Atmosphere of Titan
Encyclopedia
Titan (moon)
Titan , or Saturn VI, is the largest moon of Saturn, the only natural satellite known to have a dense atmosphere, and the only object other than Earth for which clear evidence of stable bodies of surface liquid has been found....
is known as the only fully developed atmosphere
Atmosphere
An atmosphere is a layer of gases that may surround a material body of sufficient mass, and that is held in place by the gravity of the body. An atmosphere may be retained for a longer duration, if the gravity is high and the atmosphere's temperature is low...
that exists on a natural satellite in our solar system.
History
The presence of a significant atmosphere was first suspected by Spanish astronomer Josep Comas SolàJosep Comas Solá
Josep Comas i Solà was a Catalan Spanish astronomer.He observed planets including Mars and Saturn, measuring the period of rotation of the latter...
, who observed distinct limb darkening
Limb darkening
Limb darkening refers to the diminishing of intensity in the image of a star as one moves from the center of the image to the edge or "limb" of the image...
on Titan in 1903, and confirmed by Gerard P. Kuiper in 1944 using a spectroscopic technique
Spectroscopy
Spectroscopy is the study of the interaction between matter and radiated energy. Historically, spectroscopy originated through the study of visible light dispersed according to its wavelength, e.g., by a prism. Later the concept was expanded greatly to comprise any interaction with radiative...
that yielded an estimate of an atmospheric partial pressure
Partial pressure
In a mixture of ideal gases, each gas has a partial pressure which is the pressure which the gas would have if it alone occupied the volume. The total pressure of a gas mixture is the sum of the partial pressures of each individual gas in the mixture....
of methane
Methane
Methane is a chemical compound with the chemical formula . It is the simplest alkane, the principal component of natural gas, and probably the most abundant organic compound on earth. The relative abundance of methane makes it an attractive fuel...
of the order of 100 millibars (10 kPa). In 1981, Voyager 1
Voyager 1
The Voyager 1 spacecraft is a 722-kilogram space probe launched by NASA in 1977, to study the outer Solar System and eventually interstellar space. Operating for as of today , the spacecraft receives routine commands and transmits data back to the Deep Space Network. At a distance of as of...
made the first detailed observations of Titan's atmosphere, revealing that its surface pressure was in fact thicker than Earth's, at 1.5 bars. The high surface pressure found on Titan meant that methane could only form a small fraction of Titan's atmosphere.
Extent
Observations from the VoyagerVoyager program
The Voyager program is a U.S program that launched two unmanned space missions, scientific probes Voyager 1 and Voyager 2. They were launched in 1977 to take advantage of a favorable planetary alignment of the late 1970s...
space probes have shown that the Titanian atmosphere is denser than Earth
Earth
Earth is the third planet from the Sun, and the densest and fifth-largest of the eight planets in the Solar System. It is also the largest of the Solar System's four terrestrial planets...
's, with a surface pressure about 1.45 times that of Earth's. Titan's atmosphere is about 1.19 times as massive as Earth's overall, or about 7.3 times more massive on a per surface area basis. It supports opaque haze layers that block most visible light from the Sun and other sources and renders Titan's surface features obscure. The atmosphere is so thick and the gravity so low that humans could fly through it by flapping "wings" attached to their arms. Titan's lower gravity means that its atmosphere is far more extended than Earth's; even at a distance of 975 km, the Cassini spacecraft had to make adjustments to maintain a stable orbit against atmospheric drag. The atmosphere of Titan is opaque at many wavelengths and a complete reflectance spectrum of the surface is impossible to acquire from the outside. It was not until the arrival of the Cassini–Huygens mission in 2004 that the first direct images of Titan's surface were obtained. The Huygens
Huygens probe
The Huygens probe was an atmospheric entry probe carried to Saturn's moon Titan as part of the Cassini–Huygens mission. The probe was supplied by the European Space Agency and named after the Dutch 17th century astronomer Christiaan Huygens....
probe was unable to detect the direction of the Sun during its descent, and although it was able to take images from the surface, the Huygens team likened the process to "taking pictures of an asphalt parking lot at dusk".
Composition
Stratosphere
The stratosphere is the second major layer of Earth's atmosphere, just above the troposphere, and below the mesosphere. It is stratified in temperature, with warmer layers higher up and cooler layers farther down. This is in contrast to the troposphere near the Earth's surface, which is cooler...
is 98.4% nitrogen
Nitrogen
Nitrogen is a chemical element that has the symbol N, atomic number of 7 and atomic mass 14.00674 u. Elemental nitrogen is a colorless, odorless, tasteless, and mostly inert diatomic gas at standard conditions, constituting 78.08% by volume of Earth's atmosphere...
—the only dense, nitrogen-rich atmosphere in the Solar System aside from the Earth's—with the remaining 1.6% composed of mostly of methane (1.4%) and hydrogen (0.1–0.2%). Because methane condenses out of Titan's atmosphere at high altitudes, its abundance increases as one descends below the tropopause
Tropopause
The tropopause is the atmospheric boundary between the troposphere and the stratosphere.-Definition:Going upward from the surface, it is the point where air ceases to cool with height, and becomes almost completely dry...
at an altitude of 32 km, leveling off at a value of 4.9% between 8 km and the surface. There are trace amounts of other hydrocarbons, such ethane
Ethane
Ethane is a chemical compound with chemical formula C2H6. It is the only two-carbon alkane that is an aliphatic hydrocarbon. At standard temperature and pressure, ethane is a colorless, odorless gas....
, diacetylene
Diacetylene
Diacetylene , with the formula C4H2, is a highly unsaturated hydrocarbon that contains three single bonds and two triple bonds. It is the first in the series of polyynes.-Occurrence:...
, methylacetylene
Methylacetylene
Methylacetylene is an alkyne with the chemical formula H3C≡CH. It is a component of MAPP gas along with its isomer 1,2-propadiene , which is commonly used in gas welding...
, acetylene
Acetylene
Acetylene is the chemical compound with the formula C2H2. It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block. It is unstable in pure form and thus is usually handled as a solution.As an alkyne, acetylene is unsaturated because...
and propane
Propane
Propane is a three-carbon alkane with the molecular formula , normally a gas, but compressible to a transportable liquid. A by-product of natural gas processing and petroleum refining, it is commonly used as a fuel for engines, oxy-gas torches, barbecues, portable stoves, and residential central...
, and of other gases, such as cyanoacetylene
Cyanoacetylene
Cyanoacetylene is an organic compound with formula or H-C≡C-C≡N. It is the simplest cyanopolyyne. Cyanoacetylene has been detected by spectroscopic methods in interstellar clouds, in the coma of comet Hale–Bopp and in the atmosphere of Saturn's moon Titan....
, hydrogen cyanide, carbon dioxide
Carbon dioxide
Carbon dioxide is a naturally occurring chemical compound composed of two oxygen atoms covalently bonded to a single carbon atom...
, carbon monoxide
Carbon monoxide
Carbon monoxide , also called carbonous oxide, is a colorless, odorless, and tasteless gas that is slightly lighter than air. It is highly toxic to humans and animals in higher quantities, although it is also produced in normal animal metabolism in low quantities, and is thought to have some normal...
, cyanogen
Cyanogen
Cyanogen is the chemical compound with the formula 2. It is a colorless, toxic gas with a pungent odor.The molecule is a pseudohalogen. Cyanogen molecules consist of two CN groups — analogous to diatomic halogen molecules, such as Cl2, but far less oxidizing...
, argon
Argon
Argon is a chemical element represented by the symbol Ar. Argon has atomic number 18 and is the third element in group 18 of the periodic table . Argon is the third most common gas in the Earth's atmosphere, at 0.93%, making it more common than carbon dioxide...
and helium
Helium
Helium is the chemical element with atomic number 2 and an atomic weight of 4.002602, which is represented by the symbol He. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas that heads the noble gas group in the periodic table...
. The orange color as seen from space must be produced by other more complex chemicals in small quantities, possibly tholin
Tholin
Tholin [after the ancient Greek word meaning "not clear"] is a heteropolymer molecule formed by solar ultraviolet irradiation of simple organic compounds such as methane or ethane. Tholins do not form naturally on modern-day Earth, but are found in great abundance on the surface of icy bodies in...
s, tar-like organic precipitates. The hydrocarbons are thought to form in Titan's upper atmosphere in reactions resulting from the breakup of methane by the Sun's ultraviolet
Ultraviolet
Ultraviolet light is electromagnetic radiation with a wavelength shorter than that of visible light, but longer than X-rays, in the range 10 nm to 400 nm, and energies from 3 eV to 124 eV...
light, producing a thick orange smog. Titan has no magnetic field
Magnetic field
A magnetic field is a mathematical description of the magnetic influence of electric currents and magnetic materials. The magnetic field at any given point is specified by both a direction and a magnitude ; as such it is a vector field.Technically, a magnetic field is a pseudo vector;...
, although studies in 2008 showed that Titan retains remnants of Saturn's magnetic field on the brief occasions when it passes outside Saturn's magnetosphere and is directly exposed to the solar wind
Solar wind
The solar wind is a stream of charged particles ejected from the upper atmosphere of the Sun. It mostly consists of electrons and protons with energies usually between 1.5 and 10 keV. The stream of particles varies in temperature and speed over time...
. This may ion
Ion
An ion is an atom or molecule in which the total number of electrons is not equal to the total number of protons, giving it a net positive or negative electrical charge. The name was given by physicist Michael Faraday for the substances that allow a current to pass between electrodes in a...
ize and carry away some molecules from the top of the atmosphere. In November 2007, scientists uncovered evidence of negative ions with roughly 10 000 times the mass of hydrogen in Titan's ionosphere, which are believed to fall into the lower regions to form the orange haze which obscures Titan's surface. Their structure is not currently known, but they are believed to be tholins, and may form the basis for the formation of more complex molecules, such as polycyclic aromatic hydrocarbons.
Energy from the Sun should have converted all traces of methane in Titan's atmosphere into more complex hydrocarbons within 50 million years — a short time compared to the age of the Solar System. This suggests that methane must be somehow replenished by a reservoir on or within Titan itself. That Titan's atmosphere contains over a thousand times more methane than carbon monoxide
Carbon monoxide
Carbon monoxide , also called carbonous oxide, is a colorless, odorless, and tasteless gas that is slightly lighter than air. It is highly toxic to humans and animals in higher quantities, although it is also produced in normal animal metabolism in low quantities, and is thought to have some normal...
would appear to rule out significant contributions from cometary impacts, since comets are composed of more carbon monoxide than methane. That Titan might have accreted an atmosphere from the early Saturnian nebula at the time of formation also seems unlikely; in such a case, it ought to have atmospheric abundances similar to the solar nebula, including hydrogen
Hydrogen
Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...
and neon
Neon
Neon is the chemical element that has the symbol Ne and an atomic number of 10. Although a very common element in the universe, it is rare on Earth. A colorless, inert noble gas under standard conditions, neon gives a distinct reddish-orange glow when used in either low-voltage neon glow lamps or...
. Many astronomers have suggested that the ultimate origin for the methane in Titan's atmosphere is from within Titan itself, released via eruptions from cryovolcanoes. A possible biological origin for the methane has not been discounted (see Life on Titan
Life on Titan
Whether or not there is life on Titan, the largest moon of Saturn, is at present an open question and a topic of scientific discussion and research....
).
There is also a pattern of air circulation found flowing in the direction of Titan's rotation, from west to east. Observations by Cassini of the atmosphere made in 2004 also suggest that Titan is a "super rotator", like Venus
Venus
Venus is the second planet from the Sun, orbiting it every 224.7 Earth days. The planet is named after Venus, the Roman goddess of love and beauty. After the Moon, it is the brightest natural object in the night sky, reaching an apparent magnitude of −4.6, bright enough to cast shadows...
, with an atmosphere that rotates much faster than its surface.
Titan's ionosphere is also more complex than Earth's, with the main ionosphere at an altitude of 1,200 km but with an additional layer of charged particles at 63 km. This splits Titan's atmosphere to some extent into two separate radio-resonating chambers. The source of natural Extremely Low Frequency
Extremely low frequency
Extremely low frequency is a term used to describe radiation frequencies from 3 to 300 Hz. In atmosphere science, an alternative definition is usually given, from 3 Hz to 3 kHz...
(ELF) waves on Titan, as detected by Cassini-Huygens
Cassini-Huygens
Cassini–Huygens is a joint NASA/ESA/ASI spacecraft mission studying the planet Saturn and its many natural satellites since 2004. Launched in 1997 after nearly two decades of gestation, it includes a Saturn orbiter and an atmospheric probe/lander for the moon Titan, although it has also returned...
, is unclear as there does not appear to be extensive lightning activity.
Titan's internal magnetic field
Magnetic field
A magnetic field is a mathematical description of the magnetic influence of electric currents and magnetic materials. The magnetic field at any given point is specified by both a direction and a magnitude ; as such it is a vector field.Technically, a magnetic field is a pseudo vector;...
is negligible, and perhaps even nonexistent. Its orbital distance of 20.3 Saturn radii
Radius
In classical geometry, a radius of a circle or sphere is any line segment from its center to its perimeter. By extension, the radius of a circle or sphere is the length of any such segment, which is half the diameter. If the object does not have an obvious center, the term may refer to its...
does place it within Saturn's magnetosphere occasionally. However, the difference between Saturn's rotational period (10.7 hours) and Titan's orbital period
Orbital period
The orbital period is the time taken for a given object to make one complete orbit about another object.When mentioned without further qualification in astronomy this refers to the sidereal period of an astronomical object, which is calculated with respect to the stars.There are several kinds of...
(15.95 days) causes a relative speed of about between the Saturn's magnetized plasma
Plasma (physics)
In physics and chemistry, plasma is a state of matter similar to gas in which a certain portion of the particles are ionized. Heating a gas may ionize its molecules or atoms , thus turning it into a plasma, which contains charged particles: positive ions and negative electrons or ions...
and Titan. That can actually intensify reactions causing atmospheric loss, instead of guarding the atmosphere from the solar wind
Solar wind
The solar wind is a stream of charged particles ejected from the upper atmosphere of the Sun. It mostly consists of electrons and protons with energies usually between 1.5 and 10 keV. The stream of particles varies in temperature and speed over time...
.
Evolution
The persistence of a dense atmosphere on Titan has been enigmatic as the atmospheres of the structurally similar satellitesNatural satellite
A natural satellite or moon is a celestial body that orbits a planet or smaller body, which is called its primary. The two terms are used synonymously for non-artificial satellites of planets, of dwarf planets, and of minor planets....
of Jupiter
Jupiter
Jupiter is the fifth planet from the Sun and the largest planet within the Solar System. It is a gas giant with mass one-thousandth that of the Sun but is two and a half times the mass of all the other planets in our Solar System combined. Jupiter is classified as a gas giant along with Saturn,...
, Ganymede
Ganymede (moon)
Ganymede is a satellite of Jupiter and the largest moon in the Solar System. It is the seventh moon and third Galilean satellite outward from Jupiter. Completing an orbit in roughly seven days, Ganymede participates in a 1:2:4 orbital resonance with the moons Europa and Io, respectively...
and Callisto
Callisto (moon)
Callisto named after the Greek mythological figure of Callisto) is a moon of the planet Jupiter. It was discovered in 1610 by Galileo Galilei. It is the third-largest moon in the Solar System and the second largest in the Jovian system, after Ganymede. Callisto has about 99% the diameter of the...
, are negligible. While the disparity is still poorly understood, data from recent missions have provided basic constraints on the evolution of Titan's atmosphere.
Roughly speaking, at the distance of Saturn
Saturn
Saturn is the sixth planet from the Sun and the second largest planet in the Solar System, after Jupiter. Saturn is named after the Roman god Saturn, equated to the Greek Cronus , the Babylonian Ninurta and the Hindu Shani. Saturn's astronomical symbol represents the Roman god's sickle.Saturn,...
, solar insolation
Insolation
Insolation is a measure of solar radiation energy received on a given surface area in a given time. It is commonly expressed as average irradiance in watts per square meter or kilowatt-hours per square meter per day...
and solar wind
Solar wind
The solar wind is a stream of charged particles ejected from the upper atmosphere of the Sun. It mostly consists of electrons and protons with energies usually between 1.5 and 10 keV. The stream of particles varies in temperature and speed over time...
flux
Flux
In the various subfields of physics, there exist two common usages of the term flux, both with rigorous mathematical frameworks.* In the study of transport phenomena , flux is defined as flow per unit area, where flow is the movement of some quantity per time...
are sufficiently low that elements
Chemical element
A chemical element is a pure chemical substance consisting of one type of atom distinguished by its atomic number, which is the number of protons in its nucleus. Familiar examples of elements include carbon, oxygen, aluminum, iron, copper, gold, mercury, and lead.As of November 2011, 118 elements...
and compounds
Chemical compound
A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together...
that are volatile on the terrestrial planet
Terrestrial planet
A terrestrial planet, telluric planet or rocky planet is a planet that is composed primarily of silicate rocks or metals. Within the Solar System, the terrestrial planets are the inner planets closest to the Sun...
s tend to accumulate in all three phases
Phase (matter)
In the physical sciences, a phase is a region of space , throughout which all physical properties of a material are essentially uniform. Examples of physical properties include density, index of refraction, and chemical composition...
. Titan's surface temperature
Temperature
Temperature is a physical property of matter that quantitatively expresses the common notions of hot and cold. Objects of low temperature are cold, while various degrees of higher temperatures are referred to as warm or hot...
is also quite low, about 94 kelvin
Kelvin
The kelvin is a unit of measurement for temperature. It is one of the seven base units in the International System of Units and is assigned the unit symbol K. The Kelvin scale is an absolute, thermodynamic temperature scale using as its null point absolute zero, the temperature at which all...
s (K). Consequently, the mass fractions of substances that can become atmospheric constituents are much larger on Titan than on Earth
Earth
Earth is the third planet from the Sun, and the densest and fifth-largest of the eight planets in the Solar System. It is also the largest of the Solar System's four terrestrial planets...
. In fact, current interpretations suggest that only about 50% of Titan's mass is silicate
Silicate
A silicate is a compound containing a silicon bearing anion. The great majority of silicates are oxides, but hexafluorosilicate and other anions are also included. This article focuses mainly on the Si-O anions. Silicates comprise the majority of the earth's crust, as well as the other...
s, with the rest consisting primarily of various H2O (water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...
) ice
Ice
Ice is water frozen into the solid state. Usually ice is the phase known as ice Ih, which is the most abundant of the varying solid phases on the Earth's surface. It can appear transparent or opaque bluish-white color, depending on the presence of impurities or air inclusions...
s and NH3-H2O (ammonia
Ammonia
Ammonia is a compound of nitrogen and hydrogen with the formula . It is a colourless gas with a characteristic pungent odour. Ammonia contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to food and fertilizers. Ammonia, either directly or...
hydrate
Hydrate
Hydrate is a term used in inorganic chemistry and organic chemistry to indicate that a substance contains water. The chemical state of the water varies widely between hydrates, some of which were so labeled before their chemical structure was understood....
s). NH3, which may be the original source of Titan's atmospheric N2 (dinitrogen), may constitute as much as 8% of the NH3-H2O mass. As Tobie et al. illustrate in Figure 1, Titan is most likely differentiated into layers, where the liquid water layer beneath ice Ih
Ice Ih
thumb|Photograph showing details of an ice cube under magnification. Ice Ih is the form of ice commonly seen on earth.Ice Ih is the hexagonal crystal form of ordinary ice, or frozen water. Virtually all ice in the biosphere is ice Ih, with the exception only of a small amount of ice Ic which is...
may be rich in NH3.
Tentative constraints are available, with the current loss mostly due to low gravity and solar wind aided by photolysis. The loss of Titan's early atmosphere can be estimated with the 14N/15N isotopic ratio, as the lighter 14N is preferentially lost from the upper atmosphere under photolysis and heating. Since Titan's original 14N/15N ratio is poorly constrained, the early atmosphere may have had more N2 by factors ranging from 1.5 to 100 with certainty only in the lower factor. Since N2 is the primary component (98%) of Titan's atmosphere, the isotopic ratio suggests that much of the atmosphere has been lost over geologic time. Nevertheless, atmospheric pressure on its surface remains nearly 1.5 times that of Earth as it began with a proportionally greater volatile budget than Earth
Earth
Earth is the third planet from the Sun, and the densest and fifth-largest of the eight planets in the Solar System. It is also the largest of the Solar System's four terrestrial planets...
or Mars
Mars
Mars is the fourth planet from the Sun in the Solar System. The planet is named after the Roman god of war, Mars. It is often described as the "Red Planet", as the iron oxide prevalent on its surface gives it a reddish appearance...
. It is possible that most of the atmospheric loss was within 50 million years of accretion
Accretion (astrophysics)
In astrophysics, the term accretion is used for at least two distinct processes.The first and most common is the growth of a massive object by gravitationally attracting more matter, typically gaseous matter in an accretion disc. Accretion discs are common around smaller stars or stellar remnants...
, from a highly energetic escape of light atoms carrying away a large portion of the atmosphere (hydrodynamic blow off event). Such an event could be driven by heating and photolysis effects of the early Sun's higher output of X-ray
X-ray
X-radiation is a form of electromagnetic radiation. X-rays have a wavelength in the range of 0.01 to 10 nanometers, corresponding to frequencies in the range 30 petahertz to 30 exahertz and energies in the range 120 eV to 120 keV. They are shorter in wavelength than UV rays and longer than gamma...
and ultraviolet
Ultraviolet
Ultraviolet light is electromagnetic radiation with a wavelength shorter than that of visible light, but longer than X-rays, in the range 10 nm to 400 nm, and energies from 3 eV to 124 eV...
(XUV) photons.
Since Callisto
Callisto (moon)
Callisto named after the Greek mythological figure of Callisto) is a moon of the planet Jupiter. It was discovered in 1610 by Galileo Galilei. It is the third-largest moon in the Solar System and the second largest in the Jovian system, after Ganymede. Callisto has about 99% the diameter of the...
and Ganymede
Ganymede (moon)
Ganymede is a satellite of Jupiter and the largest moon in the Solar System. It is the seventh moon and third Galilean satellite outward from Jupiter. Completing an orbit in roughly seven days, Ganymede participates in a 1:2:4 orbital resonance with the moons Europa and Io, respectively...
are structurally similar to Titan, it is unclear why their atmospheres are insignificant relative to Titan's. Nevertheless, the origin of Titan's N2 via geologically ancient photolysis of accreted
Accretion (astrophysics)
In astrophysics, the term accretion is used for at least two distinct processes.The first and most common is the growth of a massive object by gravitationally attracting more matter, typically gaseous matter in an accretion disc. Accretion discs are common around smaller stars or stellar remnants...
and degassed NH3, as opposed to degassing of N2 from accretionary clathrates, may be the key to a correct inference. Had N2 been released from clathrates, 36Ar and 38Ar that are inert
Inert gas
An inert gas is a non-reactive gas used during chemical synthesis, chemical analysis, or preservation of reactive materials. Inert gases are selected for specific settings for which they are functionally inert since the cost of the gas and the cost of purifying the gas are usually a consideration...
primordial isotopes of the solar system should also be present in the atmosphere, but neither has been detected in significant quantities. The insignificant concentration of 36Ar and 38Ar also indicates that the ~40 K temperature required to trap them and N2 in clathrates did not exist in the Saturnian subnebula. Instead, the temperature may have been higher than 75 K, limiting even the accumulation of NH3 as hydrate
Hydrate
Hydrate is a term used in inorganic chemistry and organic chemistry to indicate that a substance contains water. The chemical state of the water varies widely between hydrates, some of which were so labeled before their chemical structure was understood....
s. Temperatures would have been even higher in the Jovian subnebula due to the greater gravitational potential energy release, mass, and proximity to the Sun, greatly reducing the NH3 inventory accreted by Callisto and Ganymede. The resulting N2 atmospheres may have been too thin to survive the atmospheric erosion effects that Titan has withstood.
An alternative explanation is that cometary impacts release more energy on Callisto and Ganymede than they do at Titan due to the higher gravitational field of Jupiter
Jupiter
Jupiter is the fifth planet from the Sun and the largest planet within the Solar System. It is a gas giant with mass one-thousandth that of the Sun but is two and a half times the mass of all the other planets in our Solar System combined. Jupiter is classified as a gas giant along with Saturn,...
. That could erode the atmospheres of Callisto and Ganymede, while the cometary material would actually build Titan's atmosphere. However, the 2H/1H (i.e., D/H) ratio of Titan's atmosphere is , nearly 1.5 times lower than that of comet
Comet
A comet is an icy small Solar System body that, when close enough to the Sun, displays a visible coma and sometimes also a tail. These phenomena are both due to the effects of solar radiation and the solar wind upon the nucleus of the comet...
s. The difference suggests that cometary material is unlikely to be the major contributor to Titan's atmosphere.