Antimony tribromide
Encyclopedia
Antimony tribromide is a chemical element with the symbol Br, an atomic number of 35, and an atomic mass of 79.904. It is in the halogen element group. The element was isolated independently by two chemists, Carl Jacob Löwig and Antoine Jerome Balard, in 1825–1826...

) is a chemical compound
Chemical compound
A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together...

 containing antimony in its +3 oxidation state. It may be made by the reaction of antimony
Antimony
Antimony is a toxic chemical element with the symbol Sb and an atomic number of 51. A lustrous grey metalloid, it is found in nature mainly as the sulfide mineral stibnite...

 with elemental bromine
Bromine
Bromine ") is a chemical element with the symbol Br, an atomic number of 35, and an atomic mass of 79.904. It is in the halogen element group. The element was isolated independently by two chemists, Carl Jacob Löwig and Antoine Jerome Balard, in 1825–1826...

 or the reaction of antimony trioxide
Antimony trioxide
Antimony trioxide is the inorganic compound with the formula Sb2O3. It is the most important commercial compound of antimony. It is found in nature as the minerals valentinite and senarmontite...

 with hydrobromic acid
Hydrobromic acid
Hydrobromic acid is a strong acid formed by dissolving the diatomic molecule hydrogen bromide in water. "Constant boiling" hydrobromic acid is an aqueous solution that distills at 124.3 °C and contains 47.6% HBr by weight, which is 8.89 mol/L. Hydrobromic acid has a pKa of −9, making it a...

. It can be added to polymer
Polymer
A polymer is a large molecule composed of repeating structural units. These subunits are typically connected by covalent chemical bonds...

s such as polyethylene
Polyethylene
Polyethylene or polythene is the most widely used plastic, with an annual production of approximately 80 million metric tons...

 as a fire retardant
Fire retardant
A fire retardant is a substance other than water that reduces flammability of fuels or delays their combustion. This typically refers to chemical retardants but may also include substances that work by physical action, such as cooling the fuels; examples of these include fire-fighting foams and...

. It is also used in the production of other antimony compounds, in chemical analysis, and in dyeing.

Antimony tribromide has two crystalline forms, both having orthorhombic symmetries. When a warm carbon disulfide
Carbon disulfide
Carbon disulfide is a colorless volatile liquid with the formula CS2. The compound is used frequently as a building block in organic chemistry as well as an industrial and chemical non-polar solvent...

solution of SbBr3 is rapidly cooled, it crystallizes into the needle-like α-SbBr3, which then slowly converts to the more stable β form.

Antimony tribromide hydrolyzes in water to form hydrobromic acid and antimony trioxide:
2 SbBr3 + 3 H2O → Sb2O3 + 6 HBr
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