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Angular momentum operator
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In quantum mechanics, the angular momentum operator is an operator analogous to classical angular momentum. The angular momentum operator plays a central role in the theory of atomic physics and other quantum problems involving rotational symmetry. In both classical and quantum mechanical systems, angular momentum (together with linear momentum and energy) is one of the three fundamental properties of motion.
Intuitive meaningAngular momentum quantifies the rotational aspect of motion. Like energy and linear momentum, angular momentum in an isolated system is conserved. The concept of an angular momentum operator is necessary in quantum mechanics, as calculations of angular momentum must be made upon a wave function, rather than on a point or rigid body as classical calculations entail. This is because at the scale of quantum mechanics, the matter analyzed is best described by a wave equation or probability amplitude, rather than as a collection of fixed points or as a rigid body. Vector calculus is used in calculations of angular momentum, as angular momentum has compenents in each of the three spatial dimensions.
Mathematical definitionAngular momentum L is mathematically defined as the cross product of a wave function's position operator (r) and momentum operator (p):
In the special case of a single particle with no electric charge and no spin, the angular momentum operator can be written in the position basis as a single vector equation:
where is the gradient operator. This is a commonly encountered form of the angular momentum operator, though not the most general one.
Further analysis of commutation propertiesThe first commutation relation above is an example of what is generally known as a Lie algebra. In this case, the Lie algebra is that of SU(2) or SO(3), the rotation group in three dimensions. The second commutation relation indicates that is a Casimir invariant. The third commutation relation states that the angular momentum is a constant of motion, and is a special case of Liouville's equation for quantum mechanics, or more precisely, of Ehrenfest's theorem.
In classical physicsIt should be noted that the angular momentum in classical mechanics obeys a similar commutation relation,
where is the Poisson bracket.
Angular momentum computations in spherical coordinates- This section includes mathematical equations involving partial differential equations and Dirac notation.
Angular momentum operators usually occur when solving a problem with spherical symmetry in spherical coordinates. Then, the angular momentum in space representation is: When solving to find eigenstates of this operator, we obtain the following where
are the spherical harmonics.
See also- Runge-Lenz vector (used to describe the shape and orientation of bodies in orbit)
- Position operator
- Momentum operator
- Annihilation operator
- Creation operator
- Hamiltonian operator
- Ladder operator
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