* Nox , a video game developed by Westwood Studios...
      )
      : These are generated when nitrogen
      Nitrogen

      Nitrogen is a chemical element that has the symbol N and atomic number 7 and atomic mass 14.00674?. Elemental nitrogen is a colorless, odorless, tasteless and mostly inert diatomic gas at standard conditions, constituting 78% by volume of Earth's atmosphere....
       in the air reacts with oxygen under the high temperature and pressure conditions inside the engine. NOx emissions contribute to both smog and acid rain
      Acid rain

      Acid rain is rain or any other form of Precipitation that is unusually acidic. It has harmful effects on plants, aquatic animals, and infrastructure....
      .
    3. Carbon monoxide
      Carbon monoxide

      Carbon monoxide, with the chemical formula CO, is a colorless and odorless, tasteless, yet highly toxic gas. Its molecules consist of one carbon atom covalent bond to one oxygen atom....
       (CO)
      : a product of incomplete combustion, carbon monoxide reduces the blood's ability to carry oxygen and is dangerous to people with heart disease.
    4. Carbon dioxide
      Carbon dioxide

      Carbon dioxide is a chemical compound composed of two oxygen atoms covalent bond to a single carbon atom. It is a gas at standard temperature and pressure and exists in Earth's atmosphere in this state....
       (CO2)
      : Emissions of carbon dioxide are an increasing concern by some who believe it has a role in global warming as a greenhouse gas, but there is no known treatment to reduce carbon dioxide in the exhaust.
    5. Particulate
      Particulate

      Particulates, alternatively referred to as particulate matter or fine particles, are tiny particles of solid or liquid suspended in a gas or liquid....
      s. Particle of micrometre
      Micrometre

      A micrometre or micron is one Micro- of a metre, or equivalently one thousandth of a millimetre. It is also commonly known as a micron....
       size.
    6. Sulphur oxide (SOx) General term for oxides of sulphur, mostly sulfur dioxide
      Sulfur dioxide

      Sulfur dioxide is the chemical compound with the formula SO2. It is produced by volcanoes and in various industrial processes. Since coal and petroleum often contain sulfur compounds, their combustion generates sulfur dioxide....
       and some sulfur trioxide
      Sulfur trioxide

      Sulfur trioxide is the chemical compound with the formula SO3. In the gaseous form, this species is a significant pollutant, being the primary agent in acid rain....
      , from coal or unrefined oil.


Tailpipe emissions control

Methods of reducing exhaust emissions can be categorised into three parts:
  1. Increasing engine efficiency
  2. Increasing vehicle efficiency
  3. Cleaning up the emissions


Increasing engine efficiency

Engine efficiency has been gradually improved with major progress in following technologies:
  • Hybridization
    Hybrid electric vehicle

    A hybrid electric vehicle is a hybrid vehicle which combines a conventional ground propulsion system with a rechargeable energy storage system to achieve better fuel economy in automobiles than a conventional vehicle....
     of the drive train.
  • Electronic ignition
  • Fuel injection systems
  • Electronic control unit
    Electronic control unit

    In automotive electronics, an electronic control unit , also called a control unit, or control module, is an embedded system that controls one or more of the electrical systems or subsystems in a vehicle....


Increasing vehicle efficiency

Contributions to the goal of reducing fuel consumption and related emissions come from
  • lightweight vehicle design
  • minimized air resistance
  • reduced rolling resistance
  • improved powertrain efficiency
  • regenerative braking


Each of these items breaks down into a number of factors.

Increasing driving efficiency

Significant reduction of emissions come from
  • driving technique (some 10-30% reduction)
  • unobstructed traffic conditions
  • cruising at an optimum speed for the vehicle
  • reducing the number of cold starts


Cleaning up the emissions

Advances in engine and vehicle technology continually reduce the amount of pollutants generated, but these alone have generally been proved insufficient to meet emissions goals. Therefore, technologies to react with and clean up the remaining emissions have long been an essential part of emissions control.

Air injection
A very early emissions control system, the Air injection reactor
Air injection reactor

Theory and originsSecondary air injection is an automobile emissions control strategy introduced in 1966, wherein fresh air is injected into the exhaust stream....
 (AIR) reduces the products of incomplete combustion (hydrocarbons and carbon monoxide) by injecting fresh air into the exhaust manifolds of the engine. In the presence of this oxygen-laden air, further combustion occurs in the manifold and exhaust pipe. Generally the air is delivered through an engine-driven 'smog pump' and air tubing to the manifolds.

Exhaust Gas Recirculation
Many engines produced after the 1973 model year have an exhaust gas recirculation
Exhaust gas recirculation

Exhaust gas recirculation is a nitrogen oxide emissions reduction technique used in most gasoline and diesel engines.EGR works by recirculating a portion of an engine's exhaust gas back to the engine cylinder s....
 (EGR) valve between the exhaust and intake manifolds; its sole purpose is to reduce NOx emissions by introducing a metered, and quite small amount of inert gas into the air/fuel mixture, lowering peak combustion temperatures. In the case of EGR, the exhaust gasses are inert enough to serve this purpose.

Catalytic converters
The catalytic converter
Catalytic converter

A catalytic converter is a device used to reduce the toxicity of emissions from an internal combustion engine. First widely introduced on Mass production automobiles in the United States market for the 1975 model year to comply with tightening United States Environmental Protection Agency regulations on auto exhaust, catalytic converters a...
 is a device, placed in the exhaust pipe, which converts various emissions into less harmful ones using, generally, a combination of platinum, palladium and rhodium as catalysts. They make for a significant, and easily applied, method for reducing tailpipe emissions. Catalytic converters are damaged when used on engines that burn leaded fuels. Unleaded fuels were marketed in 1973 and by 1996 leaded fuels were banned completely for on-road use in the USA.

Evaporative emissions control

Efforts at the reduction of evaporative emissions include the capturing of vented vapors from within the vehicle, and the reduction of refuelling emissions.

Capturing vented vapors

Within the vehicle, vapors from the fuel tank are channelled through canisters containing activated carbon
Activated carbon

Activated carbon, also called activated charcoal or activated coal, is a form of carbon that has been processed to make it extremely porous and thus to have a very large surface area available for adsorption or chemical reactions....
 instead of being vented to the atmosphere. These are known as carbon canisters. The vapors are adsorbed within the canister, which feeds into the inlet manifold of the engine.

Emission Testing

In 1966, the first emission test cycle
Emission test cycle

An emission test cycle, also known as a smog check, is a specified procedure for measuring pollutant emissions of engines. For emission measurements to be comparable for different engines in a category, the measurements are performed under a specific operating pattern, or 'test cycle' of alternating high, medium, and low engine load....
 was enacted in the State of California measuring tailpipe emissions in PPM (parts per million). The Environmental Working Group
Environmental Working Group

The Environmental Working Group is an environmental organization that specializes in Environmentalism research and advocacy in the areas of Toxicity, Agricultural subsidy, public lands, and Corporate crime....
 used California ASM emissions data to create an Auto Asthma Index that rates vehicle models based on emissions of hydrocarbons and nitrogen oxides, the chemicals that create smog.

Some cities are also using a technology developed by Dr. Stedman,of University of Denver
University of Denver

The University of Denver , founded in 1864 is the oldest private university university in the Rocky Mountain Region of the United States. The University of Denver is a coeducational, four-year university in Denver, Colorado, Colorado....
 which uses lasers to detect emissions while vehicles pass by on public roads, thus eliminating the need for owners to go to a test center. Stedman's laser detection of exhaust gases is commonly used in metropolitan areas.

See also

  • Aethalometer
  • AP 42 Compilation of Air Pollutant Emission Factors
    AP 42 Compilation of Air Pollutant Emission Factors

    The AP 42 Compilation of Air Pollutant Emission Factors, was first published by the U.S. Public Health Service in 1968. In 1972, it was revised and issued as the second edition by the U.S....
  • Emission standards
  • Low carbon economy
  • Ontario's Drive Clean
    Ontario's Drive Clean

    Ontario's Drive Clean is an automobile emissions control program in Ontario, Canada. It applies only to drivers in southern Ontario. It is unlikely it will be expanded to cover northern Ontario....
  • Portable Emissions Measurement System
  • Roadway air dispersion modeling
    Roadway air dispersion modeling

    Roadway air dispersion modeling is the study of air pollutant transport from a roadway or other linear emitter. Computer models are required to conduct this analysis, because of the complex variables involved, including vehicle emissions, vehicle speed, meteorology, and terrain geometry....
  • Vehicle inspection
    Vehicle inspection

    Vehicle inspection is a procedure mandated by national or subnational governments in many countries, in which a vehicle is inspected to ensure that it conforms to regulations governing Car safety, Automobile emissions control#Emission Testing, or both....
  • On-board diagnostics#OBD-I


External links

  • on FamilyCar.com
  • of the United States Environmental Protection Agency
    United States Environmental Protection Agency

    The U.S. Environmental Protection Agency is an List of United States federal agencies of the federal government of the United States charged to Regulation of chemicals and protect human health by safeguarding the natural environment: air, water, and land....